Faraday Discussions

Article	Citations
Is reducing new particle formation a plausible solution to mitigate particulate air pollution in Beijing and other Chinese megacities?	74
The state of the field: from inception to commercialization of metal–organic frameworks	69
MOFs industrialization: a complete assessment of production costs	60
Trends in the thermal stability of two-dimensional covalent organic frameworks	44
Avoiding high ozone pollution in Delhi, India	44
Raman spectroscopy of GaSe and InSe post-transition metal chalcogenides layers	42
Hybrid scanning electrochemical cell microscopy-interference reflection microscopy (SECCM-IRM): tracking phase formation on surfaces in small volumes	38
Spiers Memorial Lecture: Coordination networks that switch between nonporous and porous structures: an emerging class of soft porous crystals	36
Introductory lecture: air quality in megacities	35
Can 3D electron diffraction provide accurate atomic structures of metal–organic frameworks?	35
Formation and growth of sub-3 nm particles in megacities: impact of background aerosols	33
Biodegradation of graphene materials catalyzed by human eosinophil peroxidase	33
Integration of aprotic CO2 reduction to oxalate at a Pb catalyst into a GDE flow cell configuration	28
Effect of thermal treatment on the stability of Na–Mn–W/SiO2 catalyst for the oxidative coupling of methane	27
Estimating the accuracy of the MARTINI model towards the investigation of peripheral protein–membrane interactions	27
Renewable carbon feedstock for polymers: environmental benefits from synergistic use of biomass and CO2	26
Graphitic carbon nitrides as platforms for single-atom photocatalysis	25
Identifying the liquid and glassy states of coordination polymers and metal–organic frameworks	25
Sources of non-methane hydrocarbons in surface air in Delhi, India	24
Stability and universal encapsulation of epitaxial Xenes	23
Exploring the dynamics of Zr-based metal–organic frameworks containing mechanically interlocked molecular shuttles	23
White graphene quantum dots as electrochemical sensing platform for ferritin	23
The role of solvation in proton transfer reactions: implications for predicting salt/co-crystal formation using the ΔpKa rule	22
Electrochemical exfoliation of graphite in H2SO4, Li2SO4 and NaClO4 solutions monitored in situ by Raman microscopy and spectroscopy	22
Multiphase chemistry experiment in Fogs and Aerosols in the North China Plain (McFAN): integrated analysis and intensive winter campaign 2018	22

Crystal melting and vitrification behaviors of a three-dimensional nitrile-based metal–organic framework	22
CO2 utilization in built environment via the PCO2 swing carbonation of alkaline solid wastes with different mineralogy	22
Visualization of catalyst dynamics and development of a practical procedure to study complex “cocktail”-type catalytic systems	22
Towards MOFs’ mass market adoption: MOF Technologies’ efficient and versatile one-step extrusion of shaped MOFs directly from raw materials	21
Concluding remarks: next generation nanoelectrochemistry – next generation nanoelectrochemists	21
The role of surface oxidation and Fe–Ni synergy in Fe–Ni–S catalysts for CO2 hydrogenation	21
Surface stability of perovskite oxides under OER operating conditions: a first principles approach	21
Low-energy electron irradiation induced synthesis of molecular nanosheets: influence of the electron beam energy	21
Multi-channel photodissociation and XUV-induced charge transfer dynamics in strong-field-ionized methyl iodide studied with time-resolved recoil-frame covariance imaging	20
Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks	20
Time-resolved pump–probe spectroscopy with spectral domain ghost imaging	20
The role of temperature and adsorbate on negative gas adsorption transitions of the mesoporous metal–organic framework DUT-49	19
Mechanistic in situ investigation of heterogeneous hydrogenation over Rh/TiO2 catalysts: selectivity, pairwise route and catalyst nature	19
Long-term trends in the contribution of PM2.5sources to organic carbon (OC) in the Los Angeles basin and the effect of PM emission regulations	19
High-throughput cryo-EM structure determination of amyloids	18
Cooperative and synchronized rotation in motorized porous frameworks: impact on local and global transport properties of confined fluids	18
Understanding entrapped molecular photosystem and metal–organic framework synergy for improved solar fuel production	18
Controlling polymorphism in molecular cocrystals by variable temperature ball milling	18
Tracer-based characterization of source variations of PM2.5 and organic carbon in Shanghai influenced by the COVID-19 lockdown	18
Concluding remarks: current and next generation MOFs	18
Molecular interactions of the M and E integral membrane proteins of SARS-CoV-2	17
Core–shell graphene oxide–polymer hollow fibers as water filters with enhanced performance and selectivity	17
Capturing spatially resolved kinetic data and coking of Ga–Pt supported catalytically active liquid metal solutions during propane dehydrogenationin situ	17
Atomistic insight in the flexibility and heat transport properties of the stimuli-responsive metal–organic framework MIL-53(Al) for water-adsorption applications using molecular simulations	17
MOF matrix isolation: cooperative conformational mobility enables reliable single crystal transformations	16
A component-specific exposure–mortality model for ambient PM2.5 in China: findings from nationwide epidemiology based on outputs from a chemical transport model	16
The persistence of a proxy for cooking emissions in megacities: a kinetic study of the ozonolysis of self-assembled films by simultaneous small and wide angle X-ray scattering (SAXS/WAXS) and Raman mi	16
Variability of physical meteorology in urban areas at different scales: implications for air quality	16
Cryomicroscopy in situ: what is the smallest molecule that can be directly identified without labels in a cell?	16
Why copper catalyzes electrochemical reduction of nitrate to ammonia	16
Interactions of polymyxin B with lipopolysaccharide-containing membranes	16
Air quality and health benefits of China’s current and upcoming clean air policies	15
iR drop in scanning electrochemical cell microscopy	15
Effect of dynamic correlation on the ultrafast relaxation of uracil in the gas phase	15
Insight into the mechanism of the water–gas shift reaction over Au/CeO2 catalysts using combined operando spectroscopies	15
Impact of metastable defect structures on carrier recombination in solar cells	15
Reaction mechanism of low-temperature catalysis by surface protonics in an electric field	15
Multiple pathways in NaCl homogeneous crystal nucleation	14
What stress components drive mechanochemistry? A study of ZDDP tribofilm formation	14
Formation sequence of solid electrolyte interphases and impacts on lithium deposition and dissolution on copper: an in situ atomic force microscopic study	14
Electrochemically probing exciton transport in monolayers of two-dimensional semiconductors	14
Spiers Memorial Lecture. Next generation nanoelectrochemistry: the fundamental advances needed for applications	14
Molecular fragmentation as a way to reveal early electron dynamics induced by attosecond pulses	14
Quantum electronic coherences by attosecond transient absorption spectroscopy: ab initio B-spline RCS-ADC study	14
Mapping static core-holes and ring-currents with X-ray scattering	14
Printable hexagonal boron nitride ionogels	14
Manipulating twisted electrons in strong-field ionization	14
Esterification catalyzed by an efficient solid acid synthesized from PTSA and UiO-66(Zr) for biodiesel production	14
Chiral and robust Zr(iv)-based metal–organic frameworks built from spiro skeletons	14
Why conductivity is not always king – physical properties governing the capacitance of 2D metal–organic framework-based EDLC supercapacitor electrodes: a Ni3(HITP)2 case study	13

Antimicrobial peptide activity in asymmetric bacterial membrane mimics	13
Understanding crystal nucleation mechanisms: where do we stand? General discussion	13
Electrochemical carbon dioxide reduction in ionic liquids at high pressure	13
A high-throughput screening of metal–organic framework based membranes for biogas upgrading	13
Impact of antimicrobial peptides on E. coli-mimicking lipid model membranes: correlating structural and dynamic effects using scattering methods	13
An evaluation of source apportionment of fine OC and PM2.5by multiple methods: APHH-Beijing campaigns as a case study	13
Using highly time-resolved online mass spectrometry to examine biogenic and anthropogenic contributions to organic aerosol in Beijing	13
The unexpected dominance of secondary over primary nucleation	13
Multi-nuclear, high-pressure, operando FlowNMR spectroscopic study of Rh/PPh3 – catalysed hydroformylation of 1-hexene	13
On the completeness of three-dimensional electron diffraction data for structural analysis of metal–organic frameworks	13
Molecular characterization of size-segregated organic aerosols in the urban boundary layer in wintertime Beijing by FT-ICR MS	13
Spiers Memorial Lecture: Mechanochemistry, tribochemistry, mechanical alloying – retrospect, achievements and challenges	13
Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering	13
CO2 reduction to acetic acid on the greigite Fe3S4{111} surface	12
Transient resonant Auger–Meitner spectra of photoexcited thymine	12
Monolithic metal–organic frameworks for carbon dioxide separation	12
Computational design of graphitic carbon nitride photocatalysts for water splitting	12
Cryo-EM samples of gas-phase purified protein assemblies using native electrospray ion-beam deposition	12
Hydrophobic thiol coatings to facilitate a triphasic interface for carbon dioxide reduction to ethylene at gas diffusion electrodes	12
The “η-sweet-spot” (ηmax) in liquid-assisted mechanochemistry: polymorph control and the role of a liquid additive as either a catalyst or an inhibitor in resonant acoustic mi	12
Photoresponsive frameworks: energy transfer in the spotlight	12
Influence of flexible side-chains on the breathing phase transition of pillared layer MOFs: a force field investigation	12
Enhanced liquid phase exfoliation of graphene in water using an insoluble bis-pyrene stabiliser	12
The micromechanical model to computationally investigate cooperative and correlated phenomena in metal–organic frameworks	12
Antimicrobial peptides: mechanism of action and lipid-mediated synergistic interactions within membranes	12
Gently does it!: in situ preparation of alkali metal–solid electrolyte interfaces for photoelectron spectroscopy	11
Stereoisomer-dependent unimolecular kinetics of 2,4-dimethyloxetanyl peroxy radicals	11
Simulation of primary and secondary particles in the streets of Paris using MUNICH	11
Coupled nuclear–electronic decay dynamics of O2 inner valence excited states revealed by attosecond XUV wave-mixing spectroscopy	11
A multiscale modelling approach to elucidate the mechanism of the oxygen evolution reaction at the hematite–water interface	11
Mineral carbonation for serpentine mitigation in nickel processing: a step towards industrial carbon capture and storage	11
Inclusion of multiple cycling of potential in the deep neural network classification of voltammetric reaction mechanisms	11
The rise of electrochemical NAPXPS operated in the soft X-ray regime exemplified by the oxygen evolution reaction on IrOx electrocatalysts	11
Improved photodegradation of anionic dyes using a complex graphitic carbon nitride and iron-based metal–organic framework material	11
Can you break the oxo-wall? A multiconfigurational perspective	11
Spiers Memorial Lecture: Catalytic activation of molecular nitrogen for green ammonia synthesis: introduction and current status	11
Photomechanochemical control over stereoselectivity in the [2 + 2] photodimerization of acenaphthylene	10
The diverse chemistry of protoplanetary disks as revealed by JWST	10
Diurnal and weekly patterns of primary pollutants in Beijing under COVID-19 restrictions	10
Combination of theoretical and in situ experimental investigations of the role of lithium dopant in manganese nitride: a two-stage reagent for ammonia synthesis	10
Enhanced bio-production from CO2by microbial electrosynthesis (MES) with continuous operational mode	10
Adsorber heat exchanger using Al-fumarate beads for heat-pump applications – a transport study	10
Towards improving the capacity of UiO-66 for antibiotic elimination from contaminated water	10
Strong-field induced fragmentation and isomerization of toluene probed by ultrafast femtosecond electron diffraction and mass spectrometry	10
A zeolite crystallisation model confirmed by in situ observation	10
Nanopore-based measurement of the interaction of P450cam monooxygenase and putidaredoxin at the single-molecule level	10
Spiers Memorial Lecture: Assembly-based pathways of crystallization	10
Insights into air pollution chemistry and sulphate formation from nitrous acid (HONO) measurements during haze events in Beijing	10
Manipulation of amorphous precursors to enhance zeolite nucleation	10
Curing time: a temporally explicit life cycle CO2 accounting of mineralization, bioenergy, and CCS in the concrete sector	10
Spiers Memorial Lecture: Next generation chalcogenide-based absorbers for thin-film solar cells	10
Rapid thermal annealing process for Se thin-film solar cells	10
Photoluminescence assessment of materials for solar cell absorbers	10
The application of machine learning for predicting the methane uptake and working capacity of MOFs	10
Hydrogenation of ethylene over palladium: evolution of the catalyst structure byoperandosynchrotron-based techniques	10
Spiers Memorial Lecture: CO2 utilization: why, why now, and how?	10
Multifunctional coatings of exfoliated and reassembled graphite on cellulosic substrates	9
THz non-linear optical response in cuprates: predominance of the BCS response over the Higgs mode	9
Nucleation in sessile saline microdroplets: induction time measurement via deliquescence–recrystallization cycling	9
Crossed-beam and theoretical studies of multichannel nonadiabatic reactions: branching fractions and role of intersystem crossing for O(3P) + 1,3-butadiene	9
Spiers Memorial Lecture : Carbon nanostructures by macromolecular design – from branched polyphenylenes to nanographenes and graphene nanoribbons	9
The impact of AlphaFold2 on experimental structure solution	9
Thermodynamic exploration of xenon/krypton separation based on a high-throughput screening	9
The influence of phosphatidylserine localisation and lipid phase on membrane remodelling by the ESCRT-II/ESCRT-III complex	9
Resolving multiphoton processes with high-order anisotropy ultrafast X-ray scattering	9
Addressing the uncertainty of DFT-determined hydrogenation mechanisms over coinage metal surfaces	9
Function from configurational degeneracy in disordered framework materials	9
Structural changes in the model of the outer cell membrane of Gram-negative bacteria interacting with melittin: an in situ spectroelectrochemical study	9
Strategies for picking membrane-associated particles within subtomogram averaging workflows	9
Nanostructured carbon-fiber surfaces for improved neurochemical detection	9
Electro-mechanochemical approach towards the chloro sulfoximidations of allenes under solvent-free conditions in a ball mill	9
The impact of antibacterial peptides on bacterial lipid membranes depends on stage of growth	9
Developing a triple helix approach for CO2 utilisation assessment	8
Time-resolved photoluminescence studies of perovskite chalcogenides	8
The philosophy of carbon: meso-entropy materials	8
Possible embryos and precursors of crystalline nuclei of calcium carbonate observed by liquid-cell transmission electron microscopy	8
Chemical conditions on Hycean worlds	8
Molecular motion in the nanospace of MOFs upon gas adsorption investigated byin situRaman spectroscopy	8
Mechanosynthesis and photophysics of colour-tunable photoluminescent group 13 metal complexes with sterically demanding salen and salophen ligands	8
Electron scattering properties of biological macromolecules and their use for cryo-EM map sharpening	8

Caveolin induced membrane curvature and lipid clustering: two sides of the same coin?	8
Visualizing optically-induced strains by five-dimensional ultrafast electron microscopy	8
Unified quantum theory of electrochemical kinetics by coupled ion–electron transfer	8
Solid-state cross-coupling reactions of insoluble aryl halides under polymer-assisted grinding conditions	8
New directions in the analysis of buried interfaces for device technology by hard X-ray photoemission	8
Spiers Memorial Lecture: Understanding reaction mechanisms in heterogeneously catalysed reactions	8
The origin of overpotential in lithium-mediated nitrogen reduction	8
Asia Pacific road transportation emissions, 1900–2050	7
Mechanochemical reaction kinetics scales linearly with impact energy	7
Predicting third-body collision efficiencies for water and other polyatomic baths	7
Tuning the degree of CO2 activation by carbon doping Cun− (n = 3–10) clusters: an IR spectroscopic study	7
Understanding catalytic CO2 and CO conversion into methanol using computational fluid dynamics	7
Methanol synthesis from CO2and H2using supported Pd alloy catalysts	7
Strong-field ionization of polyatomic molecules: ultrafast H atom migration and bond formation in the photodissociation of CH3OH	7
Stoichiometry modulates the optoelectronic functionality of zinc phosphide (Zn3−xP2+x)	7
Simulating intergrowth formation in zeolite crystals: impact on habit and functionality	7
Dynamics over a Cu–graphite electrode during the gas-phase CO2 reduction investigated by APXPS	7
A post-deposition annealing approach for organic residue control in TiO2 and its impact on Sb2Se3/TiO2 device performance	7
Carbon nanospike coated nanoelectrodes for measurements of neurotransmitters	7
Time-resolved imaging of correlation-driven charge migration in light-induced molecular magnets by X-ray scattering	7
Sol–gel synthesis of 2-dimensional TiO2: self-assembly of Ti–oxoalkoxy–acetate complexes by carboxylate ligand directed condensation	7
Crystal growth of the core and rotated epitaxial shell of a heterometallic metal–organic framework revealed with atomic force microscopy	7
Polyaniline nanowire arrays generated through oriented mesoporous silica films: effect of pore size and spectroelectrochemical response	7
Autoperforation of two-dimensional materials to generate colloidal state machines capable of locomotion	7
A screening of results on the decay length in concentrated electrolytes	7
Heterogeneity of cell membrane structure studied by single molecule tracking	7
The role of oxygenated species in the catalytic self-coupling of MeOH on O pre-covered Au(111)	7
A GPx-mimetic copper vanadate nanozyme mediates the release of nitric oxide fromS-nitrosothiols	7
Hydrogenation of substituted nitroaromatics on non-noble metal catalysts: mechanistic insights to improve selectivity	7
High-resolution rovibrational and rotational spectroscopy of the singly deuterated cyclopropenyl cation, c-C3H2D+	7
Electrochemical characterization of individual oil micro-droplets by high-frequency nanocapacitor array imaging	6
Difference in ambient-personal exposure to PM2.5 and its inflammatory effect in local residents in urban and peri-urban Beijing, China: results of the AIRLESS project	6
Evolution of surface and sub-surface morphology and chemical state of exsolved Ni nanoparticles	6
Ultrafast branching in intersystem crossing dynamics revealed by coherent vibrational wavepacket motions in a bimetallic Pt(ii) complex	6
Structural evolution under physical and chemical stimuli of metastable Au–Fe nanoalloys obtained by laser ablation in liquid	6
Sustainable ammonia synthesis through electrochemical dinitrogen activation using an Ag2VO2PO4 catalyst	6
Electronic relaxation of aqueous aminoazobenzenes studied by time-resolved photoelectron spectroscopy and surface hopping TDDFT dynamics calculations	6
Graphene-supported 2D cobalt oxides for catalytic applications	6
Intermediate-spin iron(iv)-oxido species with record reactivity	6
Fine-tuning non-covalent interactions between hybrid metal-oxo clusters and proteins	6
Comprehensive rear surface passivation of superstrate Sb2Se3 solar cells via post-deposition selenium annealing treatments and the application of an electron blocking laye	6
Lipid specificity of the immune effector perforin	6
Corrosion inhibition in acidic environments: key interfacial insights with photoelectron spectroscopy	6
Oxygen relocation during HfO2 ALD on InAs	6
Interplay between interdiffusion and shape transformations in nanoalloys evolving from core–shell to intermixed structures	6
Face-selective adsorption of a prochiral compound on the chiral pore-surface of a metal–macrocycle framework (MMF) directed towards stereoselective reactions	6
Fingerprinting fragments of fragile interstellar molecules: dissociation chemistry of pyridine and benzonitrile revealed by infrared spectroscopy and theory	6
Conversion of CO2 and small alkanes to platform chemicals over Mo2C-based catalysts	6
Examining the accuracy of methods for obtaining pressure dependent rate coefficients	6
Supported FexNiy catalysts for the co-activation of CO2 and small alkanes	6
GeSe photovoltaics: doping, interfacial layer and devices	6
Spiers Memorial Lecture: Theory of unimolecular reactions	6
Mechanochemical solid-state vinyl polymerization with anionic initiator	6
An ultra-low noise amplifier array system for high throughput single entity analysis	6
Engineering PtCu nanoparticles for a highly efficient methanol electro-oxidation reaction	6
Concluding remarks: Carbon dioxide utilization: where are we now?… and where are we going?	6
A first-principles machine-learning force field for heterogeneous ice nucleation on microcline feldspar	6
Improved microcanonical instanton theory	6
Unimolecular isomerisation of 1,5-hexadiyne observed by threshold photoelectron photoion coincidence spectroscopy	6
O2 reduction by iron porphyrins with electron withdrawing groups: to scale or not to scale	6
Single catalyst particle diagnostics in a microreactor for performing multiphase hydrogenation reactions	5
Elucidating the role of H2O in promoting the formation of methacrylic acid during the oxidation of methacrolein over heteropolyacid compounds	5
An experimental and computational study of the reaction between pent-3-en-2-yl radicals and oxygen molecules: switching from pure stabilisation to pure decomposition with increasing temperature	5
Spiers Memorial Lecture: Nanoalloys of multiple components; the road to advance the field and experimental and theoretical challenges	5
Quantum dynamics simulations of the thermal and light-induced high-spin to low-spin relaxation in Fe(bpy)3 and Fe(mtz)6	5
The impact of the physical state and the reaction phase in the direct mechanocatalytic Suzuki–Miyaura coupling reaction	5
Shear-activated chemisorption and association of cyclic organic molecules	5
Electrical noise in electrolytes: a theoretical perspective	5
The kesterite–stannite structural transition as a way to avoid Cu/Zn disorder in kesterites: the exemplary case of the Cu2(Zn,Mn)SnSe4	5
Evolution of the electrical double layer with electrolyte concentration probed by second harmonic scattering	5
Multistep nucleation compatible with a single energy barrier: catching the non-classical culprit	5
Out-of-equilibrium dynamics driven by photoinduced charge transfer in CsCoFe Prussian blue analogue nanocrystals	5
Time-resolving the UV-initiated photodissociation dynamics of OCS	5
The chemical inventory of the inner regions of planet-forming disks – the JWST/MINDS program	5
Site-selective methylene C–H oxidation of an alkyl diamine enabled by supramolecular recognition using a bioinspired manganese catalyst	5
Biological lipid hydration: distinct mechanisms of interfacial water alignment and charge screening for model lipid membranes	5
Bcl-xL inhibits tBid and Bax via distinct mechanisms	5
Structure and anomalous underscreening in ethylammonium nitrate solutions confined between two mica surfaces	5
The influence of iodide on the solution-phase growth of Cu microplates: a multi-scale theoretical analysis from first principles	5
Hunting for interstellar molecules: rotational spectra of reactive species	5
Managed pathways for CO2 mineralisation: analogy with nature and potential contribution to CCUS-led reduction targets	5
Spiers Memorial Lecture: Analysis and de novo design of membrane-interactive peptides	5
A mechanochemical approach to the synthesis of sydnones and derivatives	5
Barium hydride activates Ni for ammonia synthesis catalysis	5
Vertical profile of particle hygroscopicity and CCN effectiveness during winter in Beijing: insight into the hygroscopicity transition threshold of black carbon	5
Towards novel probes for valence charges via X-ray optical wave mixing	5
Photo-induced lattice distortion in 2H-MoTe2 probed by time-resolved core level photoemission	5
Plasmon-driven methanol oxidation on PtAg nanoalloys prepared by improved pulsed laser deposition	5
Concluding remarks: Chemistry of 2-dimensional materials: beyond graphene	5
On the use of vibronic coherence to identify reaction coordinates for ultrafast excited-state dynamics of transition metal-based chromophores	5
On the mechanism of calcium carbonate polymorph selection via confinement	5
Concluding remarks: The age of molecular movies	5
Recent advances in plasma-enabled ammonia synthesis: state-of-the-art, challenges, and outlook	5
A combined periodic DFT and QM/MM approach to understand the radical mechanism of the catalytic production of methanol from glycerol	5
The merit of pressure dependent kinetic modelling in steam cracking	5