Chemical Communications

Article	Citations
Inside front cover	162
Back cover	151
Diphosphine-induced morphological modification in Au nanoclusters and its implications for catalytic activity regulation	135
Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation	134
Electrochemical hydrocarboxylation of enol derivatives with CO2: access to β-acetoxycarboxylic acids	130
A hierarchical WC/NiCoW hollow nanotube array as a highly efficient electrocatalyst for hydrogen evolution	128
Plugging synthetic DNA nanoparticles into the central dogma of life	125
A detection system using sensing motif-tethered oligodeoxynucleotides for multiplex biomolecular analysis	120
Activating nickel foam with trace titanium oxide for enhanced water oxidation	116
Reinforced hydrogel network building by a rapid dual-photo-coupling reaction for 3D printing	109
Advances in perovskite-based photovoltaics and photocatalysis: a journey fueled by ChemComm	106
Headpiece-assisted DNA data storage in solution and solid	106
Diverse reactivity of a magnesium silanide toward ketones	96
Self-forming double-crosslinked hydrogels by the marriage of catechols and enzyme mimetic polymers	94
Correction: Influence of a neighbouring Cu centre on electro- and photocatalytic CO2 reduction by Fe-Mabiq	93
Thioamide-based fluorescent sensors for dipeptidyl peptidase 4	92
Dimensional regulation of lanthanide metal–organic frameworks and their application in bacterial detection	89
Selenium dioxide promoted selenylation/cyclization of leucosceptrane sesterterpenoids	87
Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a meso-isomer to tune dynamic aggregates induced by enantiomers	87
Structure-dependent magnetoelectric and magnetothermal effects of MOF-derived zero-valence cobalt and iron oxide nanoparticles on a carbonaceous matrix	86
Revisiting the photocharging effect on the BiVO4 (010) surface by identifying the charge reaction kinetics	86
Highly regioselective and stereoselective cascade reductive cyclization of δ-ketoamide: practical access to oxa-bridged benzazepines	86
Broadband emission in alkali halides triggered by Sb3+ doping	86
Diverging conformations guide dipeptide self-assembly into crystals or hydrogels	85
Oxidative carbonylation of N-protected indoles by Rh(iii)-zeolites	83

Aggregation-induced emission photosensitizer for antibacterial therapy of methicillin-resistant Staphylococcus aureus	81
Delivery of external proteins into the cytoplasm using protein capsules modified with IgG on the surface, created from the amphiphilic two helix-bundle protein OLE-ZIP	81
Multi-spiro junctions enable efficient thermally activated delayed fluorescent emitter	79
A multifunctional phenylphosphinamide additive for stable flexible inverted perovskite solar cells	78
An ‘AND’-based ratiometric fluorescence probe for the sequential detection of biothiols and hypochlorous acid	77
N-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines via catalytic aminofluorination of styrenes	74
Glycosyl oxazolines serve as active donors for iterative synthesis of type I oligosaccharides	73
Decoupled alkaline water electrolysis by a K0.5MnO2-Ti mediator via K-ion insertion/extraction	73
Mechanistic details for oxidative addition of PhICl2 to gold(i) complexes	73
A UV-induced self-reinforced hydrogel based onin situhydrophobic aggregation of strained 1,2-dithiolane rings	73
In situ excitation of BODIPY fluorophores by 89Zr-generated Cerenkov luminescence	72
Solid state preparation of carbon-supported Pt2Ca nanoparticles for the oxygen reduction reaction	71
An electron counting formula to explain and to predict hydrogenated and metallated borophenes	70
Enhanced label-free detection of proteins on Au nanoparticle micropatterns for surface-enhanced infrared absorption spectroscopy	69
Recent advances in the functionalization of formyl and acroleyl appended corroles	69
Light-controlled pKavalue of chiral Brønsted acid catalysts in enantioselective aza-Friedel–Crafts reaction	69
Quercetin@UiO-66 NPs and chloroquine in combined tumor therapy by dual autophagy-ubiquitination system blockade	68
Electroenzymatic tandem catalysis for the conversion of nitrate into ammonia	68
Hierarchically fractal Co with highly exposed active facets and directed electron-transfer effect	68
Dual supramolecular chirogenesis based on platinum(ii) metallotweezers	68
A thiol-activated fluorogenic probe for detection of a target protein	67
Back cover	67
Back cover	66
Correction: Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes	65
Back cover	65
Correction: DLP printing of a flexible micropattern Si/PEDOT:PSS/PEG electrode for lithium-ion batteries	65
Isothiourea – catalyzed α-selective glycosylations	64
Correction: Development of a carbon quantum dots-based fluorescent Cu2+ probe suitable for living cell imaging	63
Inside front cover	62
Lithium salt-derived artificial near-surface reconfiguration to stabilize high-voltage LiCoO2	62
Pushing the limits of electron donation for cis-chelating ligands via an alliance of phosphonium ylide and anionic abnormal NHC	61
Sn–carbon nanocomposite anode for all-solid-state chloride-ion batteries operating at room temperature	61
Contents list	59
A sequential Au(i)/TBAF-promoted rapid and selective functionalization of heteroarene N-oxides with alkynes	59
Biochar boost: revolutionizing functionalization of a difficult material	59
Zirconium vs. hafnium: a comparative study of mesoporous MOF stability	59
Water-in-salt electrolytes – molecular insights to the high solubility of lithium-ion salts	58
Inside front cover	58
Visible-light induced decarboxylative coupling of phenoxyacetic acid with disulfides: synthesis of α-arylthioanisole derivatives	57
Recent advances in visible-light-mediated functionalization of olefins and alkynes using copper catalysts	56
Nanophase-photocatalysis: loading, storing, and release of H2O2 using graphitic carbon nitride	56
Consequences of substituting framework metals in polyoxometalates on H-atom uptake: proton-coupled electron transfer at a Keggin-type polyoxomolybdate	56
Glass electrospray for mass spectrometry in situ detection of living cells	55
Construction of a dual-functional dumbbell probe-based fluorescent biosensor for cascade amplification detection of miRNAs in lung cancer cells and tissues	55
Lewis base adducts of NpCl4	55
Synthesis of chiral systems featuring the pyrrole unit: a review	55
Gold(i)-catalysed [2+4] cycloaddition of 1,1-difluoroallenes with conjugated enones: synthesis of ring-difluorinated dihydro-2H-pyrans	55
Reversing the stereoselectivity of intramolecular [2+2] photocycloaddition utilizing cucurbit[8]uril as a molecular flask	55
Enantioselective transformations of 5-hydroxymethylfurfural via catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides	55
Designing small organic molecular NIR-II fluorophores by ring strain modulation	54

An anion exchange membrane of layered silicalite nanosheets with surface quaternary ammonium cations	54
Contents list	54
Correction: Macrocyclic peptides as inhibitors of WDR5–lncRNA interactions	54
Interfacial charge-transfer enhances the dual-function of the porous NiCo2S4@SiO2 heterojunction for high-performance Li–S batteries	53
Contents list	53
Back cover	53
Contents list	53
Front cover	53
Front cover	53
Inside front cover	52
Back cover	52
Inside front cover	52
Back cover	52
Back cover	52
Front cover	52
Back cover	52
Back cover	51
Inside front cover	51
Inside front cover	51
Inside front cover	51
Contents list	50
Ruthenium(ii)-catalyzed deoxygenation of ketones	50
Activating the high-potential V4+/V5+ redox couple for an advanced NASICON sodium-ion cathode	50
Contents list	50
Contents list	50
Eosin, blue LEDs and DIPEA are employed in a simple synthesis of (poly)cyclic O,O- and N,O-acetals	49
Boosting fast and stable sodium-ion storage in TiO2 by amorphization engineering and superstructure design	49
A high-performance electrochemical biosensor using an engineered urate oxidase	49
Synthesis of naphthalene-substituted aromatic esters via Rh(iii)-catalyzed C–H bond naphthylation and cascade directing group transformation	49
Interfacial cation engineering in δ-MnO2 nanosheets for efficient oxygen reduction reaction	49
An MgV3O8 anode exhibiting enhanced rate capability and stability for lithium storage applications	49
Unraveling the mechanism of hydrogen evolution reactions in alkaline media: recent advances in in situ Raman spectroscopy	48
One-dimensional silver iodide homo-helical chains induced by achiral ammonium featuring second-order optical nonlinearity	48
Super-resolution imaging of mitochondrial cristae using a more hydrophobic far-red Si-rhodamine probe	48
A general synthetic method towards conjugated microporous polymers with ordered bicontinuous mesostructures	48
Controlling and predicting alkyl-onium electronic structure	48
Band structure engineering of W replacement in ReSe2 nanosheets for enhancing hydrogen evolution	48
Key role of subsurface doping in optimizing active sites of IrO2 for the oxygen evolution reaction	48
Inside front cover	47
NRAS DNA G-quadruplex-targeting molecules for sequence-selective enzyme inhibition	47
Iridium-catalyzed regioselective B(3,6)-dialkenylation or B(4)-alkenylation of o-carboranes via B–H activation and 1,2-carbon migration of alkynes	46
Harnessing thermal waste with a poling-free molecular pyroelectric zinc(ii) complex	46
Si-containing polycyclic aromatic hydrocarbons: synthesis and opto-electronic properties	46
In situ constructed polymer-layer-modified solid electrolyte enables high-performance all-solid-state batteries	46
A near-infrared fluorescent probe for imaging peroxynitrite levels in paw edema mice and drug evaluation	46
High-efficiency Pt catalyst immobilized on hierarchical N-doped carbon nanocages for preferential oxidation of CO in H2	46
Acetoxy allenoates as emerging synthons in annulation/cycloaddition reactions	46
Green-route manufacturing towards future industrialization of metal halide perovskite nanocrystals	45
Unsupervised classification of voltammetric data beyond principal component analysis	45
Two new tellurite compounds ACu3Te2O8 (A = Ca, Cd) with ferromagnetic spin-1/2 kagomé layers	45
Polymer-based self-assembled photonic crystals to tune light transport and emission	45
Synthesis and photochromism of a turn-on fluorescent diarylethene having benzo[b]selenophene groups as the aryl units	45
Synthesis and thermal behaviour of thiophene-based oxazine-ring substituted benzoxazine monomers & polymers	44
Rational optimization of siRNA to ensure strand bias in the interaction with the RNA-induced silencing complex	44
A PEG-borate ester solid-state polymer electrolyte to fabricate a Li6PS5Cl-rich composite for a Li metal battery	44
Correction: Photoredox radical/polar crossover enables carbo-heterofunctionalization of alkenes: facile access to 1,3-difunctionalized nitro compounds	44
Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes	44
Cationic ring-opening polymerization of N-benzylaziridines to polyamines via organic boron	44
Plasmonic and nanozyme dual-channel-based logic judgment for enhancing gold nanoparticle based colorimetric Hg2+ ion sensing performance	44
Utilising triplet–triplet annihilation upconversion for overall photocatalytic water splitting	43
Potassium nitrilotriacetate as a multifunctional modifier of the buried interface for hysteresis-reduced perovskite solar cells	43
Choline–geranate (CAGE) ionic liquids potentiate the anticancer activity of platinum-based drugs	43
Enantioselective resolution of two model amino acids using inherently chiral oligomer films with uncorrelated molecular structures	43
Peripheral nucleic bases boost H2production by synthetic molecular catalysts in acidic water	42
Stannyl phosphaketene as a synthon for phosphorus analogues of β-lactams	42
Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis	42
Regulating Ag–Cu synergy effect via Cu doping numbers to boost CO2 electroreduction on Ag14 nanoclusters	42
A water-soluble cationic [2]biphenyl-extended pillar[6]arene: synthesis, host–guest interaction with hemin and application in chemodynamic/photodynamic cancer therapy	42
A TiO2/Fe heterostructure enables high-efficiency electrochemical ammonia synthesis from nitrate	42
PNO: a promising deep-UV nonlinear optical material with the largest second harmonic generation effect	42
In situ fabrication of bendable epitaxial metal–organic framework films via spraying	42
Creation of a boron carbide-based Ti3AlBC (312) MAX phase: a route to novel MXenes for energy storage	41
Phytate-coordinated nickel foam with enriched NiOOH intermediates for 5-hydroxymethylfurfural electrooxidation	41
X-ray-responsive prodrugs and polymeric nanocarriers for multimodal cancer therapy	41
From Li2NiO3 to high-performance LiNiO2 cathodes for application in Li-ion and all-solid-state batteries	41
A Fe(iii) intercalated clay nanoplatform for combined chemo/chemodynamic therapy	41
Microcracking of Ni-rich layered oxide does not occur at single crystal primary particles even abused at 4.7 V	41
Five key concepts linking vacancies, structure, and oxygen evolution reaction activity in cobalt-based electrocatalysts	41
Enabling an ultra-specific lysosomal polarity fluorescence response via intramolecular π–π stacking-mediated conformational locking	40
Rare-earth-metal half-sandwich complexes incorporating methyl, methylidene, and hydrido ligands	40

Front cover	40
First observation of [Pu6(OH)4O4]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect	40
Cu doping in FeP enabling efficient electrochemical nitrate reduction to ammonia in neutral media	40
Cd2(IO3)(PO4) and Cd1.62Mg0.38(IO3)(PO4): metal iodate-phosphates with large SHG responses and wide band gaps	40
A brush-like Cu2O–CoO core–shell nanoarray: an efficient bifunctional electrocatalyst for overall seawater splitting	40
Photo-induced scandium-catalyzed biomimetic skeleton conversion of lathyrane to naturally rare eupholathone Euphorbia diterpenes	40
A facile mixed complex synthesis method for perovskite oxides toward electrocatalytic oxygen reduction	40
Copper-catalyzed hydroaminocarbonylation of benzylidenecyclopropanes: synthesis of γ,δ-unsaturated amides	40
Lewis acid Mg2+-doped cobalt phosphate nanosheets for enhanced electrocatalytic oxygen evolution reaction	40
Large Stokes shift by increasing intramolecular charge transfer for high signal-to-background ratio bioimaging	40
Easy conversion perovskite fluorides KCo1−xFexF3 for efficient oxygen evolution reaction	40
Microwave-assisted chemoselective transamidation of secondary amides by selective N–C(O) bond cleavage under catalyst, additive and solvent-free conditions	39
A ZnSe/Bi2Se3 heterostructure as sodium-ion battery anode displaying fast reaction kinetics, high capacity, and good full cell performance	39
Double click macrocyclization with Sondheimer diyne of aza-dipyrrins for B–Free bioorthogonal imaging	39
Synthesis of N-substituted phthalimides via Pd-catalyzed [4+1] cycloaddition reaction	39
Production of benzoic acid from wood lignin	39
Carbon nanomaterials for designing next-generation membranes and their emerging applications	39
β-Stereoselective Kdo C-glycosylation by a (p-Tol)2SO/Tf2O preactivation strategy	39
Inhibitory effect of nucleotides on acetylcholine esterase activity and its microflow-based actuation in blood plasma	39
PhpC modulates G-quadruplex-RNA landscapes in human cells	39
Ammonium fluoride additive-modified interphase chemistry stabilizes zinc anodes in aqueous electrolytes	39
Suppression of electrolyte decomposition and protection of the lithium metal anode via a lactone additive	38
Ionic–electronic dual-conductive polymer modified LiCoO2 cathodes for solid lithium batteries	38
Back cover	38
Alkali metal reduction of crown ether encapsulated alkali metal cations	38
Harvesting mechanical energy induces piezoelectric polarization of MIL-100(Fe) for cocatalyst-free hydrogen production	38
External ligand-free nickel-catalyzed atom-economical coupling of isatins with allyl alcohols via a redox-relay strategy	38
Aggregation-induced emission (AIE)-active metallacycles with near-infrared emission for photodynamic therapy	38
(4+3) annulation of enone-tethered indoles with α-alkylidene succinimides: access to seven-membered azepino[3,2,1-hi]indole scaffolds	38
Non-aqueous synthesis of high-quality Prussian blue analogues for Na-ion batteries	38
The reaction between CO2 and chloroform in anion-functionalized ionic liquids with the formation of trichloroacetates	38
Visible-light induced cross-electrophile coupling of imines and anhydrides to synthesize α-amino ketones	37
Recent advances in chiral recognition using macrocyclic receptors	37
Beyond DNA: new probes for PAINT super-resolution microscopy	37
Synthesis of 18F-labelled aryl trifluoromethyl ketones with improved molar activity	37
Ultrasound-triggered hydrogel formation through thiol–norbornene reactions	37
Mineralization of macroaggregated albumin for accurate biodistribution evaluation of pre-radiotherapy	37
Inverse CO2/C2H2 separation assisted by coordinated water in a dysprosium(iii) metal–organic framework	37
A spin crossover FeII4L6 cage based on pyridyl-hydrazone sites	36
Potential application of metallacarboranes as an internal reference: an electrochemical comparative study to ferrocene	36
Nitroreductase-sensitive fluorescent covalent organic framework for tumor hypoxia imaging in cells	36
Concurrent base and silver(i) catalysis pulsed by fuel acid	36
Phenothiazine cyclic hexamers: synthesis, properties, and complexation behavior with C60	36
Salt additives as activity boosters: a simple strategy to access heterometallic cooperativity in lactide polymerisation	36
Activation of trace LiNO3additives by BF3in high-concentration electrolytes towards stable lithium metal batteries	36
A switchable red-emitting fluorophore involving a 7.6.6 defect	36
Correction: Systematic exploration of alkali–anion pairs for descriptor identification in OH-mediated methane coupling	36
Heterogeneous copper-catalyzed Grignard reactions with allylic substrates	36
Reduction of CS2 to an ethanetetrathiolate by a hydride-bridged uranium–iridium heterobimetallic complex	36
An extended-gate-type organic transistor for monitoring the Menschutkin reaction of tetrazole at a solid–liquid interface	36
Electronic interaction between dimethyl carbonate and Li+ studied by attenuated total reflectance far-ultraviolet spectroscopy	36
Insight into the effects of pulsed CO2 electrolysis in a zero-gap electrolyzer	35
High-entropy alloy nanomaterials for electrocatalysis	35
Using H2O2 as a green oxidant to produce fluorescent GaOOH nanomaterials from a liquid metal	35
Hydrogen-bonded frameworks containing aliphatic 3D linkers show high-capacity water vapour sorption	35
Towards “homeopathic” palladium-catalysed alkoxycarbonylation of aliphatic and aromatic olefins	35
Rhombic dodecahedral gold nanoparticles: chiral sensing probes for naked-eye recognition of histidine enantiomers	35
A step-by-step strategy to design active and stable quaternary intermetallic compounds for the hydrogen evolution reaction	35
Prediction of mechanical and flame-retardant properties of MOF-loaded polymer composites	35
Electrodepositing amorphous molybdenum oxides for aqueous NH4+ storage	35
Photoinduced carbamoylation reactions: unlocking new reactivities towards amide synthesis	35
Aromatic foldamers as molecular springs in network polymers	35
Highly selective α-hydrogermylation of alkynes catalyzed by an in situ generated bulky NHC–cobalt complex	34
Merging metal–ligand cooperation and redox promoted strategy for tailored synthesis of alkylated 9H-fluorenes	34
Intrinsically photosensitive polyimide photoresist and its double crosslinking mechanism	34
Hybrid photocathode based on a Ni molecular catalyst and Sb2Se3 for solar H2 production	34
Dimeric boron complexes bearing isoquinolyl-pyrrole ligands	34
An optically reversible room-temperature solid-state cobalt(iii) photoswitch based on nitro-to-nitrito linkage isomerism	34
Iterative click reactions using trivalent platforms for sequential molecular assembly	34
A cationic gold-fluorenyl complex with a dative Au → C+ bond: synthesis, structure, and carbophilic reactivity	34
Recent progress in metal complexes functionalized nanomaterials for photodynamic therapy	34
Mechanical properties of graphene oxide from machine-learning-driven simulations	34
Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents	34
Quantum shells versus quantum dots: suppressing Auger recombination in colloidal semiconductors	34
Copper–carbon dot aerogel: a high-performance mimetic peroxidase and its application for versatile colorimetric bioassays	34
Strain engineering improves the photovoltaic performance of carbon-based hole-transport-material free CsPbIBr2 perovskite solar cells	34
Self-assembly of enzymes and prodrugs with clickable amino acids for nucleus-targeted cancer therapy	34
Phosphine-based metal–organic layers to construct single-site heterogeneous catalysts for arene borylation	34
Evolution of a ‘privileged’ P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C–C bond formation	34
Recent progress of density functional theory studies on carbon-supported single-atom catalysts for energy storage and conversion	34
Recent advances in the synthesis of chiral α-tertiary aminesviatransition-metal catalysis	34
An organic–inorganic hybrid perovskite material [Me3NCMe3]GaCl4 exhibits a two-step off–on–off SHG response with a large temperature interval	34
Boosted reverse water-gas shift activity via exsolved Cu and Ni in silicalite-1	34
A phosphatase-recruiting bispecific antibody-aptamer chimera for enhanced suppression of tumor growth	34
Stable glycosylamines at the reducing ends of cellulose nanocrystals	33
Pillar[5]arene-derived covalent organic materials with pre-encoded molecular recognition for targeted and synergistic cancer photo- and chemotherapy	33
Electrochemical low valent cobalt-catalyzed addition of aryl and vinyl chlorides to α-ketoamides via C–Cl bond activation	33
Engineering of CdS-chain arrays assembled through S⋯S interactions in 1D semiconductive coordination polymers	33
Fabrication of a hierarchical nanoreactor based on COFs for cascade enzyme catalysis	33
A Calix[4]pyrrole Functionalized with an Amidoindole Ester for the Selective Recognition of the Dihydrogen Phosphate Anion	33
Next-generation air filtration nanotechnology for improved indoor air quality	33
The advent of electrophilic hydroxylamine-derived reagents for the direct preparation of unprotected amines	33
Epimerization effects on coordination behaviours of phenanthroline-based phosphine-oxide ligands with uranyl ions	33
Resolution enhancement of NMR by decoupling with the low-rank Hankel model	33
Highly selective electroreduction of CO2 to CO with ZnO QDs/N-doped porous carbon catalysts	33