Organometallics

Article	Citations
Cationic Half-Sandwich Ruthenium(II) Complexes of 2-Picolyl-Based N-Arylguanidines as Catalysts for the Aldehyde–Water Shift Reaction	82
Synthesis, Characterization, and Reactivity of Thioether-Ligated Organoiron(II) Complexes	58
The Challenging Reaction of Cyclopropenones with Benzamide Catalyzed by Rh(III): A Computational Study	57
Flash Communication: Carbon Monoxide Insertion and Ligand Modification with Pyridine(diimine) Iron Alkyl Complexes	46
Bis(Tetrathiafulvalenes) with Mixed Phosphine and Silane Double Bridges	44
Issue Editorial Masthead	40
Issue Editorial Masthead	38
Issue Publication Information	37
Issue Publication Information	37
Hydroalumination of 1,8-Diethynylanthracenes–Al-based Bis-Lewis-Acids and their Isomerization and Complexation Behavior	36
Ylide-Functionalized Phosphine (YPhos) Platinum Complexes: Synthesis and Application in Hydrosilylations under Mild Conditions	35
Mechanism and Selectivity Investigation of [Cu]/[Pd] Synergistic Catalyzed Borylfluoroallylation of Alkyne: A DFT Study	34
Alkyllithium Reagents as a Hidden Source of Lithium Hydride	33
Catalyst Design for Rh-Catalyzed Arene and Alkane C–H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp	32
Multisite Ligand Noninnocence of (CpN3)Fe(CO)3+ with Exogenous Hydride Donors: Kinetics and Mechanism	32
Nickel-Catalyzed Arylation/Lactonization Cascade Reactions for the Synthesis of Bicyclo[3.2.1]lactones	31
Carborane-Functionalized Thiocarbohydrazones: Synthesis, Computational, and Anticancer Evaluation	29
Impact of Halide (Cl vs I) Identity on the Preferred Positioning of Substituents between Al and M (M = Co, Rh, Ir) in PAlP Pincer Complexes	28
Flash Communication: The [BPh 4 ] − Anion Is Stripped by Half-Sandwich Scandium Tetramethylalumina	28
Formation of Bisvinylidene Complexes through Consecutive Alkyne–Vinylidene Rearrangements	28
Triptycepenes: Synthesis, Metal Complexes, and Their Reactivity in Catalytic Reactions	27
Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners	26
Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines	25
Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO2 with Catecholborane	25
Multiple C–B Bond Cleavage Reactions at [BArF4]− Anions Mediated by Terphenyl Phosphine Gold Catalysts	25

Ni(3,5-CF3stb)2(Et2O): A “Super-Naked” Nickel Complex	24
High-Throughput Approach in the Ring-Opening Polymerization of β-Butyrolactone Enables Rapid Evaluation of Yttrium Salan Catalysts	24
Ruthenium-Catalyzed Formic Acid/Formate Dehydrogenation and Carbon Dioxide/(bi)carbonate Hydrogenation in Water	24
Groups 9 and 10 Complexes of C–Donor Ligands Derived from Pyridinium-Stabilized Phosphorus Ylides	23
Synthesis and Characterization of Rare-Earth Metal Complexes Bearing a 2-N,N-Dimethylamino-Ethylene-Imino-Functionalized Indolyl Ligand and Their Catalytic Activities Toward Hydrosilylat	23
Reactivity of Heterobimetallic Ion Pairs in Formic Acid Dehydrogenation	23
Oxidative Addition of Alkyl Iodides to [Sn(NMe2)2]2: In Situ Generation of RSn(NMe2)3 Compounds	22
Carbon Monoxide-Induced Mobility of Isolated Palladium Species on Silicon Dioxide at Room Temperature	22
Synthesis, Reactivity, and Theoretical Insights of Co-Sb2 and Co-Bi2 Rings	22
Activity Enhancement of Phenoxy-Imine Titanium Catalysts via σ–π Synergy and Para-Substituent Effect	22
PCP Pincer Complexes of Titanium in the +3 and +4 Oxidation States	21
Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems	21
Chromium(III) Amino-bis(phenolate) Catalysts for the Ring-Opening Copolymerization of Epoxides and Phthalic Anhydride: Effects of Cocatalysts and Cyclohexene Oxide Initiators on Copolymerization Activ	20
Kinetic and Thermodynamic Pathways in the Reactions of Five-Membered Zircona- and Hafnacyclocumulenes with Acetonitrile. Structures and Mechanisms of Formation of the Obtained Complexes	20
Flash Communication: (Ph 3 P) 2 N 2 ─Aza-Wittig	20
Influence of the Counterion on the Activation of Nickel(σ-Aryl) Precatalysts	20
Steric and Electronic Properties of Phosphinimide-Based Silylenes─The Influence of the Phosphine Moiety	20
Synthesis and Surface Attachment of Molecular Re(I) Hydride Species with Silatrane Functionalized Bipyridyl Ligands	20
Direct Stereoselective Synthesis of a Single (ebthi)Ti(BINOLate) Catalyst Enantiomer	20
Influence of Indole-N Substitution of Thiosemicarbazones in Cationic Ru(II)(η6-Benzene) Complexes on Their Anticancer Activity	20
(κ3-N∩N∩N)-Palladium Pincer Complex-Catalyzed Synthesis of Quinazolin-4(3H)-Ones Through the Acceptorless Dehydrogenation Process: Experimental Results and Computational Insights	20
Oxidative Coupling of Ruthenium Alkenyl Acetylide Complexes as a Route to Dinuclear Complexes Featuring Carbon-Rich Bridging Ligands	20
Stereoselective Epoxidation of Unfunctionalized Aliphatic Alkenes with a Macrocyclic Tetra-NHC Iron(II) Catalyst	20
Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions	20
Issue Publication Information	19
NIR-Absorbing TCBD and Expanded TCBD-Functionalized Ferrocene–Phenothiazine Conjugates	19
Reactions of Nickel(0)–Olefin Pincer Complexes with Terminal Alkynes: Cooperative C–H Bond Activation and Alkyne Coupling	19
Issue Editorial Masthead	18
Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates	18
Variable Kinetic Isotope Effect Reveals a Multistep Pathway for Protonolysis of a Pt–Me Bond	18
Tetramethylethylenediamine Stabilizes Organozinc Surface Intermediates against Chemical Etching but Not against Protodemetalation	18
Cytotoxicity of Ruthenium(II) Arene Complexes Containing Functionalized Ferrocenyl β-Diketonate Ligands	18
Back with the Flash Communication	18
Heteroleptic Bis(amido) Ca(II) and Yb(II) NHC Pincer Complexes: Synthesis, Characterization, and Catalytic Activity in Intermolecular Hydrofunctionalization of C═C Bonds	18
Electrocatalytic Anaerobic Oxidation of Benzylic Amines Enabled by Ferrocene-Based Redox Mediators	18
Mechanism and Selectivity of Bi(V)-Aryl Oxyfunctionalization in Trifluoroacetic Acid Solvents	18
Issue Editorial Masthead	18
Heterometallic Clusters with Thorium–Rhodium Bonds Supported by Double-Layer Nitrogen–Phosphorus Ligands	18
Saturated NHC-Stabilized Borenium, Boronium, Hydride-Bridged Boron Cations, and a Bora-Acyl Chloride	18
Tailoring Catalyst Activity and Substrate Scope via Modular Design of Adaptive Tridentate Ligands for Alkyne Metathesis	18
Mechanistic Insights into Rh-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silazanes: The Origin of Enantioselectivity	18
Mechanism of Perfluoro-Nickelacyclopentane Formation from Tetrafluoroethylene: Effects of Ancillary Ligand Bite Angle	17
Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me3SiCF3 and Me3SiCF2H	17
DFT Studies on the Early-Transition-Metal-Catalyzed Polymerization of Polar Monomers with a Methylene Spacer between Vinyl and Functional Groups	17
Geometric Control of Carbon–Carbon Reductive Elimination from a Platinum(IV) Pincer Complex	17
Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures	17
Bifunctional Hydroboration Catalyst Activation Using a Co SNS Amido Complex Bearing an Abnormal-NHC Ligand	17
A Contiguous Tricyclic [P6]2– Framework Spanning Across Two Vanadium(III) Centers	17
Correction to “DFT Study on the Mechanisms of Iron-Catalyzed Ortho C–H Homoallylation of Aromatic Ketones with Methylenecyclopropanes”	17
Revisiting C–C and C–H Bond Activation in Rhodium Pincer Complexes: Thermodynamics and Kinetics Involving a Common Agostic Intermediate	17

Issue Editorial Masthead	16
Metallapolycycles from the Coupling of Two Re–C Bonds	16
Carbene–Calcium Silylamides and Amidoboranes	16
Photochemistry of RMn(CO)5 Complexes as Precursor Candidates for Photoassisted Chemical Vapor Deposition	16
Divergent Approach for Tris-Heteroleptic Cyclometalated Iridium Complexes Using Triisopropylsilylethynyl-Substituted Synthons	16
CO Complexation by Ru(II) and Os(II) Porphyrin Complexes Sheds Light on the Relative Importance of Thermodynamic Stability and Kinetic Lability for CO Poisoning Antidotes	16
Flash Communication: Density Functional Theory (DFT) Calculations Indicate an Unconventional Anagostic Complex for the Initial Stage of the Reported Sc3+ Boosted C–H Bond Activation of 3,4-	16
Mechanistic Aspects of Rhodium-Catalyzed Isoprene Hydroformylation: A Computational Study	16
Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate	16
Flash Communication: Strained and Bimetallic Structures of Rhodium and Iridium Germyl Complexes with Phosphinoamido Ligands	16
Flash Communication: Ir Complexes with a PhN(CH2CH2PiPr2)2 Pincer Ligand for Reversible CO2 Hydrogenation	16
Mechanism of Nickel-Catalyzed Dual C–O Bond Activation in the Deoxygenation of Ethers via Reductive Cross-Coupling Reaction: A DFT Study	16
Phosphine-Mediated Cleavage of Sulfur–Sulfur Bonds	16
High-Temperature Solution-Phase Ethylene (Co)polymerization Catalyzed by a [O–N–P]TiBn2 Complex	16
Synthesis and Reactivity of Oxorhenium(V) Complexes Incorporating 2,6-Bis[(diphenyl)methyl]diamidopyridine (DPMDAP) Pincer Ligands as the Basic Component of Transition Metal Frustrated Lewi	16
Ligand Reorganization in the Coordination Sphere of a CCC-NHC Pincer Fe Complex and Transient Absorption Spectroscopic Characterization of [(BuCiCiCBu)	16
Rhodium-Catalyzed Arene Alkenylation Using Benzoquinone Derivatives as Oxidants	15
Ligand Modifications on a Cp(quinolate)Ru Catalyst to Improve Its Stability in a Bio-orthogonal Deprotection Reaction	15
The Intrinsic Barrier for N≡N Bond Cleavage or Formation Mediated by the Cp*Cr(dmpe) Fragment Is Insurmountable	15
Arene Insertion into the M–Cl Bond vs Addition-like Behavior of Arene and M–Cl Bond (M = Cu/Fe): A DFT Investigation of the Cu/Fe SET Mechanism of Arene sp2 C–H Chlorination	15
Metal Identity Effects in the Pincer Complex-Catalyzed Dehydrogenative Coupling of Formamides with Alcohols to Form Carbamates	15
Molecular Weight Determination of Relevant Organometallic Catalysts in Solution by DOSY-NMR to Monitor Reactivity	15
Diamidoamine Aluminum Complex as Effective Initiator for Random Copolymerization of Substituted Carbonate with L-Lactide	15
Carbon Nanotube-Supported Iron Complex Catalyzes 1-Hexene Dimerization	15
Skeletal Rearrangement of a μ–η2:η4-Hexatrienyl Ligand at a Diruthenium Site via a μ–η5-Ruthenacyclohexadienyl Intermediate	15
Amines as Activating Ligands for Phosphine Palladium(II) Precatalysts: Effect of Amine Ligand Identity on the Catalyst Efficiency	15
Catalytic Hydrogenation of Terminal Alkenes by a (PPP) Pincer-Ligated Cobalt(II) Complex	15
p-Aryl-Substituted Iminopyridine Chromium Complexes as Precatalysts for Ethylene Polymerization: The Question of the Physical Oxidation State Examined by Experimental and Density Functional Stu	15
Issue Publication Information	14
Synthesis, Characterization, and Catalytic Reactivity of Dithiolate-Bridged Diiron Complexes Supported by Bulky Cyclopentadienyl Ligands	14
Synthesis and Reactivity of Dipalladated Derivatives of Terephthalaldehyde	14
Ruthenium Bis-Sulfonate Complexes: Synthesis and Application in Asymmetric Hydrogenation	14
Issue Editorial Masthead	14
Organic Allene vs Organometallic Allene─Preference Toward Allylic Anionic Delocalization, Dative Bonding, and Tunable Reactivity	14
Hydrogen Bond Patterning and Biological Activity of Ferrocene Conjugates with Homo- and Heterochiral Ala–Pro Dipeptides	14
Synthesis of Mo(IV) para-Substituted Styrene Complexes and an Exploration of Their Conversion to 1-Phenethylidene Complexes	14
Iron–Aryloxide Complex Bearing Bis(dipyrromethene) Ligands for the Ring-Opening Polymerization of ε-Caprolactone	14
Pioneers and Influencers in Organometallic Chemistry: Professor John E. Ellis Takes Metals to the Limit	14
Methyl-Branched Polyethylene Produced by Hafnocene Complexes Exhibiting Unconventional Dialkoxy Bridges	14
Dehydrogenation of Formic Acid Catalyzed by an Osmium-Polyhydride: Relevance of Acid Assistance in the CO2 Formation Stage	13
Cobalt-Catalyzed Regio- and Stereoselective Hydrosilylation of Alk-2-ynes with Tertiary Silanes	13
Reactions of TcI(NO) and TcVN Complexes with Alkynes and Alkynides	13
Importance of Ligand Fine-Tuning: Alkyne Metathesis with Molybdenum Alkylidyne Complexes Supported by Phenyl-tert-butoxysilanolate Ligands	13
Compounds with Chelating 3-Dimethylamino-1-propyl Ligands as Chemical Vapor Deposition Precursors. Synthesis and Characterization of M[(CH2)3NMe2]2 Complexe	13
Reductive Elimination from Sterically Encumbered Ni–Polypyridine Complexes	13
Methane Activation by Different Early Actinide (Ac, Th, Pa, U, and Np) Oxides and Their Ions: A Density Functional Theory Investigation	13
Heteroditopic Chelating NHC Ligand-Supported CoIII Complexes: Catalysts for the Reductive Functionalization of Carbon Dioxide under Ambient Conditions	13
Synthesis and Characterization of Uranium Complexes Supported by Substituted Aryldimethylsilylanilide Ligands	13
Strategies for Promoting Reductive Elimination of Bi- and Bis-Oxazoline Ligated Organonickel Complexes	13
Synthesis and Single-Crystal X-ray Structures of Sterically Hindered Three Half-Sandwich (η6-p-Cymene)ruthenium(II) Schiff Base Complexes: Catalytic Applications in Selective Monoalk	13
N–N Double-Bond Cleavage and Azobenzene Rearrangement with C–C Bond Formation Induced by a Germylene	13
Photochemical Synthesis of Five-Membered Zirconacyclocumulene Complex and Its Reactions with Ketones	12
Bridging Bis(boryl) and Borylene Species Stabilized in the Coordination Sphere of Ruthenium Metals	12
Anionic Property Is Crucial for the High Activities of Metalloligand Catalysts	12
Influencing α-Olefin Selectivity and PE-Wax Suppression Using Cyclohexyl-Fused 2-Imino-1,10-phenanthroline-iron Ethylene Oligomerization Catalysts	12
Alkaline Earth Catalyzed CO2 Hydroboration into Acetal Derivatives Leading to C–S Bond Formation	12
Development of Sandwich Compound-Based Planar Chiral Six-Membered NHC Ligands with Quaternary Carbon at α-Position of Nitrogen	12
Cycloheptyl-Fused Iminopyridine-Iron Catalysts for Isoprene Polymerization with Enhanced Activity and Thermal Stability	12
Reactivity of Nickel Complexes Bearing P(C═X)P Ligands (X = O, N) Toward Diazoalkanes: Evidence for Phosphorus Ylide Intermediates	12
Understanding and Designing of Bent Aromatic Heterometallabenzenes	12
Correction to “On the Possibility of Using Aza-Cryptands to Design Superalkalis”	12
Flash Communication: Bismuthinidenes as Lewis Bases in Reversible C(sp3)–O Bond Cleavage	12
Reduction of Nitrous Oxide and Binding of Carbon Dioxide by Acenaphthene-1,2-diimine Aluminum Compounds	12
Structural Evidence for Aromatic Heterocycle N–O Bond Activation via Oxidative Addition	12
Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems	12
True Homogeneous “Ligand-Free” Catalysis in Mizoroki–Heck Mono- and Double Arylations with Nonreactive Aryl Chlorides	12
Maurice Brookhart: A Legacy to Organometallic Chemistry	12
Updates to the Organometallics Team	12
Controlled Polymerization of 3-Hexyne, 4-Octyne, and 5-Decyne by Nb(CHCMe2Ph)(NC6F5)[OC(CF3)3](PMe3)2 Catalyst: Structural	12
Issue Publication Information	12
Detection of the BICT State in a Borafluorene with High Stokes Shift Fluorescence	12
(NHC)M Cores as Catalysts for the Olefin Aziridination Reaction (M = Cu, Ag, Au): Evidencing a Concerted Mechanism for the Nitrene Transfer Process	11
Computational Study on the Role of Zn(II) Z-Type Ligands in Facilitating Diaryl Reductive Elimination from Pt(II)	11
Elemental Aspects of Transition Metals Pertinent to Organometallic Chemistry: Properties, Periodicity, Curiosities, and Related Main Group Issues	11
Fluorinated N-Heterocyclic Carbene Silver(I) Complexes with High Cancer Cell Selectivity	11
Unsymmetrical Diborane(4) as a Precursor to PBP Boryl Pincer Complexes: Synthesis and Cu(I) and Pt(II) PBP Complexes with Unusual Structural Features	11
Ion Pair Effects of Zwitterionic Ni/Pd Allyl Complexes Bearing an α-Sulfonate-β-diimine Ligand by Binding of B(C6F5)3 on Norbornene Polymerization	11
[B(O2C2(CF3)4)2]− ([FPB]−): Repurposing This Weakly Coordinating Anion for Solid-State Molecular Organometallic (SMOM) Chem	11
Structural Variety, Isomerism, and Interconversions of Polynuclear Samarium Complexes with Reduced 9,10-Phenanthrenequinone Ligand	11
Employing a Two-Step Carbonylation and Condensation Approach to Expand the Scope of Hydroesterificative Polymerization	11

Flash Communication: Multinuclear Zwitterionic Germylene with Ge4 Chain Motif	11
Manganese(I) Pincer Complexes as Catalysts for Dehydrogenative Annulation: Direct Access to Biologically Relevant Heterocycles from Alcohols and 2′-Aminoacetophenones	11
Cesium Reduction of a Lithium Diamidochloroberyllate	11
Carbon Dioxide Reduction by N -Phosphinoamidinate-Stabilized Silylenes	11
Singlet Spin State Drives [V]-Carbene To Catalyze Olefin Metathesis: A Computational Analysis	11
Synthesis, Electrochemistry, XPS, and DFT Calculations of α-Carbon-Bonded Gold(I) Ferrocenyl- and Ruthenocenyl-Containing β-Diketonato Complexes	11
Advancing Base Metal Catalysis through Data Science: Insight and Predictive Models for Ni-Catalyzed Borylation through Supervised Machine Learning	11
Issue Editorial Masthead	11
Mechanism of Photocatalytic CO2 Reduction by Iron Spin-Crossover Complex with Copper Photosensitizer	11
Living cis-1,4-Selective Polymerization of 1,3-Dienes by Enamino-Oxazolinate Rare-Earth Metal Complexes	11
A Dinuclear Ir(III) Bis(thiophosphinite) Complex Formed by Unusual meta-C–H Activation at a Pincer Ligand	11
Stable Hydrogen Energy Carrier That Stores One Electron in a Cobalt(I) Complex for More Than 3 Months	11
Issue Publication Information	11
A Hybrid Benzothiazolyl-NHC Ligand with a Flexible −CH2– Linker and Its Cationic Rh(I) Complex That Catalyzes the Olefin Hydrosilylation	11
Synthesis of [Fe2[(μ-SeCH2)2NH](CN)2(CO)4]2– and Related Iron Selenoates	11
Ethylene Polymerization with Thermally Robust Vanadium(III) Tris(2-pyridyl)borate Complexes	11
Iron-Catalyzed Hydrogenation of Alkyl Formates and Carbon Dioxide	11
Issue Editorial Masthead	11
Issue Editorial Masthead	11
Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning	10
Theoretical Studies on Relative Stability of Cationic 1,10-Phenanthroline Palladium Complexes Bearing Alkyl Groups by Using Designed Alkane Templates	10
Thiol-isocyanate Click Reaction for Rapid and Efficient Generation of a Library of Organofunctional Silanes	10
Accessing Phase-Transfer Catalysts and a Phosphoramidite Ligand via the Asymmetric Intramolecular Hydroamination Reaction	10
Flash Communication: Flexibility of a Biologically Inspired Ligand Framework for Intramolecular C–H Activation	10
Flash Communication: Selective Benzylidene Insertion Reactions in Organoplatinum Complexes	10
Sn,P-Peri-Substituted Naphthalene as a Ligand for Transition Metals	10
Phosphine-Phenoxide Nickel Catalysts for Ethylene/Acrylate Copolymerization: Olefin Coordination and Complex Isomerization Studies Relevant to the Mechanism of Catalysis	10
Mechanistic Insights into Nickel–NHC-Catalyzed Alkene Isomerization: A Computational Study on Selectivity and Reactivity	10
Synthesis, Characterization, and Photophysical Properties of Dimethylgallium(III) 9,10-Dioxoanthraceneolates	10
Issue Publication Information	10
Issue Publication Information	10
Reversible C–CN Bond Cleavage by a Formal Dinickel(I) Hydride Cation	10
Competitive Double Friedel–Crafts 2,5- and 1′,2-Diacylation of Monophosphaferrocenes	10
Ring-Closing and Ring-Opening of closo -B 12 -Fused Carboxonium Ions: PIDA-Mediated Synthesis and Reac	10
Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides	10
Catalytic Synthesis and Cyclometalation of (4-Ferrocenylphenyl)pyridines	10
Issue Editorial Masthead	10
Lewis Base and Metal Cation-Assisted Isomerization of Disilyne	10
Reactivity of Methyl Diruthenium Complexes with the Bis(diphenylphosphino)methane (dppm) Ligand and Formation of Dinitrogen and Dihydrogen Complexes via Methane Loss	10
Metallocenium Lewis Acid Catalysts for Use in Friedel–Crafts Alkylation and Diels–Alder Reactions	10
Well-Defined ENENES Re and Mn Complexes and Their Application in Catalysis: The Role of Potassium tert-Butoxide	10
Palladium-Catalyzed Carbonylation of Amines with Mo(CO)6 as the Carbonyl Source	10
ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides	10
Flash Communication: Pd2Zn2 Clusters from the Reduction of Palladium(II) Dichloride Precursors with Metallic Zinc	10
Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes: Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from CO2 Reduction to CO	10
Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron–Iridium Clusters	10
Cationic Ni(II) Species and Their Application in Olefin Polymerizations	9
Ir-Catalyzed Selective Reductive N-Formylation and Transfer Hydrogenation of N-Heteroarenes	9
Silver Instead of Gold in Nitronyl Nitroxide Chemistry	9
Aerobic Electrochemical Csp3–N Coupling between Aliphatic Carboxylic Acids and N-heterocycles	9
Predicting Dinitrogen Activation by Carborane-Based Frustrated Lewis Pairs	9
Photocatalytic CO2 Reduction Using an Iron–Bipyridyl Complex Supported by Two Phosphines for Improving Catalyst Durability	9
Mechanistic Study of Silylacetylene Hydroboration Catalyzed by a Cobalt PN5P Pincer Complex: Catalytic Cycles Altering the Reaction Efficiency	9
Substitution at a Coordinatively Saturated Aluminum Center Stabilized by Imidazolidin-2-imine	9
Cobalt-Catalyzed Hydrogermylation of Nonactivated Alkenes Enabled by Photoirradiation	9
Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents	9
Early Transition Metals in Organometallic Chemistry	9
Conversion of an NHC-Stabilized Silyliumylidene to a Dicationic Silicon(IV) Complex Capable of CO2 Activation	9
Cp2Ti(II) Mediated Rearrangement of Cyclopropyl Imines	9
Synthesis of Mono- and Acyclic Bis-aminoboranes via Controlled Hydroboration of Imines	9
Prospects for the Use of Al/Mg Cocatalysts (AlknAlCl3–n + Alk2Mg) in the Polymerization of Olefins. Studies of the Interactions between the Ac	9
Alternate Geometries in the Cobalt-Catalyzed Hydroacylation of Dienes Facilitate a High Spin Mechanism: A Density Functional Theory Study	9
Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C12H12M (M = Ti–Ni)	9
Heterobimetallic Au I /M (M = Ru II , Ir III )	9
Issue Editorial Masthead	9
Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route	9
A Three-Coordinate Cobalt(-I) Dinitrogen Complex	9
Alkyne Hydrofunctionalization Mechanism Including an Off-Cycle Alkoxycarbene Deactivation Complex	9
Homo- and Heteroleptic Silylstannylenes: Synthesis, Structure and Use as Precursors to Bimetallic Compounds	9
Tuning the Pyridone Scaffold within a Rhodium-NHC Platform for gem-Specific Alkyne Dimerization via a Ligand-Assisted Proton Shuttle Mechanism	9
Synthesis, Characterization, and Light Sensitivity in Titanium Piano Stool Alkyl and Sulfur Complexes, [(C5Me5)TiMe2R]n− (R = Me, SCPh3, S	9
Structural Investigation of the Anion Effect in Ruthenium(II) Arene Complexes Bearing Pyridyl-Triazole Ligands: Implications for Transfer Hydrogenation Catalysis	9
A Higher-Yielding Route for the Synthesis of Molecular Precursors to Thin Films of Gold by Atomic Layer Deposition	9
Ferrocene-Containing Desmuramylpeptides Adopt A Flexible Conformation and Exhibit NOD2 Agonistic Activity	9
Flash Communication: Synthesis and Characterization of an Iron(V) Thiolate Complex	9
Activation Mechanism of Nickel(0) N -Heterocyclic Carbene Catalysts Stabilized by Fumarate Ligands	9
Activation of S–H Bond with Electrophilic Phosphinidenes	9
Synthesis and Chemical Redox Studies of Half-Sandwich Chromium Carbonyl Azobenzenes	9
Issue Editorial Masthead	9
Pioneers and Influencers in Organometallic Chemistry: Alexander Nesmeyanov (1899–1980). Carbon and Hydrogen Are Good but What about the Other 100 Elements?	9
Coordination Ability of Phosphavinyl(oxo and thioxo)phosphoranes (P═C–P═X; X = O, S) toward Transition Metals	9
Understanding the Reaction Mechanism of Nickel-Catalyzed Enantioselective Arylative Activation of the Aromatic C–O Bond	9
Empowering Women in Organic Chemistry (EWOC) at Five Years: Giving Back and Getting Back	9
Cyclopentadienone Iridium Bipyridyl Complexes: Acid-Stable Transfer Hydrogenation Catalysts	8
Advances and Applications in Catalysis with Earth-Abundant Metals	8
Bis(benzimidazolin-2-ylidenes): Exploring the Impact of Ligand Properties in the Nickel-Catalyzed Suzuki–Miyaura Coupling	8
Structural and Electronic Properties of Star-like Compounds with a Central Planar Carbon Atom and D nh	8
Hydroxycarbonylation of Alkenes with Formic Acid Catalyzed by a Rhodium(III) Hydride Diiodide Complex Bearing a Bidentate Phosphine Ligand	8
Flash Communication: Isolable Stibinidene Chalcogenide Radical Anions	8
Comparing Square-Planar RhI and IrI: Metal–Ligand Proton Tautomerism, Fluxionality, and Reactivity	8
Issue Publication Information	8
Copper-Catalyzed Domino Three-Component Benzannulation: Access to Isoquinolines	8
Reductive Head-to-Head Coupling of Phenylacetylenes in the Coordination Sphere of an Osmium-Polyhydride	8
Synthesis and Cooperative Reactivity of Sterically Encumbered Silyl and Silylene ( t Bu	8
Redox Activation of Acyclic (Aryl)(amino)carbene Gold(I) Complexes	8