Accounts of Chemical Research

Article	Citations
Synergistic Modulation of Non-Precious-Metal Electrocatalysts for Advanced Water Splitting	324
Heavy-Atom-Free Photosensitizers: From Molecular Design to Applications in the Photodynamic Therapy of Cancer	320
Metal–Organic Framework Derived Nanozymes in Biomedicine	318
Fused-Ring Electron Acceptors for Photovoltaics and Beyond	268
Transition Metal-Catalyzed Tandem Reactions of Ynamides for Divergent N-Heterocycle Synthesis	266
Strategy for Treatment of Infected Diabetic Foot Ulcers	261
Advanced Platinum-Based Oxygen Reduction Electrocatalysts for Fuel Cells	252
Polyphenol-Mediated Assembly for Particle Engineering	250
Chemistry of Lipid Nanoparticles for RNA Delivery	250
CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition	237
Cross-Electrophile Couplings of Activated and Sterically Hindered Halides and Alcohol Derivatives	222
New Perspectives to Trigger and Modulate Circularly Polarized Luminescence of Complex and Aggregated Systems: Energy Transfer, Photon Upconversion, Charge Transfer, and Organic Radical	220
Radical Carboxylative Cyclizations and Carboxylations with CO2	215
Radical-Mediated Remote Functional Group Migration	211
Supramolecular Purely Organic Room-Temperature Phosphorescence	189
Expanding the Boundary of Biorefinery: Organonitrogen Chemicals from Biomass	184
Polymer Acceptors Containing B←N Units for Organic Photovoltaics	181
Data-Driven Strategies for Accelerated Materials Design	176
Chemically Stable Metal–Organic Frameworks: Rational Construction and Application Expansion	175
Narrowing the Band Gap: The Key to High-Performance Organic Photovoltaics	175
Atomic Insights into the Fundamental Interactions in Lithium Battery Electrolytes	173
Selectivity in Electrochemical CO2 Reduction	169
Long-Lived Organic Room-Temperature Phosphorescence from Amorphous Polymer Systems	167
Confinement in a Zeolite and Zeolite Catalysis	167
Organocatalytic Atroposelective Synthesis of Indole Derivatives Bearing Axial Chirality: Strategies and Applications	167

Designing High Performance Organic Batteries	164
Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer	164
Achieving High Performance Metal–Organic Framework Materials through Pore Engineering	164
Mixed Electronic States in Molecular Dimers: Connecting Singlet Fission, Excimer Formation, and Symmetry-Breaking Charge Transfer	163
Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes	160
Three-Dimensional Covalent Organic Frameworks: From Topology Design to Applications	159
Metalloporphyrins as Catalytic Models for Studying Hydrogen and Oxygen Evolution and Oxygen Reduction Reactions	159
Covalent Organic Frameworks: Pore Design and Interface Engineering	158
High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies	158
Reticular Chemistry for Highly Porous Metal–Organic Frameworks: The Chemistry and Applications	157
Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions	155
Theory of Long-Lived Room-Temperature Phosphorescence in Organic Aggregates	154
Prospects of an Electroactive Carbon Nanotube Membrane toward Environmental Applications	151
Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling	150
Eutectic Electrolytes as a Promising Platform for Next-Generation Electrochemical Energy Storage	148
Metal-Catalyzed Approaches toward the Oxindole Core	148
Supramolecularly Engineered J-Aggregates Based on Perylene Bisimide Dyes	144
Applications of Deep Learning in Molecule Generation and Molecular Property Prediction	141
Azulene-Based π-Functional Materials: Design, Synthesis, and Applications	135
Nanoscale Metal–Organic Frameworks for Cancer Immunotherapy	133
Innovative Approaches to Li-Argyrodite Solid Electrolytes for All-Solid-State Lithium Batteries	132
Engineered Nanoparticles for Cancer Vaccination and Immunotherapy	132
From C4 to C7: Innovative Strategies for Site-Selective Functionalization of Indole C–H Bonds	132
Silica-Based Nanoparticles for Biomedical Applications: From Nanocarriers to Biomodulators	132
Chiral Pd-Catalyzed Enantioselective Syntheses of Various N–C Axially Chiral Compounds and Their Synthetic Applications	131
UV/Chlorine Process: An Efficient Advanced Oxidation Process with Multiple Radicals and Functions in Water Treatment	130
Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source	128
Exploring Anion−π Interactions and Their Applications in Supramolecular Chemistry	126
Giant Rylene Imide-Based Electron Acceptors for Organic Photovoltaics	126
Cyclodextrin Metal–Organic Frameworks and Their Applications	125
Responsive Metal Complex Probes for Time-Gated Luminescence Biosensing and Imaging	124
Electrochemical Approaches for CO2 Conversion to Chemicals: A Journey toward Practical Applications	124
Lanthanide-Activated Nanoparticles: A Toolbox for Bioimaging, Therapeutics, and Neuromodulation	124
Hydrogen Generation upon Nanocatalyzed Hydrolysis of Hydrogen-Rich Boron Derivatives: Recent Developments	123
Design Strategy of Fluorescent Probes for Live Drug-Induced Acute Liver Injury Imaging	122
Zeolite Fixed Metal Nanoparticles: New Perspective in Catalysis	122
Palladium-Catalyzed Asymmetric Allylic C–H Functionalization: Mechanism, Stereo- and Regioselectivities, and Synthetic Applications	121
Electrolyte Effects on CO2 Electrochemical Reduction to CO	120
Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds	119
N-Heterocyclic Carbenes: A Door Open to Supramolecular Organometallic Chemistry	117
2-(Pyridin-2-yl)isopropyl (PIP) Amine: An Enabling Directing Group for Divergent and Asymmetric Functionalization of Unactivated Methylene C(sp3)–H Bonds	116
Rational Design of Electrochemiluminescent Devices	114
Lithium–Air Batteries: Air-Electrochemistry and Anode Stabilization	114
Metal Halide Superionic Conductors for All-Solid-State Batteries	112
How the Ligand Field in Lanthanide Coordination Complexes Determines Magnetic Susceptibility Anisotropy, Paramagnetic NMR Shift, and Relaxation Behavior	111
Heterogeneous Molecular Catalysts of Metal Phthalocyanines for Electrochemical CO2 Reduction Reactions	110
Bioinspired Applications of Porphyrin Derivatives	109
Emerging Potassium Metal Anodes: Perspectives on Control of the Electrochemical Interfaces	108
Intramolecularly Cross-Linked Polymers: From Structure to Function with Applications as Artificial Antibodies and Artificial Enzymes	107
Alkyne-Palladium(II)-Catalyzed Living Polymerization of Isocyanides: An Exploration of Diverse Structures and Functions	105

Organocatalytic Enantioselective Synthesis of Axially Chiral Molecules: Development of Strategies and Skeletons	105
Charge Transport in Zirconium-Based Metal–Organic Frameworks	104
Chiral Induced Spin Selectivity Gives a New Twist on Spin-Control in Chemistry	104
2D Conjugated Covalent Organic Frameworks: Defined Synthesis and Tailor-Made Functions	104
Programmable Morphing Hydrogels for Soft Actuators and Robots: From Structure Designs to Active Functions	103
Halide Ion Migration in Perovskite Nanocrystals and Nanostructures	103
Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value-Added Products over Porous Metal/Covalent Organic Frameworks	103
Promoting Rechargeable Batteries Operated at Low Temperature	102
Making ATRP More Practical: Oxygen Tolerance	102
Forging Odd-Membered Rings: Palladium-Catalyzed Asymmetric Cycloadditions of Trimethylenemethane	102
n-Type Organic and Polymeric Semiconductors Based on Bithiophene Imide Derivatives	102
Issues and Advances in Scaling up Sulfide-Based All-Solid-State Batteries	101
The Concept of Chemical Generators: On-Site On-Demand Production of Hazardous Reagents in Continuous Flow	101
Supramolecular Chirality in Metal–Organic Complexes	97
Exploring Multifunctional Hydrogen-Bonded Organic Framework Materials	97
Nano–Bio Interactions in Cancer: From Therapeutics Delivery to Early Detection	96
New Multiphase Chemical Processes Influencing Atmospheric Aerosols, Air Quality, and Climate in the Anthropocene	96
Lipid Nanoparticle–mRNA Formulations for Therapeutic Applications	94
Vanadium-Based Materials: Next Generation Electrodes Powering the Battery Revolution?	93
Engineering of Norbornadiene/Quadricyclane Photoswitches for Molecular Solar Thermal Energy Storage Applications	92
Reductive Cross-Coupling of Unreactive Electrophiles	92
Exploiting Heavier Organochalcogen Compounds in Donor–Acceptor Cyclopropane Chemistry	92
Molecular Photoswitching in Confined Spaces	90
Spray-Drying Synthesis of MOFs, COFs, and Related Composites	90
Selenium-Containing Organic Photovoltaic Materials	90
Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity	90
Carbon Shell on Active Nanocatalyst for Stable Electrocatalysis	90
Engineering Catalyst–Electrolyte Microenvironments to Optimize the Activity and Selectivity for the Electrochemical Reduction of CO2 on Cu and Ag	88
Metal Chalcogenide Supertetrahedral Clusters: Synthetic Control over Assembly, Dispersibility, and Their Functional Applications	88
Fuzziness and Frustration in the Energy Landscape of Protein Folding, Function, and Assembly	88
Development and Evolution of Energetic Cocrystals	88
Copper-Catalyzed Carbonylative Coupling of Alkyl Halides	88
Current Strategies for Modulating Aβ Aggregation with Multifunctional Agents	87
Tetracoordinate Boron Intermediates Enable Unconventional Transformations	87
Chemical Interface Damping of Surface Plasmon Resonances	87
Local and Targeted Delivery of Immune Checkpoint Blockade Therapeutics	86
Exotic Topological Bands and Quantum States in Metal–Organic and Covalent–Organic Frameworks	86
The Prodigious Hydrogen Bonds with Sulfur and Selenium in Molecular Assemblies, Structural Biology, and Functional Materials	86
CO2 Reduction Using Water as an Electron Donor over Heterogeneous Photocatalysts Aiming at Artificial Photosynthesis	85
Atropisomerism in the Pharmaceutically Relevant Realm	85
Electrochemical Conversion of CO2 to Syngas with Palladium-Based Electrocatalysts	85
Development of Multimodal Machine Learning Potentials: Toward a Physics-Aware Artificial Intelligence	84
Layered Oxide Cathodes for Sodium-Ion Batteries: Storage Mechanism, Electrochemistry, and Techno-economics	84
NMR Calculations with Quantum Methods: Development of New Tools for Structural Elucidation and Beyond	84
Solvation and Mobilization of Copper Active Sites in Zeolites by Ammonia: Consequences for the Catalytic Reduction of Nitrogen Oxides	83
Mechanisms of Thermal Atomic Layer Etching	83
Strategies to Combat Multi-Drug Resistance in Tuberculosis	82
Time and Pot Economy in Total Synthesis	82
The Role of Carbonate in Catalytic Oxidations	82
The RaPID Platform for the Discovery of Pseudo-Natural Macrocyclic Peptides	82
Dynamic Core–Shell and Alloy Structures of Multimetallic Nanomaterials and Their Catalytic Synergies	82
Photobiocatalysis for Abiological Transformations	81
Effect of Surface Ligands in Perovskite Nanocrystals: Extending in and Reaching out	80
Crystal Phase Control of Gold Nanomaterials by Wet-Chemical Synthesis	78
Biomaterials as Local Niches for Immunomodulation	77
Ferritin: A Multifunctional Nanoplatform for Biological Detection, Imaging Diagnosis, and Drug Delivery	77
Stimuli-Induced Reversible Proton Transfer for Stimuli-Responsive Materials and Devices	77
A Strategy for Selective Catalytic B–H Functionalization of o-Carboranes	77
The Surface Chemistry and Structure of Colloidal Lead Halide Perovskite Nanocrystals	76
Enantioselective Synthesis of Atropisomers via Vinylidene ortho-Quinone Methides (VQMs)	76
Fluorinated Ylides/Carbenes and Related Intermediates from Phosphonium/Sulfonium Salts	76
Predicting Reaction Yields via Supervised Learning	76
Stimuli-Responsive Crystalline Smart Materials: From Rational Design and Fabrication to Applications	75
Latest Advances in Flexible Symmetric Supercapacitors: From Material Engineering to Wearable Applications	75
Development of Triggerable, Trackable, and Targetable Carbon Monoxide Releasing Molecules	75
Organogermanes as Orthogonal Coupling Partners in Synthesis and Catalysis	75
Opportunity of Atomically Thin Two-Dimensional Catalysts for Promoting CO2 Electroreduction	75
Toward the Copolymerization of Propylene with Polar Comonomers	74
Methane Oxidation to Methanol in Water	74
Neutral Nickel(II) Catalysts: From Hyperbranched Oligomers to Nanocrystal-Based Materials	73
The Pauli Repulsion-Lowering Concept in Catalysis	73
Large Cages of Zeolitic Imidazolate Frameworks	73
Yne–Enones Enable Diversity-Oriented Catalytic Cascade Reactions: A Rapid Assembly of Complexity	72
Mapping Materials and Molecules	72
Self-Assembling Supramolecular Dendrimers for Biomedical Applications: Lessons Learned from Poly(amidoamine) Dendrimers	72
Recent Advances in Stimuli-Responsive Platforms for Cancer Immunotherapy	72
Aromatic π-Components for Enantioselective Heck Reactions and Heck/Anion-Capture Domino Sequences	72
Manipulating the Dynamics of Dark Excited States in Organic Materials for Phototheranostics	71
N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry	71
Cobalt-Catalyzed Cross-Couplings between Alkyl Halides and Grignard Reagents	71

NiH-Catalyzed Functionalization of Remote and Proximal Olefins: New Reactions and Innovative Strategies	71
The Optoelectronic Nose	71
Biphen[n]arenes: Modular Synthesis, Customizable Cavity Sizes, and Diverse Skeletons	70
Two-Dimensional Nanofluidic Membranes toward Harvesting Salinity Gradient Power	70
Carboxylic Acids as Adaptive Functional Groups in Metallaphotoredox Catalysis	70
Double-Cable Conjugated Polymers with Pendant Rylene Diimides for Single-Component Organic Solar Cells	70
The Discovery of Multifunctional Chiral P Ligands for the Catalytic Construction of Quaternary Carbon/Silicon and Multiple Stereogenic Centers	70
Transition Metal-Catalyzed Biaryl Atropisomer Synthesis via a Torsional Strain Promoted Ring-Opening Reaction	70
Advanced Pt-Based Core–Shell Electrocatalysts for Fuel Cell Cathodes	69
Reimagining Druggability Using Chemoproteomic Platforms	68
Large-Scale Atomic Simulation via Machine Learning Potentials Constructed by Global Potential Energy Surface Exploration	68
Molecular Triangles: A New Class of Macrocycles	67
Intrinsically Porous Molecular Materials (IPMs) for Natural Gas and Benzene Derivatives Separations	67
Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics	67
General-Purpose Machine Learning Potentials Capturing Nonlocal Charge Transfer	67
Pillararene-Inspired Macrocycles: From Extended Pillar[n]arenes to Geminiarenes	67
Plasma-Enhanced Chemical Vapor Deposition of Two-Dimensional Materials for Applications	67
N-Functionalized Pyridinium Salts: A New Chapter for Site-Selective Pyridine C–H Functionalization via Radical-Based Processes under Visible Light Irradiation	66
Bifunctional Iminophosphorane Superbase Catalysis: Applications in Organic Synthesis	66
Functional Regulation and Stability Engineering of Three-Dimensional Covalent Organic Frameworks	66
Enzyme-Laden Bioactive Hydrogel for Biocatalytic Monitoring and Regulation	66
The Importance of Highly Connected Building Units in Reticular Chemistry: Thoughtful Design of Metal–Organic Frameworks	66
Achieving Efficient n-Doping of Conjugated Polymers by Molecular Dopants	66
Excitons and Polarons in Organic Materials	65
Low Temperature Activation of Methane on Metal-Oxides and Complex Interfaces: Insights from Surface Science	65
Mimicking Color-Changing Organisms to Enable the Multicolors and Multifunctions of Smart Fluorescent Polymeric Hydrogels	65
Inorganometallic Photocatalyst for CO2 Reduction	65
Carbon Nanotube Photoluminescence Modulation by Local Chemical and Supramolecular Chemical Functionalization	65
Large π-Extended and Curved Carbon Nanorings as Carbon Nanotube Segments	64
Ultralong Organic Phosphorescence: From Material Design to Applications	64
Density Functional Theory Based Methods for the Calculation of X-ray Spectroscopy	64
Tumor-Targeted Nanomedicine for Immunotherapy	64
Photocatalytic Systems for CO2 Reduction: Metal-Complex Photocatalysts and Their Hybrids with Photofunctional Solid Materials	64
Non-liver mRNA Delivery	64
Hierarchically Porous MOFs Synthesized by Soft-Template Strategies	63
Smart Nanosized Drug Delivery Systems Inducing Immunogenic Cell Death for Combination with Cancer Immunotherapy	63
Modulation of Metal Halide Structural Units for Light Emission	63
Developing Biodegradable Lipid Nanoparticles for Intracellular mRNA Delivery and Genome Editing	63
A Type of Structurally Adaptable Aromatic Spiroketal Based Chiral Diphosphine Ligands in Asymmetric Catalysis	63
Autonomous Chemical Experiments: Challenges and Perspectives on Establishing a Self-Driving Lab	62
Digitizing Chemistry Using the Chemical Processing Unit: From Synthesis to Discovery	62
Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations	62
Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations	62
Corannulene: A Curved Polyarene Building Block for the Construction of Functional Materials	62
Excited-State Engineering in Heteroleptic Ionic Iridium(III) Complexes	61
Visualizing the Sensitive Lithium with Atomic Precision: Cryogenic Electron Microscopy for Batteries	61
Oriented Attachment: From Natural Crystal Growth to a Materials Engineering Tool	61
Polymerized Molecular Receptors as Adsorbents to Remove Micropollutants from Water	61
Catalytic Chemo- and Enantioselective Transformations of gem-Diborylalkanes and (Diborylmethyl)metallic Species	61
Emerging Electrochemical Techniques for Probing Site Behavior in Single-Atom Electrocatalysts	60
Palladium-Catalyzed Enantioselective β-C(sp3)–H Activation Reactions of Aliphatic Acids: A Retrosynthetic Surrogate for Enolate Alkylation and Conjugate Addition	60
Ionic-Liquid-Catalyzed Approaches under Metal-Free Conditions	60
Black-Box Optimization for Automated Discovery	59
Liquid–Liquid Phase Separation in Supermicrometer and Submicrometer Aerosol Particles	59
Cobalt Carbide Nanocatalysts for Efficient Syngas Conversion to Value-Added Chemicals with High Selectivity	58
Charge Transport in Organic Semiconductors: The Perspective from Nonadiabatic Molecular Dynamics	58
The Genesis of Molecular Volcano Plots	57
Adsorption Enthalpies for Catalysis Modeling through Machine-Learned Descriptors	57
High-Throughput Raman Flow Cytometry and Beyond	57
Nanomedicines for Renal Management: From Imaging to Treatment	57
Coupling without Coupling Reactions: En Route to Developing Phenols as Sustainable Coupling Partners via Dearomatization–Rearomatization Processes	57
Light-Induced Voltages in Catalysis by Plasmonic Nanostructures	57
Bioinspired Superspreading Surface: From Essential Mechanism to Application	57
Fluorination Promotes the Cytosolic Delivery of Genes, Proteins, and Peptides	57
The Power of Fiber Twist	56
Functional Nucleic Acids for Pathogenic Bacteria Detection	56
Design Principles for Efficient and Stable Water Splitting Photoelectrocatalysts	56
Alkylammonium Halides for Facet Reconstruction and Shape Modulation in Lead Halide Perovskite Nanocrystals	56
Asymmetric Synthesis of Fluoro, Fluoromethyl, Difluoromethyl, and Trifluoromethylcyclopropanes	56
Theories for Electrolyte Effects in CO2 Electroreduction	55
Automated Experimentation Powers Data Science in Chemistry	55
Sulfono-γ-AApeptides as Helical Mimetics: Crystal Structures and Applications	55
A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices	55
Nickel-Catalyzed Reductive Carboxylation and Amidation Reactions	55
Guiding CO2RR Selectivity by Compositional Tuning in the Electrochemical Double Layer	55
New Twists in Nazarov Cyclization Chemistry	54
Importance of Engineered and Learned Molecular Representations in Predicting Organic Reactivity, Selectivity, and Chemical Properties	54
Symmetry-Breaking Sites for Activating Linear Carbon Dioxide Molecules	54
Combining Computational Modeling with Reaction Kinetics Experiments for Elucidating the In Situ Nature of the Active Site in Catalysis	54
From Low to No O2-Dependent Hypoxia Photodynamic Therapy (hPDT): A New Perspective	54
Fluorescent Probes for Biological Species and Microenvironments: from Rational Design to Bioimaging Applications	54
Collective Behaviors of Magnetic Active Matter: Recent Progress toward Reconfigurable, Adaptive, and Multifunctional Swarming Micro/Nanorobots	54
Controlling Defect-State Photophysics in Covalently Functionalized Single-Walled Carbon Nanotubes	53
Rhodium-Catalyzed C–H Alkenylation/Electrocyclization Cascade Provides Dihydropyridines That Serve as Versatile Intermediates to Diverse Nitrogen Heterocycles	53
Synthesis of C2+ Chemicals from CO2 and H2 via C–C Bond Formation	53
Engineering Strategies for Lymph Node Targeted Immune Activation	53
Cross-Coupling Reactions of Nitroarenes	53
LAURDAN since Weber: The Quest for Visualizing Membrane Heterogeneity	53
Self-Assembly and Regrowth of Metal Halide Perovskite Nanocrystals for Optoelectronic Applications	52
Road Map for the Construction of High-Valued N-Heterocycles via Denitrogenative Annulation	52
Advances in Molecular Understanding of α-Helical Membrane-Active Peptides	52
The Dawn of Metal-Oxo Clusters as Artificial Proteases: From Discovery to the Present and Beyond	52
Data Science Meets Physical Organic Chemistry	51
Learning to Approximate Density Functionals	51
Engineering the Bio–Nano Interface Using a Multifunctional Coordinating Polymer Coating	51