Chemical Communications

Article	Citations
Inside front cover	167
Back cover	153
Diphosphine-induced morphological modification in Au nanoclusters and its implications for catalytic activity regulation	138
Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation	135
Electrochemical hydrocarboxylation of enol derivatives with CO2: access to β-acetoxycarboxylic acids	133
Plugging synthetic DNA nanoparticles into the central dogma of life	132
A hierarchical WC/NiCoW hollow nanotube array as a highly efficient electrocatalyst for hydrogen evolution	132
Activating nickel foam with trace titanium oxide for enhanced water oxidation	122
A detection system using sensing motif-tethered oligodeoxynucleotides for multiplex biomolecular analysis	122
Reinforced hydrogel network building by a rapid dual-photo-coupling reaction for 3D printing	110
Advances in perovskite-based photovoltaics and photocatalysis: a journey fueled by ChemComm	109
Headpiece-assisted DNA data storage in solution and solid	107
Diverse reactivity of a magnesium silanide toward ketones	97
Correction: Influence of a neighbouring Cu centre on electro- and photocatalytic CO2 reduction by Fe-Mabiq	97
Self-forming double-crosslinked hydrogels by the marriage of catechols and enzyme mimetic polymers	97
Thioamide-based fluorescent sensors for dipeptidyl peptidase 4	96
Selenium dioxide promoted selenylation/cyclization of leucosceptrane sesterterpenoids	93
Developing chiral aggregates exhibiting anti-S-shaped CD-ee dependence: using a meso-isomer to tune dynamic aggregates induced by enantiomers	93
Structure-dependent magnetoelectric and magnetothermal effects of MOF-derived zero-valence cobalt and iron oxide nanoparticles on a carbonaceous matrix	90
Highly regioselective and stereoselective cascade reductive cyclization of δ-ketoamide: practical access to oxa-bridged benzazepines	89
Broadband emission in alkali halides triggered by Sb3+ doping	89
Revisiting the photocharging effect on the BiVO4 (010) surface by identifying the charge reaction kinetics	86
Diverging conformations guide dipeptide self-assembly into crystals or hydrogels	86
Oxidative carbonylation of N-protected indoles by Rh(iii)-zeolites	85
Aggregation-induced emission photosensitizer for antibacterial therapy of methicillin-resistant Staphylococcus aureus	84

Multi-spiro junctions enable efficient thermally activated delayed fluorescent emitter	82
Delivery of external proteins into the cytoplasm using protein capsules modified with IgG on the surface, created from the amphiphilic two helix-bundle protein OLE-ZIP	82
A multifunctional phenylphosphinamide additive for stable flexible inverted perovskite solar cells	80
Mechanistic details for oxidative addition of PhICl2 to gold(i) complexes	80
N-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines via catalytic aminofluorination of styrenes	80
A UV-induced self-reinforced hydrogel based onin situhydrophobic aggregation of strained 1,2-dithiolane rings	78
Glycosyl oxazolines serve as active donors for iterative synthesis of type I oligosaccharides	78
Decoupled alkaline water electrolysis by a K0.5MnO2-Ti mediator via K-ion insertion/extraction	76
In situ excitation of BODIPY fluorophores by 89Zr-generated Cerenkov luminescence	74
Solid state preparation of carbon-supported Pt2Ca nanoparticles for the oxygen reduction reaction	74
An electron counting formula to explain and to predict hydrogenated and metallated borophenes	73
Light-controlled pKavalue of chiral Brønsted acid catalysts in enantioselective aza-Friedel–Crafts reaction	72
Electroenzymatic tandem catalysis for the conversion of nitrate into ammonia	72
Enhanced label-free detection of proteins on Au nanoparticle micropatterns for surface-enhanced infrared absorption spectroscopy	72
Quercetin@UiO-66 NPs and chloroquine in combined tumor therapy by dual autophagy-ubiquitination system blockade	71
Dual supramolecular chirogenesis based on platinum(ii) metallotweezers	71
Back cover	70
Back cover	70
Hierarchically fractal Co with highly exposed active facets and directed electron-transfer effect	70
A thiol-activated fluorogenic probe for detection of a target protein	70
Correction: Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes	70
Correction: DLP printing of a flexible micropattern Si/PEDOT:PSS/PEG electrode for lithium-ion batteries	69
Back cover	68
Inside front cover	67
Correction: Development of a carbon quantum dots-based fluorescent Cu2+ probe suitable for living cell imaging	67
Isothiourea – catalyzed α-selective glycosylations	67
Lithium salt-derived artificial near-surface reconfiguration to stabilize high-voltage LiCoO2	66
Sn–carbon nanocomposite anode for all-solid-state chloride-ion batteries operating at room temperature	64
Pushing the limits of electron donation for cis-chelating ligands via an alliance of phosphonium ylide and anionic abnormal NHC	63
A sequential Au(i)/TBAF-promoted rapid and selective functionalization of heteroarene N-oxides with alkynes	63
Biochar boost: revolutionizing functionalization of a difficult material	62
Zirconium vs. hafnium: a comparative study of mesoporous MOF stability	62
Water-in-salt electrolytes – molecular insights to the high solubility of lithium-ion salts	60
Inside front cover	60
Contents list	60
Recent advances in visible-light-mediated functionalization of olefins and alkynes using copper catalysts	59
Nanophase-photocatalysis: loading, storing, and release of H2O2 using graphitic carbon nitride	59
Enantioselective transformations of 5-hydroxymethylfurfural via catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides	59
Visible-light induced decarboxylative coupling of phenoxyacetic acid with disulfides: synthesis of α-arylthioanisole derivatives	59
Consequences of substituting framework metals in polyoxometalates on H-atom uptake: proton-coupled electron transfer at a Keggin-type polyoxomolybdate	58
Gold(i)-catalysed [2+4] cycloaddition of 1,1-difluoroallenes with conjugated enones: synthesis of ring-difluorinated dihydro-2H-pyrans	57
Lewis base adducts of NpCl4	57
Correction: Macrocyclic peptides as inhibitors of WDR5–lncRNA interactions	57
Glass electrospray for mass spectrometry in situ detection of living cells	57
Designing small organic molecular NIR-II fluorophores by ring strain modulation	57
Reversing the stereoselectivity of intramolecular [2+2] photocycloaddition utilizing cucurbit[8]uril as a molecular flask	57
Front cover	56
An anion exchange membrane of layered silicalite nanosheets with surface quaternary ammonium cations	56
Contents list	56
Contents list	56

Inside front cover	55
Front cover	55
Interfacial charge-transfer enhances the dual-function of the porous NiCo2S4@SiO2 heterojunction for high-performance Li–S batteries	55
Contents list	55
Back cover	55
Inside front cover	54
Back cover	54
Back cover	54
Back cover	54
Front cover	54
Back cover	54
Contents list	53
Inside front cover	53
Contents list	53
Back cover	53
Inside front cover	53
Inside front cover	53
Copper-catalyzed hydroaminocarbonylation of benzylidenecyclopropanes: synthesis of γ,δ-unsaturated amides	52
Contents list	52
Lewis acid Mg2+-doped cobalt phosphate nanosheets for enhanced electrocatalytic oxygen evolution reaction	52
Enabling an ultra-specific lysosomal polarity fluorescence response via intramolecular π–π stacking-mediated conformational locking	52
Photo-induced scandium-catalyzed biomimetic skeleton conversion of lathyrane to naturally rare eupholathone Euphorbia diterpenes	52
Activating the high-potential V4+/V5+ redox couple for an advanced NASICON sodium-ion cathode	52
Enantioselective resolution of two model amino acids using inherently chiral oligomer films with uncorrelated molecular structures	51
A Fe(iii) intercalated clay nanoplatform for combined chemo/chemodynamic therapy	51
Peripheral nucleic bases boost H2production by synthetic molecular catalysts in acidic water	51
Rare-earth-metal half-sandwich complexes incorporating methyl, methylidene, and hydrido ligands	51
Utilising triplet–triplet annihilation upconversion for overall photocatalytic water splitting	51
Front cover	50
Easy conversion perovskite fluorides KCo1−xFexF3 for efficient oxygen evolution reaction	50
Potassium nitrilotriacetate as a multifunctional modifier of the buried interface for hysteresis-reduced perovskite solar cells	50
In situ fabrication of bendable epitaxial metal–organic framework films via spraying	50
First observation of [Pu6(OH)4O4]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect	50
Large Stokes shift by increasing intramolecular charge transfer for high signal-to-background ratio bioimaging	50
A facile mixed complex synthesis method for perovskite oxides toward electrocatalytic oxygen reduction	50
β-Stereoselective Kdo C-glycosylation by a (p-Tol)2SO/Tf2O preactivation strategy	49
Creation of a boron carbide-based Ti3AlBC (312) MAX phase: a route to novel MXenes for energy storage	49
Inhibitory effect of nucleotides on acetylcholine esterase activity and its microflow-based actuation in blood plasma	48
Double click macrocyclization with Sondheimer diyne of aza-dipyrrins for B–Free bioorthogonal imaging	48
PNO: a promising deep-UV nonlinear optical material with the largest second harmonic generation effect	48
Iterative click reactions using trivalent platforms for sequential molecular assembly	48
X-ray-responsive prodrugs and polymeric nanocarriers for multimodal cancer therapy	48
Stannyl phosphaketene as a synthon for phosphorus analogues of β-lactams	48
NRAS DNA G-quadruplex-targeting molecules for sequence-selective enzyme inhibition	47
Controlling and predicting alkyl-onium electronic structure	47
Inside front cover	47
An organic–inorganic hybrid perovskite material [Me3NCMe3]GaCl4 exhibits a two-step off–on–off SHG response with a large temperature interval	47
Si-containing polycyclic aromatic hydrocarbons: synthesis and opto-electronic properties	46
Polymer-based self-assembled photonic crystals to tune light transport and emission	46
A near-infrared fluorescent probe for imaging peroxynitrite levels in paw edema mice and drug evaluation	46
Two new tellurite compounds ACu3Te2O8 (A = Ca, Cd) with ferromagnetic spin-1/2 kagomé layers	46
Synthesis and photochromism of a turn-on fluorescent diarylethene having benzo[b]selenophene groups as the aryl units	46
In situ constructed polymer-layer-modified solid electrolyte enables high-performance all-solid-state batteries	46
Acetoxy allenoates as emerging synthons in annulation/cycloaddition reactions	46
Green-route manufacturing towards future industrialization of metal halide perovskite nanocrystals	46
High-efficiency Pt catalyst immobilized on hierarchical N-doped carbon nanocages for preferential oxidation of CO in H2	46
Rational optimization of siRNA to ensure strand bias in the interaction with the RNA-induced silencing complex	45
Unsupervised classification of voltammetric data beyond principal component analysis	45
Synthesis and thermal behaviour of thiophene-based oxazine-ring substituted benzoxazine monomers & polymers	45
Correction: Photoredox radical/polar crossover enables carbo-heterofunctionalization of alkenes: facile access to 1,3-difunctionalized nitro compounds	45
Visible-light organophotoredox-catalyzed fluoroalkyl aminoxylation of unactivated and activated alkenes	45
Boosting fast and stable sodium-ion storage in TiO2 by amorphization engineering and superstructure design	44
Phenothiazine cyclic hexamers: synthesis, properties, and complexation behavior with C60	44
Band structure engineering of W replacement in ReSe2 nanosheets for enhancing hydrogen evolution	44
One-dimensional silver iodide homo-helical chains induced by achiral ammonium featuring second-order optical nonlinearity	44
A high-performance electrochemical biosensor using an engineered urate oxidase	43
Eosin, blue LEDs and DIPEA are employed in a simple synthesis of (poly)cyclic O,O- and N,O-acetals	43
Synthesis of naphthalene-substituted aromatic esters via Rh(iii)-catalyzed C–H bond naphthylation and cascade directing group transformation	43
Interfacial cation engineering in δ-MnO2 nanosheets for efficient oxygen reduction reaction	42
Super-resolution imaging of mitochondrial cristae using a more hydrophobic far-red Si-rhodamine probe	42
Recent advances in the synthesis of chiral α-tertiary aminesviatransition-metal catalysis	42
A phosphatase-recruiting bispecific antibody-aptamer chimera for enhanced suppression of tumor growth	42
An MgV3O8 anode exhibiting enhanced rate capability and stability for lithium storage applications	42
Copper–carbon dot aerogel: a high-performance mimetic peroxidase and its application for versatile colorimetric bioassays	42
Quantum shells versus quantum dots: suppressing Auger recombination in colloidal semiconductors	42
A general synthetic method towards conjugated microporous polymers with ordered bicontinuous mesostructures	42
A cationic gold-fluorenyl complex with a dative Au → C+ bond: synthesis, structure, and carbophilic reactivity	42
Hybrid photocathode based on a Ni molecular catalyst and Sb2Se3 for solar H2 production	42
Stereoselective synthesis of vinylphosphonates through aromatic aza-Claisen rearrangement of α-aminophosphonates	41
Stable glycosylamines at the reducing ends of cellulose nanocrystals	41

Recent progress of density functional theory studies on carbon-supported single-atom catalysts for energy storage and conversion	41
Engineering of CdS-chain arrays assembled through S⋯S interactions in 1D semiconductive coordination polymers	41
Palladium-catalyzed ligand-regulated divergent synthesis of pyrrole[2,3-b]indoles and ureas from 2-ethynylanilines and isocyanides	41
Evolution of a ‘privileged’ P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C–C bond formation	41
Photoredox catalyzed reductive trifluoromethylation of imines via a radical umpolung strategy	41
Intrinsically photosensitive polyimide photoresist and its double crosslinking mechanism	41
Self-assembly of enzymes and prodrugs with clickable amino acids for nucleus-targeted cancer therapy	41
Dangling carboxylic-acid functionality in a fish-bone-shaped 2D framework as a hydrogen-bond-donating catalyst in Friedel–Crafts alkylation	40
A TiO2/Fe heterostructure enables high-efficiency electrochemical ammonia synthesis from nitrate	40
Regulating Ag–Cu synergy effect via Cu doping numbers to boost CO2 electroreduction on Ag14 nanoclusters	40
Next-generation air filtration nanotechnology for improved indoor air quality	40
Synergistic phototherapy of NIR wavelength xanthene-quinoline salt-based heavy-atom-free photosensitizers for tumor therapy	40
Redshifted and thermally bistable one-way quantitative hemithioindigo-derived photoswitches enabled by isomer-specific excited state intramolecular proton transfer	40
Epimerization effects on coordination behaviours of phenanthroline-based phosphine-oxide ligands with uranyl ions	40
Amorphous palladium-based alloy nanoparticles as highly active electrocatalysts for ethanol oxidation	40
The synthesis of polydopamine nano- and microspheres in microdroplets	40
Resolution enhancement of NMR by decoupling with the low-rank Hankel model	40
A bis-quinoline ruthenium(ii) arene complex with submicromolar cytotoxicity in castration-resistant prostate cancer cells	40
A giant macrocycle overcomes the post-treatment phototoxicity of photofrin through host–guest complexation	40
Pillar[5]arene-derived covalent organic materials with pre-encoded molecular recognition for targeted and synergistic cancer photo- and chemotherapy	40
Recent advances in carboxyl-directed dimerizations and cascade annulations via C–H activations	40
Mechanical properties of graphene oxide from machine-learning-driven simulations	39
Hydroxyfluorooxoborate (NH4)[C(NH2)3][B3O3F4(OH)] for exploring the effects of cation substitution on structure and optical properties	39
Aggregation-induced emission (AIE)-active metallacycles with near-infrared emission for photodynamic therapy	39
Radical-polar crossover reaction of glycine derivatives	39
Synthesis and electronic properties of nitrogen-rich nanographene	39
The reaction between CO2 and chloroform in anion-functionalized ionic liquids with the formation of trichloroacetates	39
Five key concepts linking vacancies, structure, and oxygen evolution reaction activity in cobalt-based electrocatalysts	39
Photocatalyst-free visible-light-induced highly selective acylation of purine nucleosides at the C6 position	39
External ligand-free nickel-catalyzed atom-economical coupling of isatins with allyl alcohols via a redox-relay strategy	39
Mineralization of macroaggregated albumin for accurate biodistribution evaluation of pre-radiotherapy	38
Heterogeneous copper-catalyzed Grignard reactions with allylic substrates	38
Ultrasound-triggered hydrogel formation through thiol–norbornene reactions	38
Visible-light induced cross-electrophile coupling of imines and anhydrides to synthesize α-amino ketones	38
Reduction of CS2 to an ethanetetrathiolate by a hydride-bridged uranium–iridium heterobimetallic complex	38
Beyond DNA: new probes for PAINT super-resolution microscopy	38
Synthesis of 18F-labelled aryl trifluoromethyl ketones with improved molar activity	38
Back cover	38
Potential application of metallacarboranes as an internal reference: an electrochemical comparative study to ferrocene	38
Activation of trace LiNO3additives by BF3in high-concentration electrolytes towards stable lithium metal batteries	37
Using H2O2 as a green oxidant to produce fluorescent GaOOH nanomaterials from a liquid metal	37
Salt additives as activity boosters: a simple strategy to access heterometallic cooperativity in lactide polymerisation	37
Correction: Systematic exploration of alkali–anion pairs for descriptor identification in OH-mediated methane coupling	37
An extended-gate-type organic transistor for monitoring the Menschutkin reaction of tetrazole at a solid–liquid interface	37
Hydrogen-bonded frameworks containing aliphatic 3D linkers show high-capacity water vapour sorption	37
Nitroreductase-sensitive fluorescent covalent organic framework for tumor hypoxia imaging in cells	37
Towards “homeopathic” palladium-catalysed alkoxycarbonylation of aliphatic and aromatic olefins	37
A switchable red-emitting fluorophore involving a 7.6.6 defect	37
Rhombic dodecahedral gold nanoparticles: chiral sensing probes for naked-eye recognition of histidine enantiomers	37
Electronic interaction between dimethyl carbonate and Li+ studied by attenuated total reflectance far-ultraviolet spectroscopy	37
Construction of a dual-functional dumbbell probe-based fluorescent biosensor for cascade amplification detection of miRNAs in lung cancer cells and tissues	37
A step-by-step strategy to design active and stable quaternary intermetallic compounds for the hydrogen evolution reaction	37
Cooperative dihydrogen activation at a Na(i)2/Mg(i)2ensemble	36
Transition-metal-catalyzed auxiliary-assisted C–H functionalization using vinylcyclopropanes and cyclopropanols	36
Synthesis of chiral systems featuring the pyrrole unit: a review	36
Aromatic foldamers as molecular springs in network polymers	36
Prediction of mechanical and flame-retardant properties of MOF-loaded polymer composites	36
High-throughput label-free opioid receptor binding assays using an automated desorption electrospray ionization mass spectrometry platform	36
Critical role of hydrogen bonding between microcrystalline cellulose and g-C3N4 enables highly efficient photocatalysis	36
Carbodiimide-fueled catalytic reaction cycles to regulate supramolecular processes	36
Push–pull [7]helicene diimide: excited-state charge transfer and solvatochromic circularly polarised luminescence	36
Concurrent base and silver(i) catalysis pulsed by fuel acid	36
A spin crossover FeII4L6 cage based on pyridyl-hydrazone sites	36
A chiral supramolecular liquid crystal based on pillararene and its application in information encryption	36
A microfluidic organic transistor for reversible and real-time monitoring of H2O2 at ppb/ppt levels in ultrapure water	36
A water-soluble cationic [2]biphenyl-extended pillar[6]arene: synthesis, host–guest interaction with hemin and application in chemodynamic/photodynamic cancer therapy	36
Microcracking of Ni-rich layered oxide does not occur at single crystal primary particles even abused at 4.7 V	36
Insight into the effects of pulsed CO2 electrolysis in a zero-gap electrolyzer	36
An ‘AND’-based ratiometric fluorescence probe for the sequential detection of biothiols and hypochlorous acid	36
Phosphine-based metal–organic layers to construct single-site heterogeneous catalysts for arene borylation	36
Ruthenium(ii)-catalyzed deoxygenation of ketones	35
Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review	35
Nucleophilic strategies to construct –CF2– linkages using borazine-CF2Ar reagents	35
Synthesis and optical properties of antimony(v) complexes of a trianionic N2O2-type tetradentate dipyrrin ligand	35
Cationic ring-opening polymerization of N-benzylaziridines to polyamines via organic boron	35
Plasmonic and nanozyme dual-channel-based logic judgment for enhancing gold nanoparticle based colorimetric Hg2+ ion sensing performance	35
Reducing binding site heterogeneity via truncation of the RTX domain enhances selectivity for rare earth element separation	35
Highly selective α-hydrogermylation of alkynes catalyzed by an in situ generated bulky NHC–cobalt complex	35
A new interphase enabled by CaI2 and Ca(BH4)2 for reversible calcium metal anodes	35
Iridium-catalyzed regioselective B(3,6)-dialkenylation or B(4)-alkenylation of o-carboranes via B–H activation and 1,2-carbon migration of alkynes	35
Harvesting mechanical energy induces piezoelectric polarization of MIL-100(Fe) for cocatalyst-free hydrogen production	35
Electrodepositing amorphous molybdenum oxides for aqueous NH4+ storage	35
From Li2NiO3 to high-performance LiNiO2 cathodes for application in Li-ion and all-solid-state batteries	35
Oxime ester-enabled anti-Markovnikov hydrosilylation of alkenes	35
Cd2(IO3)(PO4) and Cd1.62Mg0.38(IO3)(PO4): metal iodate-phosphates with large SHG responses and wide band gaps	35
High-efficiency NP-carbon dots above 60% with both delayed fluorescence and room-temperature phosphorescence	35
Key role of subsurface doping in optimizing active sites of IrO2 for the oxygen evolution reaction	35
Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents	35
Fabrication of a hierarchical nanoreactor based on COFs for cascade enzyme catalysis	35
Neutral isocyanide-templated assembly of pillar[5]arene [2] and [3]pseudorotaxanes	34
An optically reversible room-temperature solid-state cobalt(iii) photoswitch based on nitro-to-nitrito linkage isomerism	34
Photoredox radical/polar crossover enables carbo-heterofunctionalization of alkenes: facile access to 1,3-difunctionalized nitro compounds	34
Phytate-coordinated nickel foam with enriched NiOOH intermediates for 5-hydroxymethylfurfural electrooxidation	34
An acyclic aluminyl anion	34
Supramolecular localization in liquid–liquid phase separation and protein recruitment in confined droplets	34