Organometallics

Article	Citations
Role of Solvent Coordination on the Structure and Dynamics of ansa-Zirconocenium Ion Pairs in Aromatic Hydrocarbons	83
Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems	62
Synthesis, Characterization, and Reactivity of Thioether-Ligated Organoiron(II) Complexes	51
NaBHT Generated In Situ from BHT and NaOtBu: Crystallographic Characterization and Applications in Buchwald–Hartwig Amination	42
The Challenging Reaction of Cyclopropenones with Benzamide Catalyzed by Rh(III): A Computational Study	37
Flash Communication: Carbon Monoxide Insertion and Ligand Modification with Pyridine(diimine) Iron Alkyl Complexes	36
Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions	35
Cyclometalated Iron and Ruthenium Complexes Supported by a Tetradentate Ligand Scaffold with Mixed O, N, and C Donor Atoms: Synthesis, Structures, and Excited-State Properties	34
Alkyllithium Reagents as a Hidden Source of Lithium Hydride	34
Mechanism and Selectivity Investigation of [Cu]/[Pd] Synergistic Catalyzed Borylfluoroallylation of Alkyne: A DFT Study	32
Synthesis and Bond Activation Chemistry of Palladium(II) Pincer Complexes with a Weakly Coordinating Side Arm	29
Reversible C–C Double Bond Cleavage to Form a Metal Carbene and an Alkene Enabled on an Iridium Complex Bearing a Pincer-type Alkoxycarbene Ligand	29
Groups 9 and 10 Complexes of C–Donor Ligands Derived from Pyridinium-Stabilized Phosphorus Ylides	27
Bis(Tetrathiafulvalenes) with Mixed Phosphine and Silane Double Bridges	27
Deracemization of Chiral-at-Ruthenium Catalyst by Diastereoselective Dynamic Resolution	26
Triptycepenes: Synthesis, Metal Complexes, and Their Reactivity in Catalytic Reactions	26
Impact of Halide (Cl vs I) Identity on the Preferred Positioning of Substituents between Al and M (M = Co, Rh, Ir) in PAlP Pincer Complexes	25
Nickel-Catalyzed Arylation/Lactonization Cascade Reactions for the Synthesis of Bicyclo[3.2.1]lactones	25
Synthesis and Characterization of Rare-Earth Metal Complexes Bearing a 2-N,N-Dimethylamino-Ethylene-Imino-Functionalized Indolyl Ligand and Their Catalytic Activities Toward Hydrosilylat	24
Multiple C–B Bond Cleavage Reactions at [BArF4]− Anions Mediated by Terphenyl Phosphine Gold Catalysts	24
Oxidative Coupling of Ruthenium Alkenyl Acetylide Complexes as a Route to Dinuclear Complexes Featuring Carbon-Rich Bridging Ligands	24
Influence of the Counterion on the Activation of Nickel(σ-Aryl) Precatalysts	24
Dissimilarity in the Chemical Behavior of Osmaoxazolium Salts and Osmaoxazoles: Two Different Aromatic Metalladiheterocycles	24
Formation of Bisvinylidene Complexes through Consecutive Alkyne–Vinylidene Rearrangements	24
Steric and Electronic Properties of Phosphinimide-Based Silylenes─The Influence of the Phosphine Moiety	23

Ni(3,5-CF3stb)2(Et2O): A “Super-Naked” Nickel Complex	23
Oxidative Addition of Alkyl Iodides to [Sn(NMe2)2]2: In Situ Generation of RSn(NMe2)3 Compounds	23
Making 2022 Picture Perfect	23
Reactivity of Heterobimetallic Ion Pairs in Formic Acid Dehydrogenation	22
Stereoselective Epoxidation of Unfunctionalized Aliphatic Alkenes with a Macrocyclic Tetra-NHC Iron(II) Catalyst	22
PCP Pincer Complexes of Titanium in the +3 and +4 Oxidation States	22
Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO2 with Catecholborane	22
Issue Publication Information	21
Reactions of Nickel(0)–Olefin Pincer Complexes with Terminal Alkynes: Cooperative C–H Bond Activation and Alkyne Coupling	21
Issue Editorial Masthead	21
Catalyst Design for Rh-Catalyzed Arene and Alkane C–H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp	21
Ruthenium-Catalyzed Formic Acid/Formate Dehydrogenation and Carbon Dioxide/(bi)carbonate Hydrogenation in Water	20
Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners	20
Issue Publication Information	20
Multisite Ligand Noninnocence of (CpN3)Fe(CO)3+ with Exogenous Hydride Donors: Kinetics and Mechanism	20
Carbon Monoxide-Induced Mobility of Isolated Palladium Species on Silicon Dioxide at Room Temperature	20
Issue Publication Information	20
Issue Editorial Masthead	20
Influence of Indole-N Substitution of Thiosemicarbazones in Cationic Ru(II)(η6-Benzene) Complexes on Their Anticancer Activity	20
High-Throughput Approach in the Ring-Opening Polymerization of β-Butyrolactone Enables Rapid Evaluation of Yttrium Salan Catalysts	19
Cationic Half-Sandwich Ruthenium(II) Complexes of 2-Picolyl-Based N-Arylguanidines as Catalysts for the Aldehyde–Water Shift Reaction	19
(κ3-N∩N∩N)-Palladium Pincer Complex-Catalyzed Synthesis of Quinazolin-4(3H)-Ones Through the Acceptorless Dehydrogenation Process: Experimental Results and Computational Insights	19
Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines	19
Hydroalumination of 1,8-Diethynylanthracenes–Al-based Bis-Lewis-Acids and their Isomerization and Complexation Behavior	19
Synthesis, Reactivity, and Theoretical Insights of Co-Sb2 and Co-Bi2 Rings	18
Ionic Cyclopropenium-Derived Triplatinum Cluster Complex [(Ph3C3)2Pt3(MeCN)4]2+(BF4–)2: Synthesis, St	18
Ylide-Functionalized Phosphine (YPhos) Platinum Complexes: Synthesis and Application in Hydrosilylations under Mild Conditions	18
Kinetic and Thermodynamic Pathways in the Reactions of Five-Membered Zircona- and Hafnacyclocumulenes with Acetonitrile. Structures and Mechanisms of Formation of the Obtained Complexes	18
Mechanism and Selectivity of Bi(V)-Aryl Oxyfunctionalization in Trifluoroacetic Acid Solvents	17
Amines as Activating Ligands for Phosphine Palladium(II) Precatalysts: Effect of Amine Ligand Identity on the Catalyst Efficiency	17
Synthesis and Surface Attachment of Molecular Re(I) Hydride Species with Silatrane Functionalized Bipyridyl Ligands	17
Skeletal Rearrangement of a μ–η2:η4-Hexatrienyl Ligand at a Diruthenium Site via a μ–η5-Ruthenacyclohexadienyl Intermediate	17
Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me3SiCF3 and Me3SiCF2H	17
Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates	17
Hydrogen Production via Aqueous-Phase Reforming of Ethanol Catalyzed by Ruthenium Alkylidene Complexes	17
Cytotoxicity of Ruthenium(II) Arene Complexes Containing Functionalized Ferrocenyl β-Diketonate Ligands	17
Phosphine-Mediated Cleavage of Sulfur–Sulfur Bonds	17
Mechanistic Insights into Rh-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silazanes: The Origin of Enantioselectivity	17
DFT Studies on the Early-Transition-Metal-Catalyzed Polymerization of Polar Monomers with a Methylene Spacer between Vinyl and Functional Groups	17
Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures	17
Ring-Opening Polymerization of ε-Caprolactone Utilizing Aluminum Alkyl Complexes Bearing Dianionic Scorpionate Ligands	16
Metal Identity Effects in the Pincer Complex-Catalyzed Dehydrogenative Coupling of Formamides with Alcohols to Form Carbamates	16
Catalytic Asymmetric Hydrophosphination as a Valuable Tool to Access Dihydrophosphinated Curcumin and Its Derivatives	16
Back with the Flash Communication	16
Ligand Reorganization in the Coordination Sphere of a CCC-NHC Pincer Fe Complex and Transient Absorption Spectroscopic Characterization of [(BuCiCiCBu)	16
A Contiguous Tricyclic [P6]2– Framework Spanning Across Two Vanadium(III) Centers	16
Double 1,2-Migration of Bromine and Silicon in Directed C–H Alkynylation Reactions with Silyl-Substituted Alkynyl Bromides through an Iridium Vinylidene Intermediate	16
Geometric Control of Carbon–Carbon Reductive Elimination from a Platinum(IV) Pincer Complex	16
Heterometallic Clusters with Thorium–Rhodium Bonds Supported by Double-Layer Nitrogen–Phosphorus Ligands	16
Correction to “DFT Study on the Mechanisms of Iron-Catalyzed Ortho C–H Homoallylation of Aromatic Ketones with Methylenecyclopropanes”	16

Mechanism of Perfluoro-Nickelacyclopentane Formation from Tetrafluoroethylene: Effects of Ancillary Ligand Bite Angle	16
Revisiting C–C and C–H Bond Activation in Rhodium Pincer Complexes: Thermodynamics and Kinetics Involving a Common Agostic Intermediate	16
p-Aryl-Substituted Iminopyridine Chromium Complexes as Precatalysts for Ethylene Polymerization: The Question of the Physical Oxidation State Examined by Experimental and Density Functional Stu	16
Synthesis of Benzofused O- and N-Heterocycles through Cascade Carbopalladation/Cross-Alkylation of Alkynes Involving the C–C Cleavage of Cyclobutanols	16
Metallapolycycles from the Coupling of Two Re–C Bonds	15
Ligand Modifications on a Cp(quinolate)Ru Catalyst to Improve Its Stability in a Bio-orthogonal Deprotection Reaction	15
Synthesis and Reactivity of Oxorhenium(V) Complexes Incorporating 2,6-Bis[(diphenyl)methyl]diamidopyridine (DPMDAP) Pincer Ligands as the Basic Component of Transition Metal Frustrated Lewi	15
Molecular Weight Determination of Relevant Organometallic Catalysts in Solution by DOSY-NMR to Monitor Reactivity	15
Diamidoamine Aluminum Complex as Effective Initiator for Random Copolymerization of Substituted Carbonate with L-Lactide	15
Catalytic Hydrogenation of Terminal Alkenes by a (PPP) Pincer-Ligated Cobalt(II) Complex	15
Mechanism of Nickel-Catalyzed Dual C–O Bond Activation in the Deoxygenation of Ethers via Reductive Cross-Coupling Reaction: A DFT Study	15
Photochemistry of RMn(CO)5 Complexes as Precursor Candidates for Photoassisted Chemical Vapor Deposition	15
Electrocatalytic Anaerobic Oxidation of Benzylic Amines Enabled by Ferrocene-Based Redox Mediators	15
Variable Kinetic Isotope Effect Reveals a Multistep Pathway for Protonolysis of a Pt–Me Bond	15
Flash Communication: Ir Complexes with a PhN(CH2CH2PiPr2)2 Pincer Ligand for Reversible CO2 Hydrogenation	15
Flash Communication: Density Functional Theory (DFT) Calculations Indicate an Unconventional Anagostic Complex for the Initial Stage of the Reported Sc3+ Boosted C–H Bond Activation of 3,4-	15
Substituent Effects on the Activity of Cp*Ir(pyridine-carboxylate) Water Oxidation Catalysts: Which Ligand Fragments Remain Coordinated to the Active Ir Centers?	15
Saturated NHC-Stabilized Borenium, Boronium, Hydride-Bridged Boron Cations, and a Bora-Acyl Chloride	15
Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate	14
Issue Editorial Masthead	14
Bimetallic Nickel Complexes Containing Benzotriazole-Derived Diamine-Bisphenolate Ligands as Highly Active Catalysts for the Copolymerization of Carbon Dioxide with Cyclohexene Oxide: Synthesis, Catal	14
Heteroditopic Chelating NHC Ligand-Supported CoIII Complexes: Catalysts for the Reductive Functionalization of Carbon Dioxide under Ambient Conditions	14
Synthesis and Reactivity of Dipalladated Derivatives of Terephthalaldehyde	14
Arene Insertion into the M–Cl Bond vs Addition-like Behavior of Arene and M–Cl Bond (M = Cu/Fe): A DFT Investigation of the Cu/Fe SET Mechanism of Arene sp2 C–H Chlorination	14
Carbene–Calcium Silylamides and Amidoboranes	14
The Intrinsic Barrier for N≡N Bond Cleavage or Formation Mediated by the Cp*Cr(dmpe) Fragment Is Insurmountable	14
Iron, Cobalt, and Nickel Complexes Supported by a iPrPNPhP Pincer Ligand	14
High-Temperature Solution-Phase Ethylene (Co)polymerization Catalyzed by a [O–N–P]TiBn2 Complex	14
Bifunctional Hydroboration Catalyst Activation Using a Co SNS Amido Complex Bearing an Abnormal-NHC Ligand	14
Organic Allene vs Organometallic Allene─Preference Toward Allylic Anionic Delocalization, Dative Bonding, and Tunable Reactivity	14
Carbon Nanotube-Supported Iron Complex Catalyzes 1-Hexene Dimerization	14
Divergent Approach for Tris-Heteroleptic Cyclometalated Iridium Complexes Using Triisopropylsilylethynyl-Substituted Synthons	14
Heteroleptic Bis(amido) Ca(II) and Yb(II) NHC Pincer Complexes: Synthesis, Characterization, and Catalytic Activity in Intermolecular Hydrofunctionalization of C═C Bonds	14
Issue Editorial Masthead	14
Issue Publication Information	14
CO Complexation by Ru(II) and Os(II) Porphyrin Complexes Sheds Light on the Relative Importance of Thermodynamic Stability and Kinetic Lability for CO Poisoning Antidotes	14
Issue Editorial Masthead	14
Iron–Aryloxide Complex Bearing Bis(dipyrromethene) Ligands for the Ring-Opening Polymerization of ε-Caprolactone	14
Synthesis of Mo(IV) para-Substituted Styrene Complexes and an Exploration of Their Conversion to 1-Phenethylidene Complexes	14
Hydrogen Bond Patterning and Biological Activity of Ferrocene Conjugates with Homo- and Heterochiral Ala–Pro Dipeptides	14
Methyl-Branched Polyethylene Produced by Hafnocene Complexes Exhibiting Unconventional Dialkoxy Bridges	14
Mechanistic Aspects of Rhodium-Catalyzed Isoprene Hydroformylation: A Computational Study	14
Issue Editorial Masthead	14
Detection of the BICT State in a Borafluorene with High Stokes Shift Fluorescence	13
Synthesis, Characterization, and Catalytic Reactivity of Dithiolate-Bridged Diiron Complexes Supported by Bulky Cyclopentadienyl Ligands	13
Alkaline Earth Catalyzed CO2 Hydroboration into Acetal Derivatives Leading to C–S Bond Formation	13
Controlled Polymerization of 3-Hexyne, 4-Octyne, and 5-Decyne by Nb(CHCMe2Ph)(NC6F5)[OC(CF3)3](PMe3)2 Catalyst: Structural	13
Flash Communication: Bismuthinidenes as Lewis Bases in Reversible C(sp3)–O Bond Cleavage	13
Reactions of TcI(NO) and TcVN Complexes with Alkynes and Alkynides	13
Reduction of Nitrous Oxide and Binding of Carbon Dioxide by Acenaphthene-1,2-diimine Aluminum Compounds	13
Issue Editorial Masthead	13
Pioneers and Influencers in Organometallic Chemistry: Professor John E. Ellis Takes Metals to the Limit	13
Cobalt-Catalyzed Regio- and Stereoselective Hydrosilylation of Alk-2-ynes with Tertiary Silanes	13
Cobalt-Catalyzed Alkylation of Nitriles with Alcohols	13
Synthesis and Characterization of Uranium Complexes Supported by Substituted Aryldimethylsilylanilide Ligands	13
Issue Publication Information	13
Development of Sandwich Compound-Based Planar Chiral Six-Membered NHC Ligands with Quaternary Carbon at α-Position of Nitrogen	13
N–N Double-Bond Cleavage and Azobenzene Rearrangement with C–C Bond Formation Induced by a Germylene	13
Compounds with Chelating 3-Dimethylamino-1-propyl Ligands as Chemical Vapor Deposition Precursors. Synthesis and Characterization of M[(CH2)3NMe2]2 Complexe	13
Photochemical Synthesis of Five-Membered Zirconacyclocumulene Complex and Its Reactions with Ketones	12
Computational Study on the Role of Zn(II) Z-Type Ligands in Facilitating Diaryl Reductive Elimination from Pt(II)	12
Singlet Spin State Drives [V]-Carbene To Catalyze Olefin Metathesis: A Computational Analysis	12
Updates to the Organometallics Team	12
Strategies for Promoting Reductive Elimination of Bi- and Bis-Oxazoline Ligated Organonickel Complexes	12
Synthesis of [Fe2[(μ-SeCH2)2NH](CN)2(CO)4]2– and Related Iron Selenoates	12
Importance of Ligand Fine-Tuning: Alkyne Metathesis with Molybdenum Alkylidyne Complexes Supported by Phenyl-tert-butoxysilanolate Ligands	12
Ion Pair Effects of Zwitterionic Ni/Pd Allyl Complexes Bearing an α-Sulfonate-β-diimine Ligand by Binding of B(C6F5)3 on Norbornene Polymerization	12
A Dinuclear Ir(III) Bis(thiophosphinite) Complex Formed by Unusual meta-C–H Activation at a Pincer Ligand	12
Propellanes as Drop-In ROMP Initiators	12
Cycloheptyl-Fused Iminopyridine-Iron Catalysts for Isoprene Polymerization with Enhanced Activity and Thermal Stability	12
Reductive Elimination from Sterically Encumbered Ni–Polypyridine Complexes	12
Structural Evidence for Aromatic Heterocycle N–O Bond Activation via Oxidative Addition	12
Catalytic Synthesis and Cyclometalation of (4-Ferrocenylphenyl)pyridines	12
Elemental Aspects of Transition Metals Pertinent to Organometallic Chemistry: Properties, Periodicity, Curiosities, and Related Main Group Issues	12
Ethylene Polymerization with Thermally Robust Vanadium(III) Tris(2-pyridyl)borate Complexes	12
Reactivity of Nickel Complexes Bearing P(C═X)P Ligands (X = O, N) Toward Diazoalkanes: Evidence for Phosphorus Ylide Intermediates	12
Palladium-Catalyzed Carbonylation of Amines with Mo(CO)6 as the Carbonyl Source	12
Dehydrogenation of Formic Acid Catalyzed by an Osmium-Polyhydride: Relevance of Acid Assistance in the CO2 Formation Stage	12
Synthesis and Single-Crystal X-ray Structures of Sterically Hindered Three Half-Sandwich (η6-p-Cymene)ruthenium(II) Schiff Base Complexes: Catalytic Applications in Selective Monoalk	12
Synthesis, Electrochemistry, XPS, and DFT Calculations of α-Carbon-Bonded Gold(I) Ferrocenyl- and Ruthenocenyl-Containing β-Diketonato Complexes	12

Effect of Pincer Methylation on the Selectivity and Activity in (PNP)Cobalt-Catalyzed C(sp2)–H Borylation	11
Flash Communication: Multinuclear Zwitterionic Germylene with Ge4 Chain Motif	11
Competitive Double Friedel–Crafts 2,5- and 1′,2-Diacylation of Monophosphaferrocenes	11
A Hybrid Benzothiazolyl-NHC Ligand with a Flexible −CH2– Linker and Its Cationic Rh(I) Complex That Catalyzes the Olefin Hydrosilylation	11
Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes: Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from CO2 Reduction to CO	11
Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems	11
ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides	11
Study of the Electronic Structure of M2(CH2CMe3)6 (M = Mo, W) by Photoelectron Spectroscopy and Density Functional Theory	11
Iron-Catalyzed Hydrogenation of Alkyl Formates and Carbon Dioxide	11
Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides	11
Bridging Bis(boryl) and Borylene Species Stabilized in the Coordination Sphere of Ruthenium Metals	11
Maurice Brookhart: A Legacy to Organometallic Chemistry	11
(NHC)M Cores as Catalysts for the Olefin Aziridination Reaction (M = Cu, Ag, Au): Evidencing a Concerted Mechanism for the Nitrene Transfer Process	11
Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning	11
C(sp3)–H Amination Catalyzed by Ir(Me)-Porphyrin: A Computational Study	11
Cesium Reduction of a Lithium Diamidochloroberyllate	11
Mechanism of Photocatalytic CO2 Reduction by Iron Spin-Crossover Complex with Copper Photosensitizer	11
Structural Variety, Isomerism, and Interconversions of Polynuclear Samarium Complexes with Reduced 9,10-Phenanthrenequinone Ligand	11
Flash Communication: Selective Benzylidene Insertion Reactions in Organoplatinum Complexes	11
Issue Editorial Masthead	11
Tetraaminocyclopentadienone Iron Complexes as Hydrogenation Catalysts	11
Issue Editorial Masthead	11
[B(O2C2(CF3)4)2]− ([FPB]−): Repurposing This Weakly Coordinating Anion for Solid-State Molecular Organometallic (SMOM) Chem	11
Stable Hydrogen Energy Carrier That Stores One Electron in a Cobalt(I) Complex for More Than 3 Months	11
Correction to “On the Possibility of Using Aza-Cryptands to Design Superalkalis”	11
Sn,P-Peri-Substituted Naphthalene as a Ligand for Transition Metals	11
Fluorinated N-Heterocyclic Carbene Silver(I) Complexes with High Cancer Cell Selectivity	11
Unsymmetrical Diborane(4) as a Precursor to PBP Boryl Pincer Complexes: Synthesis and Cu(I) and Pt(II) PBP Complexes with Unusual Structural Features	11
Employing a Two-Step Carbonylation and Condensation Approach to Expand the Scope of Hydroesterificative Polymerization	11
Advancing Base Metal Catalysis through Data Science: Insight and Predictive Models for Ni-Catalyzed Borylation through Supervised Machine Learning	11
Phosphine-Phenoxide Nickel Catalysts for Ethylene/Acrylate Copolymerization: Olefin Coordination and Complex Isomerization Studies Relevant to the Mechanism of Catalysis	11
Understanding and Designing of Bent Aromatic Heterometallabenzenes	11
Issue Editorial Masthead	11
True Homogeneous “Ligand-Free” Catalysis in Mizoroki–Heck Mono- and Double Arylations with Nonreactive Aryl Chlorides	11
Living cis-1,4-Selective Polymerization of 1,3-Dienes by Enamino-Oxazolinate Rare-Earth Metal Complexes	11
Reactivity of Methyl Diruthenium Complexes with the Bis(diphenylphosphino)methane (dppm) Ligand and Formation of Dinitrogen and Dihydrogen Complexes via Methane Loss	10
Accessing Phase-Transfer Catalysts and a Phosphoramidite Ligand via the Asymmetric Intramolecular Hydroamination Reaction	10
Silver Instead of Gold in Nitronyl Nitroxide Chemistry	10
Flash Communication: Flexibility of a Biologically Inspired Ligand Framework for Intramolecular C–H Activation	10
Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents	10
Issue Editorial Masthead	10
Conversion of an NHC-Stabilized Silyliumylidene to a Dicationic Silicon(IV) Complex Capable of CO2 Activation	10
Lewis Base and Metal Cation-Assisted Isomerization of Disilyne	10
Reversible C–CN Bond Cleavage by a Formal Dinickel(I) Hydride Cation	10
Cationic Ni(II) Species and Their Application in Olefin Polymerizations	10
Structural Investigation of the Anion Effect in Ruthenium(II) Arene Complexes Bearing Pyridyl-Triazole Ligands: Implications for Transfer Hydrogenation Catalysis	10
Mechanistic Study of Silylacetylene Hydroboration Catalyzed by a Cobalt PN5P Pincer Complex: Catalytic Cycles Altering the Reaction Efficiency	10
Activation Mechanism of Nickel(0) N-Heterocyclic Carbene Catalysts Stabilized by Fumarate Ligands	10
Tuning the Pyridone Scaffold within a Rhodium-NHC Platform for gem-Specific Alkyne Dimerization via a Ligand-Assisted Proton Shuttle Mechanism	10
Thiol-isocyanate Click Reaction for Rapid and Efficient Generation of a Library of Organofunctional Silanes	10
Issue Publication Information	10
Cobalt-Catalyzed Hydrogermylation of Nonactivated Alkenes Enabled by Photoirradiation	10
Understanding the Reaction Mechanism of Nickel-Catalyzed Enantioselective Arylative Activation of the Aromatic C–O Bond	10
Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C12H12M (M = Ti–Ni)	10
Coordination Ability of Phosphavinyl(oxo and thioxo)phosphoranes (P═C–P═X; X = O, S) toward Transition Metals	10
Synthesis and Chemical Redox Studies of Half-Sandwich Chromium Carbonyl Azobenzenes	10
Theoretical Studies on Relative Stability of Cationic 1,10-Phenanthroline Palladium Complexes Bearing Alkyl Groups by Using Designed Alkane Templates	10
Flash Communication: Pd2Zn2 Clusters from the Reduction of Palladium(II) Dichloride Precursors with Metallic Zinc	10
Predicting Dinitrogen Activation by Carborane-Based Frustrated Lewis Pairs	10
Alkyne Hydrofunctionalization Mechanism Including an Off-Cycle Alkoxycarbene Deactivation Complex	10
Aerobic Electrochemical Csp3–N Coupling between Aliphatic Carboxylic Acids and N-heterocycles	10
IPr# Complexes─Highly-Hindered, Sterically-Bulky Cu(I) and Ag(I) N-Heterocyclic Carbenes: Synthesis, Characterization, and Reactivity	10
Issue Publication Information	10
Flash Communication: Synthesis and Characterization of an Iron(V) Thiolate Complex	10
Head-to-Head Homocoupling of Ynamides via a Dual Activation Mode of Triple Bonds by Half-Sandwich Metal Complexes	10
Well-Defined ENENES Re and Mn Complexes and Their Application in Catalysis: The Role of Potassium tert-Butoxide	10
Metallocenium Lewis Acid Catalysts for Use in Friedel–Crafts Alkylation and Diels–Alder Reactions	10
Reversible Ligand Protonation in Noninnocent Constrained-Geometry-Like Group 4 Complexes	10
Pioneers and Influencers in Organometallic Chemistry: Dr. Alan H. Cowley and the Renaissance of Main-Group Organometallics	10
Pd-Catalyzed Formal [3+3] Annulation of Benzylic gem-Diacetates: Synthesis of Various (Hetero)Arene-Fused Benzo[f]chromenes	9
Comparing Square-Planar RhI and IrI: Metal–Ligand Proton Tautomerism, Fluxionality, and Reactivity	9
Synthesis and Activity of Vanadium Oxo NHC Alkylidenes. Remarkable Preference for Degenerate Metathesis and Application for Carbon Isotope Exchange	9
A σ-Poor, π-Rich Pyridonate Pincer Ligand Designed To Enhance C–H Oxidative Addition at Platinum Group Metals: Experimental and Computational Studies	9
Reactivity of Cyclopropenylaluminates	9
Investigation of Iron Silyl Complexes as Active Species in the Catalytic Hydrosilylation of Aldehydes and Ketones	9
Issue Editorial Masthead	9
Issue Editorial Masthead	9
Functionalization Strategy in 2D Flexible Zn(BTTB)-MOF for Improving Storage and Release of Anticancer Drugs: A Comprehensive Computational Investigation	9
C∧C* Platinum(II) Complexes with PtXPX Metallacycle Forming (X = N and S) Auxiliary Ligands: Synthesis, Crystal Structures, and Properties	9
3H-1,2,3,4-Triazaphosphole Constructs Derived from Sterically Encumbered Aryl Polyazides: Synthesis, Structure, and Reactivity	9
Well-Defined Cobalt-Silyl Complexes and Their Role in Catalytic Carbonyl Hydrosilylation	9
Reductive Head-to-Head Coupling of Phenylacetylenes in the Coordination Sphere of an Osmium-Polyhydride	9
An Electrophilic, Intramolecularly Base-Stabilized Platinum–Antimony Complex	9
Issue Publication Information	9
Issue Editorial Masthead	9
Copper-Catalyzed Domino Three-Component Benzannulation: Access to Isoquinolines	9
Hydroxycarbonylation of Alkenes with Formic Acid Catalyzed by a Rhodium(III) Hydride Diiodide Complex Bearing a Bidentate Phosphine Ligand	9
Cyclometalated Platinum(II) Complexes with 10-(Aryl)phenoxarsine Ligands: Synthesis, Structure, and Photophysical Properties	9
Redox Activation of Acyclic (Aryl)(amino)carbene Gold(I) Complexes	9
Electronic Directing Group Modification for Improved Ni(II)-Mediated C(sp3)–H Activation: A Hammett Investigation of 8-Aminoquinoline	9
Unsymmetrically Substituted Bis(phosphino)Ferrocenes Triggering Through-Space 31(P, P′)-Nuclear Spin Couplings and Encapsulating Coinage Metal Cations	9
Pyrrolo[1,2-c]pyrimidin-1-ylidene: A Diamino Carbene Embedded in a Six-Membered Aromatic Scaffold	9
Issue Editorial Masthead	9
Issue Editorial Masthead	9
Bis(benzimidazolin-2-ylidenes): Exploring the Impact of Ligand Properties in the Nickel-Catalyzed Suzuki–Miyaura Coupling	9