Organometallics

Article	Citations
Issue Editorial Masthead	65
Strong Be–Be Covalent Bond in Be2L2 and Na2Be2L2 Molecules with Cyano-Based Ligands	52
Bis(Tetrathiafulvalenes) with Mixed Phosphine and Silane Double Bridges	50
Tetradentate Platinum(II) Complex with a 6/5/7 Metallocycle	49
Issue Publication Information	44
Issue Editorial Masthead	41
Synthesis, Reactivity, and Theoretical Insights of Co-Sb2 and Co-Bi2 Rings	38
Production of Methane by Catalytic Decarboxylation of Methyl Formate as a Liquid Surrogate	33
Solid-State Phosphine Ligand Engineering via Postsynthetic Modification of Amine-Functionalized Metal–Organic Frameworks	33
Optimizing the Cation Binding Pocket in Nickel Phenoxyimine Catalysts Improves Ethylene Polymerization Efficiency	32
Mixed Methyl/Chlorido Yttrium(III) Complexes Supported by a Neutral Tridentate N-Donor Ligand	31
Influence of the Counterion on the Activation of Nickel(σ-Aryl) Precatalysts	31
Ligand Substitution, Catalyst Activation, and Oxidative Addition Studies of a Stable Dialkyl Palladium Precatalyst	31
Formation of Homoleptic Zirconium and Hafnium Dithiocarbamates via Insertion of CS2: Breaking Bonds and Taking Names	31
Thermally Stable Rare-Earth Metal Complexes Supported by Chelating Silylene Ligands	30
Ruthenium-Catalyzed Formic Acid/Formate Dehydrogenation and Carbon Dioxide/(bi)carbonate Hydrogenation in Water	29
C^N^N Coordination Accelerates the iClick Reaction of Square-Planar Palladium(II) and Platinum(II) Azido Complexes with Electron-Poor Alkynes and Enables Cycloaddition with Terminal Alkynes	28
Synthesis of Carboxylic Acids via Reaction of Ketones/Aldehydes with CO2 and H2	28
Regioselective Dehydrogenation of the Secondary Amine Complexes into Imine Complexes under Visible-Light Irradiation	27
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Iron Pivalate Complexes Containing PNN Pincer Ligand: Synthesis and Application to Dehydrogenative Hydrosilane Coupling	25
Pt(II), Pd(II), and Ni(II) Complexes with Tridentate Cyclometalating Five- and Six-Ring Chelating N^C*N, C^N*N, and N*C*N Quinolinyl Ligands	24
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Site-Selectivity of C(sp2)–H Oxidative Addition of Fluorinated Arenes with Pyridine(dicarbene) Cobalt(I) Complexes and Aryl Isomerization	24
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Flash Communication: Rearrangement of a tris-Carbene Ligand Precursor to an all-N-Bound tris-Imidazole Iron Complex: Flipping the Umbrella	23
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Silver(I)-Catalyzed Stereochemical Isomerization of Cyclopropanols	23
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Computational Insights into the Effect of Ligand Redox Properties on Reductive Elimination from Au(III), Pd(II), and Pt(II) Complexes	21
A Zirconium Complex Bearing an [NPN] Tridentate Ligand Composed of Dibenzophosphole and Pyrrolide Moieties: Synthesis, Structure, and Ethylene-Polymerization Ability	21
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Thermodynamic–Kinetic Comparison of Palladium(II)-Mediated Alcohol and Hydroquinone Oxidation	21
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Issue Editorial Masthead	20
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Pioneers and Influencers in Organometallic Chemistry: A Profile of Dr. Barbara Burger	20
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Amidinate- and Dithiolene-Based Silicon Complexes	20
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Effect of the Dihedral Angle of Biaryl-Bridged Bis(N-Heterocylic Carbene) Ligands on Enantioselectivity in Pd-Catalyzed Asymmetric Aryl–Aryl Cross-Coupling	19
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Nickel-Catalyzed Arylation/Lactonization Cascade Reactions for the Synthesis of Bicyclo[3.2.1]lactones	18
Pierre Dixneuf: A Pioneering Career in Organometallic Chemistry Highlighting Ruthenium as a Star Metal in Homogeneous Catalysis	18
σ3/σ5-P Tautomerism and Coordination Behavior of α,α-Dialkyl-2-(diphenylphosphino)benzenemethanols	18
Issue Editorial Masthead	18
Issue Editorial Masthead	18
A Strategy to Conjugate Bioactive Fragments to Cytotoxic Diiron Bis(cyclopentadienyl) Complexes	18
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Oxidative Addition of Alkyl Iodides to [Sn(NMe2)2]2: In Situ Generation of RSn(NMe2)3 Compounds	18
Synthesis, Structural Studies, and Application of Aluminum Aryloxides for Ring-Opening Metathesis Polymerization	18
Making 2022 Picture Perfect	18
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Issue Editorial Masthead	17
Flash Communication: Mononuclear Metallacycle Mechanism in Binuclear Cr/PNCNP Catalyst May Trigger the Switch from Ethylene Trimerization into Tetramerization	17
The Curious Case of [AnH(NR2)3] (An = Th, U; R = SiMe3): Two Monomeric Actinide Hydrides Revisited	17
Issue Editorial Masthead	17
Tolman Electronic Parameter Predictions from a Machine Learning Model Provide Insight into Phosphine Ligand Electronic Effects	17
Issue Publication Information	17
The Effect of Pyridine-2-thiolate Ligands on the Reactivity of Tungsten Complexes toward Oxidation and Acetylene Insertion	17
Photoinduced Perfluoroalkylation Mediated by Cobalt Complexes Supported by Naphthyridine Ligands	17
Group 11 Bis(alumanyl)metallates	17
Isolation and Characterization of Sulfonium-Ylide-Stabilized Palladium Carbenes	16

Multiple C–B Bond Cleavage Reactions at [BArF4]− Anions Mediated by Terphenyl Phosphine Gold Catalysts	16
Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems	16
Ylide-Functionalized Phosphine (YPhos) Platinum Complexes: Synthesis and Application in Hydrosilylations under Mild Conditions	16
Ruthenium Complexes Bearing a Tetradentate Hemilabile Ligand: Synthesis, Structure, Hemilabile Feature, and Catalytic Application to C–H Borylation of Unactivated Arenes	16
B–H Bond Activation in a Rh(III) Hydrido Borohydride Complex [Rh(H)(K2-BH4)tBu4(PNCNP)] Gives a Rh(I) σ-Dihydrogen Complex [Rh(η2-H2)	16
Isolation of a [Fe(CO)4]2–-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5 with Uranium(III)	16
Structure and Conjugation Study of Organometallic [4]Radialenes of Group 4 Metallocenes. Synthesis of Zirconium [4]Radialene	16
Alkynylated Palladium(II) and Platinum(II) Acyclic Diaminocarbene Complexes and Their Intramolecular Cyclization via trans-Chlorometalation	16
Impact of the N-Heterocyclic Carbene (NHC) Ligand on the trans-[Pd(NHC)(NH2nBu)Cl2] Precatalyst Architecture in C–N Bond-Forming Reactions	16
C(sp2)–X (X = Cl, Br, and I) Reductive Eliminations from Well-Defined Gold(III) Complexes: Concerted or Dissociation Pathways?	16
Boron-Mediated C–C and C≡N Bond Cleavage of Acetonitrile: Matrix Infrared Spectra and Theoretical Calculations	16
Mono- and Dinuclear Binding Modes of the 2,5-Bis(α-pyridyl)pyrrolate Ligand in Platinum(II) Complexes	15
Ligand-Induced Regioselectivity in Metal-Catalyzed Aryne Reactions Using Borylaryl Triflates as Aryne Precursors	15
Technetium Hydrides Revisited: Syntheses, Structures, and Reactions of [TcH3(PPh3)4] and [TcH(CO)3(PPh3)2]	15
Synthesis of Triarylmethanes via Palladium-Catalyzed Suzuki–Miyaura Reactions of Diarylmethyl Esters	15
Cycloaddition and C–S Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Alkynes and Phenyl Isothiocyanate	15
Fe-Promoted C–F Activation of Aryl Fluorides Enables Heck-Type Coupling with Alkenes and One-Pot Synthesis of Indenes	15
An Exploration of the Acid-Catalyzed Interconversion of Mo(NAr)(CR1R2)(OR)2 Complexes and Their Mo(NAr)(Olefin)(OR)2 Isomers (Ar = 2,6-i-Pr2C6H3	15
The Effect of Symmetric and Asymmetric NHCs on the Structure and Catalytic Properties of Dialkylgallium Alkoxides in the Ring-Opening Polymerization of rac-Lactide—Linking the Structure, Activi	15
Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO2 with Catecholborane	15
Application of a Stable and Soluble Dibenzylbarium Reagent in the Synthesis of a Barium Imido Cluster	15
Pathways to Metal–Ligand Cooperation in Quinoline-Based Titanium(IV) Pincers: Nonelectrophilic N-methylation, Deprotonation, and Dihydropyridine Formation	15
Upgrading of Ethanol to n-Butanol via a Ruthenium Catalyst in Aqueous Solution	15
Isolation and Characterization of Elusive Tetrabenzylthorium Complexes	15
Unsymmetrical Naphthyridine-Based Dicopper(I) Complexes: Synthesis, Stability, and Carbon–Hydrogen Bond Activations	15
High-Throughput Approach in the Ring-Opening Polymerization of β-Butyrolactone Enables Rapid Evaluation of Yttrium Salan Catalysts	15
Synthesis, Characterization, and Structural Transformation of Picolyl-Functionalized Polynuclear Silver(I)– and Gold(I)–N-Heterocyclic Carbene Complexes	15
Mechanisms of the Ruthenium Sulfur Complex in Generation and Stabilization of Silicon and Aluminum Electrophiles for C(sp3)–F Bond Activation	15
Directing Selectivity to Aldehydes, Alcohols, or Esters with Diphobane Ligands in Pd-Catalyzed Alkene Carbonylations	15
U–C Bond Insertion, Ring-Opening, and C–H Activation in a Uranium Bis(diisopropylamino)cyclopropenylidene (BAC) Adduct	15
Redox Chemistry of an End-Deck cyclo-As3 Nickel Complex	14
Gold-to-Boron Aryl Transfer from a T-Shaped Phosphine–Borane Gold(I) Complex	14
Synthesis of Aluminum Complexes Stabilized by Amine-Bridged Tris(phenolato) Ligands and Their Applications in the Cycloaddition Reaction of CO2 and Epoxides	14
Polymerization of Racemic 2,2′-Dialkyl-Sila[1]ferrocenophanes: DFT-Assisted Polymer Analysis by 29Si NMR Spectroscopy Using Model Compounds	14
Cyclopentadienone Iridium Bipyridyl Complexes: Acid-Stable Transfer Hydrogenation Catalysts	14
Synthesis of an Indazole/Indazolium Phosphine Ligand Scaffold and Its Application in Gold(I) Catalysis	14
Access to a Variety of Ge(II) and Sn(II) Compounds through Substitution of Hypersilyl Moiety	14
Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners	14
Ru-Catalyzed Site-Selective Aliphatic C–H Bond Silylation of Amides and Carbamides	14
Synthesis, Structure, and Magnetic Properties of Rare-Earth Benzoborole Complexes	14
Synthesis, Structures, and Reactivity of Diazabutadiene-Ligated Rare-Earth Radical Complexes Bearing Adaptable Auxiliary Ligands	14
Controlled Activation of Dipicolinyl-Substituted Propargylic Alcohol by Ru(II) and Os(II) for Unprecedented Indolizine-Fused Metallafuran Complexes	14
Chromium-Catalyzed Borylative Coupling of Aliphatic Bromides with Pinacolborane by Hydrogen Evolution	14
Synthesis and Surface Attachment of Molecular Re(I) Hydride Species with Silatrane Functionalized Bipyridyl Ligands	14
Mechanism and Selectivity Investigation of [Cu]/[Pd] Synergistic Catalyzed Borylfluoroallylation of Alkyne: A DFT Study	14
Three-Coordinate Halide and Methyl Complexes of Chromium, Manganese, Iron, Cobalt, and Nickel Enabled by an Imidazolin-2-iminato Ligand	14
Thermal Dehydrogenation and Hydrolysis of BH3NH3 Catalyzed by Cyclic (Alkyl)(amino)carbene Iridium Complexes under Mild Conditions	14
Benzylnickel(II) Complexes of 2-Iminopyrrolyl Chelating Ligands: Synthesis, Structure, and Catalytic Oligo-/Polymerization of Ethylene to Hyperbranched Polyethylene	14
Zinc Hydride-Catalyzed Dihydroboration of Isonitriles and Nitriles: Mechanistic Studies with the Structurally Characterized Zinc Intermediates	14
Latency and Immobilization in Silicone Resin by (NHC)Pt(dvtms) Complexes through a Partially Self-Consuming Ligand	13
Synthesis of a Tetraphenyl-Substituted Dihydropentalene and Its Alkali Metal Hydropentalenide and Pentalenide Complexes	13
Syntheses of Rare-Earth Metal Alkyl Complexes Bearing a Dianionic α-Iminopyridyl Ligand and Their Catalytic Activities toward Polymerization of 2-Vinylpyridine	13
Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines	13
Chirality Transfer of Stereogenic Boron Centers Enabled by a SN2-Type Mechanism	13
Azacycle-Directed Formal Aromatic C(sp2)–H Insertion with Cr(0) Fischer Carbene Complex via Oxidative Hydrogen Migration	13
Linear Gold(I) Halide Complexes with a Diamidocarbene Ligand: Synthesis, Reactivity, and Phosphorescence	13
Regioselective Diels–Alder Reactions of C70 Directed by Endohedral Ca and Th Atoms	13
Mapping Out the Role of σ-Silane Complexes in the Ruthenium-Catalyzed Hydrosilylation of Nitriles	13
Synthesis of Molybdenum Dihapto Carbon Dioxide Complexes via Oxidation of a Carbonyl Ligand	13
Examining the Modular Synthesis of [Cp*Rh] Monohydrides Supported by Chelating Diphosphine Ligands	13
The Challenging Reaction of Cyclopropenones with Benzamide Catalyzed by Rh(III): A Computational Study	13
Role of TMEDA in Iron-Catalyzed C(sp2)–C(sp3) Cross-Coupling Reactions: A Mechanistic Study Using DFT Calculations	13
Deracemization of Chiral-at-Ruthenium Catalyst by Diastereoselective Dynamic Resolution	13
Alkyllithium Reagents as a Hidden Source of Lithium Hydride	13
Photoluminescence of a Platinum(II) Complex Containing Multiresonance B–N Motif in the Cyclometalated Ligand	13
Experimental and Theoretical Investigation of Ion Pairing in Gold(III) Catalysts	13
Iron(II)-Catalyzed Activation of Si–N and Si–O Bonds Using Hydroboranes	13
Synthesis of Si(IV)- and Ge(II)-Substituted Amines, Hydrazone, and Hydrazine from Hypersilyl Germylene	13
Diruthenium Complexes with π-Extended Bridging Bis(alkenyl)arylene Ligands, A Derived Metallamacrocycle, and Their Oxidized Forms	13
Reversible C–C Double Bond Cleavage to Form a Metal Carbene and an Alkene Enabled on an Iridium Complex Bearing a Pincer-type Alkoxycarbene Ligand	13
Conjugated Building Blocks Based on Electron-Deficient Thiaborin S-Oxides	13
Synthesis and Structure of a Dimeric Yttrium Complex [LSi(BH3)(C5Me4)Y(CH2SiMe3)2]2 (L = PhC(NtBu)2) and	13
Bis(phenoxy-imine) Alkaline–Earth Complexes with Competing Binding Pockets	13
Pyrrole-Based Ti(III) and Ti(IV) PNP Pincer Complexes: Insertion of Ketones into the Ti(IV)-Phosphorus Bond	13
Light-Promoted Transfer of an Iridium Hydride in Alkyl Ether Cleavage	13
Reactions of Nickel(0)–Olefin Pincer Complexes with Terminal Alkynes: Cooperative C–H Bond Activation and Alkyne Coupling	13
NaBHT Generated In Situ from BHT and NaOtBu: Crystallographic Characterization and Applications in Buchwald–Hartwig Amination	13
Chromium(II) Alkylcyclopentadienyl Complexes with Carbon or Hydride Donor Ligands	13
Exploring the Formation of Copper–Ruthenium Bimetallic Complexes in Olefin Metathesis	13
On the Possibility of Using Aza-Cryptands to Design Superalkalis	12

Reversible C–H Activation in Zirconaaziridine Species: Characterization and Bonding of a Bridging (Amino)alkylidene Complex Active in Alkyne Hydroaminoalkylation	12
Diborane Reductions of CO2 and CS2 Mediated by Dicopper μ-Boryl Complexes of a Robust Bis(phosphino)-1,8-naphthyridine Ligand	12
[{SiNDipp}MgNa]2: A Potent Molecular Reducing Agent	12
Silyl(silylene) Coinage Metal Complexes Obtained from Isolable Cyclic Alkylsilylenes	12
Synthesis and Alkyne Metathesis Activity of Pincer Rhenium Carbyne Complexes	12
Two-Stage Catalysis in the Pd-Catalyzed Formation of 2,2,2-Trifluoroethyl-Substituted Acrylamides: Oxidative Alkylation of PdII by an IIII Reagent and Roles for Acetate, Triflate	12
Ni-Catalyzed Larock Indenone Annulation with Aliphatic- and Silyl-Substituted Alkynes Supported by Mechanistic Analysis	12
What is a Sandwich Complex?	12
Zn Metal–Organic Framework with High Stability and Sorption Selectivity for CO2	12
Redox-Inactive Cation Assisted Direct Productions of Oxalic Acid and Dimethyl Oxalate via Oxidative CO Coupling Catalyzed by Coplanar Dicobalt Complexes	12
In Silico Investigation of Ligand-Regulated Palladium-Catalyzed Formic Acid Dehydrative Decomposition under Acidic Conditions	12
Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand	12
Carbene Character in a Series of Neutral PCcarbeneP Cobalt(I) Complexes: Radical Carbenes versus Nucleophilic Carbenes	12
Dissimilarity in the Chemical Behavior of Osmaoxazolium Salts and Osmaoxazoles: Two Different Aromatic Metalladiheterocycles	12
Synthesis and Bond Activation Chemistry of Palladium(II) Pincer Complexes with a Weakly Coordinating Side Arm	12
H2 Activation across Manganese(I)–C Bonds: Atypical Metal–Ligand Cooperativity in the Aromatization/Dearomatization Paradigm	12
Nickel-Catalyzed N-Arylation of Diarylamines for Triarylamine Synthesis	12
Cyclometalated Iron and Ruthenium Complexes Supported by a Tetradentate Ligand Scaffold with Mixed O, N, and C Donor Atoms: Synthesis, Structures, and Excited-State Properties	12
Noninnocent Behavior of a (3-Imino)indol-2-yl Ligand in Metal Complexes	12
Is Mn(I) More Promising Than Fe(II)─A Comparison of Mn vs Fe Complexes for Olefin Metathesis	12
Organoboron Derivatives of 1,8-Bis(dimethylamino)naphthalene: Synthesis, Structure, Stability, and Reactivity	12
Synthesis and Characterization of N,N,C and N,N,O Tridentate β-Diketiminato Rare-Earth Metal Alkyl Complexes and Their Catalytic Performances on the Dimerizat	12
Six-Membered Iridacycles with Five Nitrogen Atoms in the Ring	12
Spectroscopic Characterization of Heterohalogenic Dihalomethylzinc Carbenoids: Application to a More Efficient Chlorocyclopropanation Reaction	12
Vertex-Fused Clusters Featuring a Flattened Butterfly	12
Catalyst Design for Rh-Catalyzed Arene and Alkane C–H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp	12
Role of Solvent Coordination on the Structure and Dynamics of ansa-Zirconocenium Ion Pairs in Aromatic Hydrocarbons	12
Ionic Cyclopropenium-Derived Triplatinum Cluster Complex [(Ph3C3)2Pt3(MeCN)4]2+(BF4–)2: Synthesis, St	12
Coordination of E–C Bonds (E = Zn, Mg, Al) and the Zn–H Bonds of (C5Me5)ZnH and (C5Me5)ZnZnH across a Quadruply Bonded Dimolybdenum Dihydride Complex	11
A Theoretical Study of Unsupported Uranium–Ruthenium Bonds Based on Tripodal Ligands	11
Theoretical Study of Rhodium-Catalyzed Dual C–H Activation to Synthesize C–N Axially Chiral N-Aryloxindoles: Origin of Axial Chirality	11
Epoxide Hydrogenolysis Catalyzed by Ruthenium PNN and PNP Pincer Complexes	11
Metal-Rich Fused Clusters: Syntheses, Structures, and Bonding of Heteronuclear Condensed Metallaboranes	11
Racemic and Meso Diastereomers of a P-Chirogenic Diboranyldiphosphinoethane	11
Multisite Ligand Noninnocence of (CpN3)Fe(CO)3+ with Exogenous Hydride Donors: Kinetics and Mechanism	11
Synthesis, Characterization, and Reactivity of Thioether-Ligated Organoiron(II) Complexes	11
Group 4 Metallocene Complexes Supported by a Redox-Active O,C-Chelating Ligand	11
A Ruthenium Protic N-Heterocyclic Carbene Complex as a Precatalyst for the Efficient Transfer Hydrogenation of Aryl Ketones	11
Nitrene-Transfer Chemistry to C–H and C═C Bonds Mediated by Triangular Coinage Metal Platforms Supported by Triply Bridging Pnictogen Elements Sb(III) and Bi(III)	11
Pentamethylcyclopentadienyltrimethylgermane: A Nontoxic Entry to Mid-Valent Monopentamethylcyclopentadienylvanadium Chloride Complexes	11
Protonolysis of the [B(ArF)4]− Anion Mediated by Nucleophile/Electrophile/Water Cooperativity in a Platinum–PMe2OH Complex	11
Synthesis of Methylated, Hydroxylated, and Aminated Metallaaromatics via Ring-Opening Reactions of the Fused Three-Membered Ring Units	11
Investigating Reductive Elimination and Ligand Exchange Pathways from Homoleptic Lithium Nickelate Acetylide Complexes	11
Effects of Substituted Triarylphosphine Ligands on Electron Transfer in [(p-Cymene)Ru] Complexes	11
Iron-Catalyzed Activation of Carbon–Halogen Bonds	11
Diazo Decomposition and Carbene Transfer Mediated by a Pincer Gold(III) Complex	11
Density Functional Theory Studies of the Catalyst Structure–Activity and Selectivity Relationships in Rh(I)-Catalyzed Transfer C–H Borylation of Alkenes	11
MD-DFT Computational Studies on the Mechanistic and Conformational Parameters for the Chemoselective Tyrosine Residue Reactions of G-Protein-Coupled Receptor Peptides with [Cp*Rh(H2O)3	11
Ni(3,5-CF3stb)2(Et2O): A “Super-Naked” Nickel Complex	11
Solid-State Conformational Isomerism Lacking a Gas-Phase Energy Barrier: Its Structural, Spectroscopic, and Theoretical Identification in an Organochromium(III) Complex	11
Configurational Flexibility of a Triaryl-Supported SBS Ligand with Rh and Ir: Structural Investigations and Olefin Isomerization Catalysis	11
Highly Emissive Platinum(II) Complexes Bearing Bulky Phenyltriazolate Ligands: Synthesis, Structure, and Photophysics	11
Reactions of Titanium- and Zirconium-Based 1-Metallacyclobuta-2,3-diene Complexes with Diazenes: N═N Bond Cleavage versus N–C Bond Formation and Dearomatization	11
Substituent Effects and the Mechanism of Gold to Alkene Benzylidene Transfer Employing a Gold Sulfonium Benzylide Complex	11
Flash Communication: Carbon Monoxide Insertion and Ligand Modification with Pyridine(diimine) Iron Alkyl Complexes	11
Synthesis and Characterization of New Counterion-Substituted Triacylgermenolates and Investigation of Selected Metal–Metal Exchange Reactions	11
Rhodium-Catalyzed Asymmetric Dehydrocoupling-Cyclophosphination of Supermesitylphosphines: Enantioselective Synthesis of a P-Stereogenic Benzophospholane via C–H Activation–Functionalization	11
Thio-imino-tetrahydroacridine Iron Complexes for Ethylene Polymerization	11
Synthesis and Reactivity of a Dimeric Ni(I) Methyl Complex	11
Mixed Lithium–Aluminum Hydrides Bearing Ar-Bian Ligands: Reactivity Toward Heteroallenes	11
Lactide Polymerization Using Zinc Dichloride Complexes Containing a Neutral Bidentate Ligand with a Diacylated Cyclic Guanidine	10
Computational Mechanistic Elucidation of C–N Cross-Coupling Reactions via Ligand-Enabled Au(I)/Au(III) Catalysis: Insights into Y-Arylation of Y–H Bonds (Y = N, C, O, S) Under Base-Free Conditions	10
Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions	10
PCP Pincer Complexes of Titanium in the +3 and +4 Oxidation States	10
Chiral Tetra-coordinate Aluminum Cation in Catalysis	10
Combined B–H and Si–H Bond Activations at Ruthenium	10
Visible-Light Photohydrogenation of Ketones, Aldehydes, and Imines Using a Strongly Reducing Photosensitizer	10
Homoleptic Enantiopure Lanthanide Complexes: Synthesis, Structure, and Characterization	10
Comparisons of bpy and phen Ligand Backbones in Cr-Mediated (Co-)Electrocatalytic CO2 Reduction	10
C–H and H–H Bond Activation by a Cationic Germylyne Complex	10
Heteroleptic Aluminum Allyls as Initiators for Lactide Polymerization	10
Divalent Organocopper Complexes: Masked Radicals for Effective Electrochemically Driven Atom Transfer Radical Addition	10
Breaking and Entering: Diazene Cleavage and Insertion into U(III)–Si Bonds	10
Oxidative Coupling of Ruthenium Alkenyl Acetylide Complexes as a Route to Dinuclear Complexes Featuring Carbon-Rich Bridging Ligands	10
Copper-Mediated Fluoroalkylation of Aryl Bromides and Chlorides Enabled by Directing Groups	10
Reactivity of Heterobimetallic Ion Pairs in Formic Acid Dehydrogenation	10
Suzuki–Miyaura Csp2–Csp2 Cross-Couplings Employing Nickel(II) Pincer Precatalysts: Mechanistic Investigations	10
Lewis Base Activation by Uranium(III) Complexes	10
Spotlight on Ligand Effects in 1,2,3-Triazolylidene Gold Complexes for Hydroamination Catalysis: Synthesis and Catalytic Application of an Activated MIC Gold Triflimide Complex and Various MIC Gold Ch	10
Copper Complexes Supported by Iminotriazole Ligands: Effective Catalysts for the Monooxygenation of Phenols	10
Ambivalent Role of Rotamers in Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Enantioselective Ring-Opening Cross-Metathesis	10
Oxidation-Induced Ligand Swap: Oxygen Insertion into a Cobalt-Phosphine Complex	10
Steric and Electronic Properties of Phosphinimide-Based Silylenes─The Influence of the Phosphine Moiety	10
Synthesis and Characterization of Rare-Earth Metal Complexes Bearing a 2-N,N-Dimethylamino-Ethylene-Imino-Functionalized Indolyl Ligand and Their Catalytic Activities Toward Hydrosilylat	10
Kinetic and Thermodynamic Pathways in the Reactions of Five-Membered Zircona- and Hafnacyclocumulenes with Acetonitrile. Structures and Mechanisms of Formation of the Obtained Complexes	10
Synthesis and Reactivity of Redox-Active Cerium(IV) Aryloxide Complexes	10
Ni-Catalyzed Photochemial Sulfamidation of Aryl Chlorides with Soluble Organic Amine as Base	10
Evaluation of Volatility and Thermal Stability in Monomeric and Dimeric Lanthanide(III) Complexes Containing Enaminolate Ligands	10
Synthesis of Germacyclic Compounds by Cyclization and Annulation Reactions Utilizing In Situ Generated Germyl Cations	10
2,2′-Diphosphino- and 2,2′-Diarsenotolanes and Their Fe-, Co-, and Ni-Complexes: Pnictogen-Dependent Cyclization Tendencies and Metal-Dependent Stability and Reactivity Patterns	10
(Arylimido)niobium(V)–Alkylidenes as the Catalysts for Ring-Opening Metathesis Polymerization (ROMP) of Cyclic Olefins: Z-Specific ROMP of Cyclooctene by Nb(CHSiMe3)(NC6H<	10
Development of an In Situ Protocol for the Intramolecular Olefination of Oximes	10
The Role of Ligands in Oxidative Addition Chemistry of Low-Valent Main Group Derivatives: Not Only Stabilization but Also Activation	10
Di- and Trinuclear Complexes of Pd(0) and Pt(0) with Bridging Silylene Ligands: Structures with a Coordinatively Unsaturated Metal Center and Their Reactions with Alkynes	10
Synthesis and Characterization of a 1,2,4-Diazarsolide Anion	10