Journal of Analytical Atomic Spectrometry

Papers
(The TQCC of Journal of Analytical Atomic Spectrometry is 6. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2022-06-01 to 2026-06-01.)
ArticleCitations
Nano-imaging mass spectrometry by means of high-energy laser desorption ionization (HELDI)60
Back cover52
Spectroscopic characterization of uranium atoms in uranium-dioxide laser-produced plasma in a high-vacuum environment48
Back cover41
Front cover39
Evaluation of miniaturized ultrasonic nebulization for high-efficiency sampling in characterization of silver nanoparticles by single particle inductively coupled plasma mass spectrometry38
Nanoparticle-enhanced laser-induced breakdown spectroscopy for serum element analysis using an Ag NP-coated filter paper substrate34
Contents list34
Fast and high spatially resolved multielemental mapping of otoliths using IR&UV-femtosecond laser ablation-ICP-TOFMS33
Build-a-bone: development of a matrix-matched reference material for quantitative analysis of bone with portable LIBS33
Improvement in the sensitivity of LA-ICP-MS bioimaging by addition of nitrogen to the argon carrier gas32
Instrumental mass-independent fractionation accounting for the sensitivity of the double spike proportion effect by MC-ICP-MS: a case study of Zn isotope measurements31
Precise determination of stable W isotopic compositions of seawater with Fe co-precipitation and double spike MC-ICP-MS30
High-accuracy quantification of soil elements by laser-induced breakdown spectroscopy based on PCA-GS-ELM29
Plasma emission intensity expansion of Zr metal and Zr oxide via microwave enhancement laser-induced breakdown spectroscopy28
The potential of a multi-method platform centred on ICP-MS to provide new insights into the size-resolved quantification of TiO2 particles in food28
An efficient Cd two-stage column system for high-precision determination of Cd isotopic compositions by double spike MC-ICP-MS28
Correction: Development of a multi-isotopic (Pb, Fe, Cu) analytical protocol in gold matrices for ancient coin provenance studies25
Lithium-ion batteries: direct solid sampling for characterisation of black mass recyclates using graphite furnace atomic absorption spectrometry25
Investigation of signal enhancement in nanoparticle enhanced molecular LIBS of graphite25
: a selection tool for asymmetric reflections of spherically bent crystal analyzers for high resolution X-ray spectroscopy23
Two-stage semi-supervised machine learning for classification of Ti-rich nanoparticles and microparticles measured by spICP-TOFMS23
Direct quantification of total organic carbon in soils using native CN and C 2 molecular emissions by laser-induced breakdown spectroscopy (LIBS)22
Detection of lead in water at ppt levels using resin-enrichment combined with LIBS-LIF22
A novel hydride generation and gas–liquid separation device for the determination of trace zinc by atomic fluorescence spectrometry22
Accurate thresholding using a compound-Poisson-lognormal lookup table and parameters recovered from standard single particle ICP-TOFMS data22
Automated online SPE-ICP-MS for ultra-trace determination of mercury in freshwaters21
A newly synthesized reference material for in situ sulfur isotope measurement of sphalerite using laser ablation MC-ICP-MS21
Uncertainties in isotopic ratio measurements of individual silver nanoparticles using multiple-collector ICP-mass spectrometry21
Detection of chromium in different valence states in water and soil using laser-induced breakdown spectroscopy combined with an ion enrichment chip21
Trigger-free LIBS using kHz and a few mJ laser in combination with random forest regression for the quantitative analysis of steel elements20
Continuous-flow analyses of calcium isotopes using a Neoma MC-ICPMS/MS with H 2 or SF 620
Back cover20
Potential direct mass spectral elemental analysis of solids by microwave plasma torch surface release and ionization20
Measurement of uranium and fission products in a spent fuel sample using fiber-optic laser-induced breakdown spectroscopy20
High-precision double-spike Sn isotope analysis of geological materials by MC-ICP-MS20
Iron, copper and zinc isotope compositions of biological reference materials determined by MC-ICP-MS19
Investigation of Al Kα satellite lines through a high-efficiency multi-channel FSSR19
Development of a simple and rapid EDXRF method for quantification of ZrO2 and HfO2 in aqueous and organic process stream solutions generated from a zirconium extraction facility19
Inside front cover19
Hidra aeschynite-(Y): a potential natural reference material for microbeam Pb–Pb and Lu–Hf geochronology18
Quantitative fluoride imaging of teeth using CaF emission by laser induced breakdown spectroscopy18
Contents list18
Spectral signal enhancement in laser-induced breakdown spectroscopy via arc discharge assistance18
High-precision quantification and low detection limits of chlorine and fluorine in coal via laser-induced breakdown spectroscopy18
Fast analysis of metal components in coal dust using spark emission spectroscopy18
The feasibility of using a pyrite standard to calibrate the sulfur isotope ratio of marcasite during SIMS analysis18
In situ detection of neodymium isotopes using tunable diode laser absorption spectroscopy for nuclear forensic analysis17
Development of sulfur isotope microanalysis of calcite using secondary ion mass spectrometry: methodology and matrix effects17
Zirconium analysis in microscopic spent nuclear fuel samples by resonance ionization mass spectrometry17
Experimental determination of ruthenium L-shell fluorescence yields and Coster–Kronig transition probabilities17
Feasibility study to evaluate composition and degradation of orichalcum ingots through combined XRF and VIS-SWIR reflectance mapping17
The KNW rutile—a natural reference material for microbeam U–Pb age and trace element determination17
High-sensitivity analysis of trace elements in water using femtosecond LIBS with dry droplet pretreatment on a metallic substrate16
Analysis of gold in mineral ores based on a newly-built portable handheld LIBS system16
Synthesis and characterization of a U/Pu mixed-actinide microparticulate reference material16
A spectral microsensor applied in LIBS for heavy metal detection in water16
Simultaneously obtaining stable and radiogenic Nd isotope ratios through a single DGA column using double spike TIMS16
Effect of matrix temperature on the LIBS signal of Au16
Data augmentation using GANN in the quantitative LIBS analysis of scarce samples: a case study on polymetallic nodules from 5000 m ocean depth16
Simultaneous analysis of gadolinium and surface imaging using a fiber-coupled acoustic wave-assisted microchip LIBS system16
Atomic spectrometry update: review of advances in environmental analysis16
Influence of laser wavelength (532 nm vs. 1064 nm) on plasma diagnostics and self-absorption in LIBS of titanium for automotive applications16
Bimodal data fusion of LIBS spectroscopy and plasma acoustic emission signals: improving the accuracy of machining process identification for low roughness samples16
Vesuvianite: a new mineral species of (U–Th)/He geochronology16
Depth profiling of noble gases in ilmenite and olivine substrates16
Ultra-trace elemental determination of Si by means of graphite furnace-atomic absorption spectrometry16
Morphology–spectral correlations of laser-induced Al plasma with plate wall spatial confinement15
High-accuracy uranium determination via functional decomposition to address matrix effects in XRF spectroscopy15
Inside back cover15
The Saha ionisation equilibrium shift correction model applied to MPT-OES for analysing complex matrix samples: an example for brine samples15
Cu fractionation, isotopic analysis, and data processing via machine learning: new approaches for the diagnosis and follow up of Wilson's disease via ICP-MS15
SP-IM and SP-SP: two potential natural sphalerite reference materials for in situ Zn and S isotope analysis by LA-MC-ICP-MS15
Contents list15
A digestion-purging-trapping method for precise stable mercury isotope measurements of natural carbonates15
Comment on “Limitations in using the Cu isotopic composition of minerals from ancient copper mines for archaeometric purposes – a case study” by P. A. Penanes, M. Costas-Rodríguez, M. Moldovan, J. I. 15
TARIM calcite: a potential reference material for laser ICPMS in situ calcite U–Pb dating15
Concomitant ion matrix effects in SCGD-OES enhanced with formic acid15
Front cover14
An emergency radiobioassay method for Pu, Am and Cm isotopes in urine samples using tandem quadrupole ICP-MS14
Boron elemental and isotopic determination via the BF diatomic molecule using high-resolution continuum source graphite furnace molecular absorption spectrometry14
Back cover14
Investigation of a method for the correction of self-absorption by Planck function in laser induced breakdown spectroscopy14
Effect of repeated irradiation on laser-induced breakdown spectroscopy of copper immersed in a sodium chloride aqueous solution and normalization with bubble collapse time14
On the use of end-on observation in optical emission spectroscopy measurements of the maximum electric field strength in the cathode sheath of Grimm-type glow discharges in helium14
Accurate determination of sulfur, selenium and tellurium in geological reference materials by isotope dilution inductively coupled plasma-tandem mass spectrometry (ID-ICP-MS/MS)14
A convective heated digestion system with closed vessels: a new digestor for elemental inorganic analysis14
Sensitive determination of neodymium isotope in seawater by multi-collector inductively coupled plasma mass spectrometry with ultrasound nebulization-dielectric barrier discharge vapor generation as s14
A synthesized sphalerite standard for in situ analysis of sulfur isotopes and trace elements by LA-MC-ICP-MS and LA-ICP-MS13
Improvements in low-level radionuclide measurement capability through use of the Apex Q sample introduction system combined with ICP-MS/MS13
Uranium isotopic analysis in unpurified solutions by ICP-MS13
Impact of Ag NPs on temporal evolution of plasma emission in nanoparticle-enhanced laser-induced breakdown spectroscopy13
Determination of Ce and La in REE-rich ores using handheld LIBS and PLS regression13
In situ Rb/Sr dating of potassium salt minerals (sylvite and carnallite) by 157 nm LA-ICP-MS/MS13
Insights into the role of transition and noble metals mediating photochemical vapor generation13
Strategies to enhance figures of merit in ICP-ToF-MS13
Contents list13
Atomic spectrometry update: review of advances in atomic spectrometry and related techniques13
Isoclock: a free and novel routine for common Pb correction in U–Th–Pb data reduction of LA-ICP-MS analysis13
A Pb-free Sn–Bi alloy mount preparation method for secondary ion mass spectrometry (SIMS) analyses12
A novel LIBS method for quantitative and high-throughput analysis of macro- and micronutrients in plants12
Apatite MAP-3: a new homogeneous and low common lead natural reference for laser in situ U–Pb dating and Nd isotope analysis12
A portable smartphone platform with FeNPs@g-C3N4 nano-enzyme for visual and on-site sensing of F and Al3+ in tea12
Accuracy enhancement of laser-induced breakdown spectroscopy using a combination of a confinement ring and quadrupole discharge arc12
Correction: Quantification of ferric iron content in minerals via the STEM-EELS-mapping method12
Enhancing soil geographic recognition through LIBS technology: integrating the joint skewness algorithm with back-propagation neural networks12
Elemental composition analysis of electronic waste using neutron-based analytical techniques: a novel approach to assessing environmental and resource recovery potential12
Multiple-element analysis of coal using collinear double-pulse laser-induced breakdown spectroscopy12
New natural garnet reference materials for determining the oxidation state of iron in garnet using the electron microprobe flank method11
Exploratory studies on total reflection X-ray fluorescence spectrometry combined with slurry sampling for the multi-element analysis of copper-nickel sulfide ore11
Interference-free electron probe micro-analysis of bromine in halogen-bearing minerals and glasses: high-resolution measurements and quantitative elemental mapping11
PRECISE IN SITU 87 RB- 87 SR DATING OF TERRESTRIAL AND EXTRATERRESTRIAL SAMPLES WITH THE NU SAPPHI11
A novel (NH4)2HPO4–LiBO2 fusion technique for bulk silicate rock analysis by laser ablation-inductively coupled plasma-mass spectrometry11
Magneto-electrical fusion enhancement of LIBS signals: a case of Al and Fe emission lines' characteristic analysis in soil11
Inside front cover11
A novel approach for the determination of exchangeable copper in serum using protein precipitation11
Difficulties and artefacts in cryo-fixation of ovarian tissues for X-ray fluorescence analyses11
A two-step chromatographic purification method for Ni for its isotopic analysis by MC-ICP-MS11
Innovative sample preparation method using a conductively heated digestion system for trace element analysis of radioactive oil sludge by ICP-OES11
Studying the degradation of bulk PTFE into microparticlesviaSP ICP-MS: a systematically developed method for the detection of F-containing particles11
Recent advances in micro-XANES application in biology at the TwinMic beamline11
A novel chemical purification method for accurate Sn isotope measurement by MC-ICP-MS10
Brama: a new freeware Python software for reduction and imaging of LA-ICP-MS data from U–Pb scans10
Inside front cover10
Rapid, accurate, and reagent-free determination of chlorine concentration in glass by femtosecond LA-ICP-MS/MS with a scanning galvo mirror system using hydrogen as reaction gas10
TrCSL: a transferred CNN-SE-LSTM model for high-accuracy quantitative analysis of laser-induced breakdown spectroscopy with small samples10
Particle generated spectral interferences in single particle ICP-MS: a roadblock to accurate nanometrology10
On a single method for determining As and Hg in dietary supplements by CVG-MIP OES: optimization of the multimode sample introduction system10
A comparison of calibration strategies for quantitative laser ablation ICP-mass spectrometry (LA-ICP-MS) analysis of fused catalyst samples10
Determination of polysulfide anions and molecular sulfur via coupling HPLC with ICP-MS10
Front cover10
Combining a physics-informed broad learning system and multimodal spectral fusion for accurate analysis of chromium speciation in tailings10
Multi-information fusion of characteristic spectral lines for enhanced quantitative accuracy in laser-induced breakdown spectroscopy10
Doppler-free ablation fluorescence spectroscopy of Ca for high-resolution remote isotopic analysis10
A lab-based micro-X-ray fluorescence spectrometer with high photon flux and spatial resolution for ancient ceramic research10
Long-term reproducibility detection method for quantitative LIBS using Kalman filtering10
Fundamental studies of laser ablation ICPMS using a nitrogen plasma source and helium, argon and nitrogen as carrier gas10
Contents list10
Contents list10
Effects of laser-focusing geometry on underwater laser ablation and LIBS measurement of a submerged target10
Synthesis of a new olivine reference material by a novel method for in situ iron and magnesium isotope analyses using laser ablation MC-ICP-MS10
Front cover10
Asymmetric Rowland circle geometries for spherically bent crystal analyzers in laboratory and synchrotron applications10
Dolomite reference material synthesized by pressureless sintering for laser ablation MC-ICP-MS carbon and magnesium isotope analysis9
LA-ICP-MS/MS-based Rb–Sr isotope mapping for geochronology9
Uranium enrichment measurements using tunable laser spectroscopy coupled with fiber-optic laser-induced breakdown spectroscopy9
Automated analysis of natural variations in isotopes of silicon by the thermal decomposition of BaSiF 69
Improved alkaline fusion method for B isotope and concentration measurements of silicate materials9
Automated detection of element-specific features in LIBS spectra9
Challenges in measuring nanoparticles and microparticles by single particle ICP-QMS and ICP-TOFMS: size-dependent transport efficiency and limited linear dynamic range9
A new potential synthetic pyrrhotite reference material for Fe–S isotope microanalysis9
Combined effect of borohydride hydrolysis and chemical additives on lead determination by CVG in the presence of transition metals9
Quantitative analysis of Cu, Zn, and Pb elements in ores by X-ray fluorescence using a hierarchical convolutional network with attention excitation9
Inside back cover9
Layer-resolving ability and model analysis of LIBS for multilayer samples with a four-layer structure under different focusing conditions9
Calcite TLM and LSJ07 – two natural low-Sr reference materials for microbeam Sr isotope analysis9
A review of spectral broadening in laser atomic absorption spectroscopy9
High throughput laser ablation ICP-MS bioimaging of silver distribution in animal organisms and plant tissue after exposure to silver sulfide nanoparticles9
ICP-OES determination of major and trace composition of gadolinium(iii) oxide crystals doped with europium9
A community-led calibration of the Zr isotope reference materials: NIST candidate RM 8299 and SRM 31699
Evaluating accuracy improvements of laser ablation ICPMS element analysis in silicate glasses and carbonates via downhole fractionation correction – an old problem re-assessed9
Contents list9
PXCG-1 and PXCG-2: two reference materials for gypsum U–Th dating9
Investigating the sensitivity difference of gaseous and particulate carbon in two-phase sample transport in LA-ICP-MS9
Development of two novel natural calcite reference materials for enhanced in situ elemental and Sr isotopic analysis9
Quantitative analysis of Fe 3+ /ΣFe in silicate glasses based on XPS Fe 3p core-level spectroscopy9
A data-driven, post-acquisition quality diagnostic pipeline for isotope analysis by MC-ICP-MS9
Investigating the influence of spatial confinement on self-absorption effects in laser-induced breakdown spectroscopy9
Assessment of matrix effects in boron isotope analysis using 257 nm fs-LA and 193 nm ns-LA-MC-ICP-MS with new tourmaline reference materials8
High-precision measurement of Sn isotopic compositions in cassiterite and igneous rock reference materials by double-spike technique using MC-ICP-MS/MS8
Highly resolved detection of deuterium at atmospheric pressure8
Influence of key parameters on signal quality in double-pulse laser-induced breakdown spectroscopy (DP-LIBS)8
Towards the best total consumption infrared-heated sample introduction system for nanoparticle measurement using single particle inductively coupled plasma mass spectrometry8
First demonstration of in situ Lu–Hf dating using LA-ICP-MS/MS applied to monazite8
Optimization of laser-induced breakdown spectroscopy for Be element detection with self-absorption effect correction8
Integration of capillary vibrating sharp-edge spray ionization as a nebulization device for ICP-MS8
Deep spectral feature fusion network combined with attention mechanism to predict heavy metal elements in soil by XRF8
Atomic spectrometry update: review of advances in X-ray fluorescence spectrometry8
Combination of the internal standard and dominant factor PLS for improving long-term stability of LIBS measurements8
Investigating the potential of methyl fluoride cell gas for radionuclide interference removal and measurement using ICP-MS/MS8
A miniaturized microplasma excitation source coupled with photochemically induced volatile species generation as a cost-effective tool for in situ mercury pollution analyses8
Classification of uneven steel samples by laser induced breakdown spectroscopy based on a Bessel beam8
A comprehensive chromatographic method for sequential separation of Pb, Rb, Sr, Nd, Sm, Lu, U, and Hf for high-precision isotope analysis of micro-sized silicate samples8
Front cover8
Determination of thallium isotopic composition through MC-ICP-MS with mass bias corrected using admixed W8
Ultra-sensitive determination of mercury in flue gas by atmospheric pressure glow discharge atomic emission spectrometry coupled with gold amalgam enrichment8
Operando laboratory XAS on battery materials using the DANOISE cell in a von Hámos spectrometer8
Quantitative elemental mapping of chondritic meteorites using laser ablation-inductively coupled plasma-time of flight-mass spectrometry (LA-ICP-TOF-MS)8
Front cover8
Filament induced breakdown spectroscopy with enhanced excitations from plasma gratings8
Contents list8
Novel calibration approach for particle size analysis of microplastics by laser ablation single particle-ICP-MS8
Determination of REEs in permanent magnets and their production chain using ICP-MS8
An efficient and stable sample preparation and calibration strategy for nanoparticle analysis using laser ablation single particle-ICP-MS8
Accurate determination of trace silver in geological reference materials by inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS)8
High-precision MC-ICP-MS measurements of Cd isotopes using a novel double spike method without Sn isobaric interference8
AC needle-to-needle bare electrode discharge with nebulized sample injection for elemental analysis8
Improving quantitative analysis of cement elements in laser-induced breakdown spectroscopy through combining matrix matching with regression8
A MnO 2 –Co 3 O 4 –CaO catalytic pyrolysis meth8
Enhancement of LIBS plasma and efficient collection of emitted light by open smooth triangular cavities8
A deep spectral prediction network to quantitatively determine heavy metal elements in soil by X-ray fluorescence8
LIBS analysis of elemental carbon and fixed carbon in coal by dual-cycle regression based on matrix-matched calibration8
Kinetic analysis of boron therapeutics in head and neck cancer cells by complementary bulk ICP-MS and single-cell (scICP-MS) approaches8
Atomic spectrometry update: review of advances in the analysis of clinical and biological materials, foods and beverages8
On-line vacuum degree monitoring of vacuum circuit breakers based on laser-induced breakdown spectroscopy combined with random forest algorithm8
Comparison of different mass bias correction procedures for the measurement of mercury species-specific isotopic composition by gas chromatography coupled to multicollector ICP-MS8
Quantitative imaging of fluorine in human teeth by cryogenic laser ionization time-of-flight mass spectrometry8
A new reference material for O–Sr isotope determination in epidote using a micro-beam8
Decoding the interfering L-lines by artificial neural network-based modeling for direct analysis of lanthanides in water samples using total reflection X-ray fluorescence spectrometry7
Highly accurate classification of herbals relying on toxic elements via laser-induced breakdown spectroscopy and chemometrics7
Development of gold reference materials for in situ Ag isotopic analysis7
Real-time elemental analysis of liquids for process monitoring using laser-induced breakdown spectroscopy with a liquid wheel sampling approach7
Partial matrix matching multi-energy calibration for direct quantification of Al, Fe, Li and Si in spodumene by laser-induced breakdown spectroscopy7
Determination of trace arsenic using noble metal-free Ni 2 P/CdS composites for photochemical vapor generation for sample introduction into ICP-MS7
Rapid isotopic analysis of uranium particles by laser ablation MC-ICP-MS7
Trace xenon detection in ambient helium by double-pulse laser-induced breakdown spectroscopy7
Influence of ambient pressure on spatial–temporal evolution of local thermodynamic equilibrium for laser-induced plasma7
A Gaussian spot overlap ablation model for prediction of aluminium alloy spectral peak intensity in high pulse repetition frequency LIBS7
Mechanism of elemental fractionation during femtosecond laser ablation revealed by high-time-resolution MC-ICP-MS analysis of 208Pb/232Th ratios in single particles7
Contents list7
K, Mg, and Ca isotopic analysis from a single aliquot of thirteen biological certified reference materials7
Spectral enhancement and quantitative accuracy improvement of trace metal elements in aqueous solutions using electrostatic-assisted laser-induced breakdown spectroscopy7
Laser-induced breakdown spectroscopy (LIBS) of LPBF-fabricated alloy steel: effect of surface roughness and the laser–material interaction mechanism7
Single-particle isotope ratio analysis of lanthanide-doped microplastics using inductively coupled plasma time-of-flight mass spectrometry7
High-precision lithium isotopic analysis using the Nu Sapphire MC-ICP-MS7
External electric field assisted laser-induced plasma and bubble dynamics for optimizing Mn 2 O 3 7
Wavefront-enhanced laser-induced breakdown spectroscopy (WELIBS) utilizing a crystalline silicon wafer for a flat-top IR laser beam7
Precise analysis of sub-ppm trace elements in olivine by LA-ICP-MS and application to metamorphic olivine from serpentinite7
Back cover7
Synthesis of molybdenite reference materials for in situ molybdenum and sulfur isotope measurement using laser ablation MC-ICP-MS7
Contents list7
A physical modification and spectrum-image fusion dual-dimensional method for coal analysis using LIBS7
Contents list7
Classification of gaseous UF6 assay by femtosecond LIBS in the 424.4 nm spectral region using numerical HOGSVD-DTW features7
Evaluation of microwave-assisted digestion methods for ID-ICP-MS characterization of KRISS lake sediment CRM 109-05-0027
Simultaneous analysis of the chemical composition and surface flatness of steel using laser-induced breakdown spectroscopy combined with a multi-task convolutional neural network7
A newly characterized natural sphalerite reference material (IGGSph-1) for in situ S and Zn isotope microanalysis7
Two new barite reference materials for SIMS sulfur isotope analysis: evaluation of the crystallographic orientation effect and homogeneity7
Determination of ultralow iridium concentration in small geological samples using isotope dilution coupled with multiple ion counting inductively coupled plasma mass spectrometry7
90Sr bioassay in small-volume urine by ICP-MS/MS with CO2 as the reaction gas7
Chemical vapour generation assisted by Cr3+/KCN coupled to atomic fluorescence spectrometry for ultrasensitive determination of cadmium in water and rice samples7
Evaluations of the optimal plasma treated area in total reflection X-ray fluorescence analysis and the retention period of superhydrophilic ability of the substrate7
Flow techniques in the analysis of biological samples by inductively coupled plasma mass spectrometry – a review7
Spectral correction study to reduce the influence of sample surface morphology on laser-induced breakdown spectroscopy7
Catching up on calibration-free LIBS7
Calibration and application of a large-scale LIBS project based on transfer learning in the online quantitative analysis of coal7
Back cover7
Multi-channel dilution analysis7
High-precision Fe isotope analysis for low contents using a Nu Sapphire instrument7
Preparation of rutile reference materials for in situ elemental and Hf–Ti isotopic microanalysis using spark plasma sintering7
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