Advanced Synthesis & Catalysis

Papers
(The TQCC of Advanced Synthesis & Catalysis is 9. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2021-08-01 to 2025-08-01.)
ArticleCitations
Front Cover Picture: Filling the Gaps in the Challenging Asymmetric Hydrogenation of Exocyclic Benzofused Alkenes with Ir−P,N Catalysts (Adv. Synth. Catal. 2/2023)132
A Gold(I)‐Catalyzed Cyclization/Semipinacol Rearrangement Cascade of 1,6‐Enynes to Access Spiro[4.5]decanes and 7‐Azaspiro[4.5]decanes103
Gold(I)‐Catalyzed Cascade Cyclization of Nitrogen or Oxygen Containing Nucleophile Tethered‐Vinylidenecyclopropanes to Pyrrole, Furan, Pyrrolidine and Piperidine Skeletons93
A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes91
Palladium‐Catalyzed Reaction of 2,3‐Allenols with Amines: Synthesis of [3]Dendralenes and 1,3‐Dienes Containing Allylic Amino and Hydroxy Groups80
Asymmetric Synthesis of N‐Substituted γ‐Amino Esters and γ‐Lactams Containing α,γ‐Stereogenic Centers via a Stereoselective Enzymatic Cascade73
Front Cover Picture: Chemo‐ and Regioselective Construction of Functionalized Isocoumarin, Flavone, and Isoquinolinedione via a One‐pot Reaction of o‐Quinol Acetate and Soft Nucleophiles71
Chiral Aminomethylbinaphthol‐Catalyzed Diastereo‐ and Enantioselective Epoxidation of Trisubstituted Acrylonitriles69
Catalyst‐Free, One‐Pot, Three‐Component Synthesis of 3‐Arylsulfonylated Thioflavones67
Copper‐Catalyzed Acylhalogenation of 3‐Methylanthranils with Acid Halides: Synthesis of N‐(2‐(2‐Haloyl)phenyl)amides62
Nickel‐Catalyzed Hydroborylative Polycyclization of Allenynes: an Atom‐Economical and Diastereoselective Synthesis of Bicyclic 5–5 Fused Rings.62
Selective α‐Deuteration of Cinnamonitriles using D2O as Deuterium Source56
Cu(III) Trifluoromethyl Complexes with 1,3‐Diketonate Ligands and Their Versatile Reactivity in C−H Trifluoromethylation54
Electrochemical Oxidative C−C Bond Functionalization of Methylenecyclopropanes with Diselenides/Ditellurides Leading to 2‐Substituted‐3,4‐Dihydronaphthalenes53
Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides53
51
Synthesis of Chiral Nine‐Membered N‐Heterocycles through Silver(I)‐Promoted Cycloaddition and Rearrangement from N‐Vinyl‐α,β‐Unsaturated Nitrones with Chiral 3‐Propioloyloxazolidin‐2‐Ones50
Synthesis of 2‐Amino‐3‐arylindoles and their Fused Analogues via Intramolecular C‐Arylation48
Constructing 5‐Methyl‐2,4‐diaryl‐1H‐imidazoles Using Calcium Carbide as Alkyne Source via A3‐Coupling Cyclization46
Site‐Selective Direct Intermolecular C(sp3)−H Alkylation of Saccharides and Switching of Reaction Sites by Changing Photocatalysts44
Copper‐Catalyzed Oxidative 1,2‐Alkylarylation of Styrenes with Unactivated C(sp3)‐H Alkanes and Electron‐Rich Aromatics via C(sp3)‐H/C(sp2)‐H Func43
Aryne‐Based Synthesis of Cyclobutadiene‐Containing Oligoacenes and Related Extended Biphenylene Derivatives43
Asymmetric Tandem Conjugate Addition and Reaction with Carbocations on Unsaturated Heterocycles42
Unusual Ring Opening of Bicyclic Terpenes During Pd‐Catalyzed Coupling with Aromatic Halides40
Synthesis of Furfural Sulfides and 4‐Alkylthiopyridines via Heterocyclization of α‐Acyl Ketene Dithioacetals40
Molecular Oxygen‐Mediated Radical Cyclization of Acrylamides with Boronic Acids40
Front Cover Picture: Catalytic Asymmetric Arylations of Ketimines (Adv. Synth. Catal. 12/2024)39
Formal Insertion of a Metal Carbene Complex into a σ‐Carbon‐Carbon Bond. Gold‐Catalyzed Synthesis of 3H‐Indoles39
Selective Formation of 2,3,5‐Trisubstituted Furans from 1,3‐Dicarbonyls and Hydroxyketones38
Cover Picture: Bench‐Stable Electrophilic Reagents for the Direct Di‐ and Trifluoroethylthiolation of Indoles (Adv. Synth. Catal. 20/2023)38
Enzymatic Dimerization of Fungal Natural Products Through Intermolecular Disulfide Bridges37
Access to 2‐Sulfonyl‐4‐arylphenols and 2,6‐Bis‐sulfonyl 5‐Aryl‐4‐arylidene‐2‐cyclohexenones via Metal Triflates‐Catalyzed Domino Cyclocondensation of 1,3‐Bis‐sulfonylacetones and 3‐Arylacroleins37
Nitrosonium Ion Catalyzed Oxidative Bromination of Arenes36
Electrochemical Stereoselective Synthesis of (Z)‐Allyl Aryl Selenides and Sulfides from Baylis‐Hillman Acetates36
Recent Advances in Organocatalytic Enantioselective Synthesis of Axially Chiral Allenes36
Martin Silicates as Partners in Photoredox/Ni Dual Catalysis for the Installation of CH3, CH2D, CD2H, CD3and13CH3Groups onto (Hetero)A36
Regio‐ and Stereoselective, Intramolecular [2+2] Cycloaddition of Allenes, Promoted by Visible Light Photocatalysis35
Cobalt‐Catalyzed Selective Transformation of Levulinic Acid and Amines into Pyrrolidines and Pyrrolidinones using Hydrogen35
Ag(I)‐Catalyzed Synthesis of 2‐Aminoquinolines from 1‐Aminobutadiynes and Anilines35
Asymmetric Synthesis of Tricycle‐Fused Dispirooxindoles via Organocatalyzed Three‐Component Cascade Reactions of 2‐Pyrones and Trifluoroethylisatin Ketimines34
Synthesis of 2‐Aminopyridines via Cobalt‐Catalyzed Cycloaddition of Diynes with N‐Substituted and N‐Unsubstituted Cyanamides34
Hypervalent Iodine‐Mediated Regioselective Dearomatization of Non‐Activated Arenes34
Witnessing the Birth of Directed Evolution of Stereoselective Enzymes as Catalysts in Organic Chemistry34
Enantioselective Syntheses of Multiply Functionalized Six‐Membered Carbocycles from Nitroalkenes and γ,δ‐Unsaturated ß‐Ketoesters using Chiral Catalysts Derived from Cobalt(III) and 1,2‐Diphenylethyle33
Tandem Enantioselective Cycloaromatization/Intramolecular Friedel–Crafts Desymmetrization of Cyclohexadienones32
Gold‐Catalyzed Annulation Between 1‐[2‐(Dimethoxymethyl)phenyl]prop‐2‐yn‐1‐yl Acetates and α‐Diazo Esters or Anilines to Form Substituted Naphthoates and Indeno[1,2‐b]quinoline, Respectively32
Divergent Reactivity of E/Z‐Azobenzene‐Based Phosphine‐Gold Catalysts: Toward an ON‐ON Catalytic Photoswitch Process32
Visible‐light‐induced and EDA Complex‐initiated Hydroxyselenization of α‐CF3 Alkenes: Access to α‐trifluoromethyl‐β‐selanyl tertiary Alcohols31
Imidazolium‐Dithiocarboxylate Zwitterions Catalysed Ring‐Opening Additions of Cyclopropenones31
Recent Advances in Transition Metal Catalysed Dearomatization Toward the Synthesis of Complex Cyclic Compounds31
Magnesium and Calcium Bisguanidinates: Catalytic Activity in the Hydroboration of Unsaturated Molecules31
Continuous Flow Technology Enabling Photochemistry31
Solvent‐ and Temperature‐Switched Chemoselectivity: Controlled Synthesis of Diverse Pyrazolo[5,1‐a]isoquinolines31
tert‐Butyl Nitrite Promoted Visible‐Light‐Induced Steric‐Hindrance‐Regulated Concurrent Cross‐Coupling and Regioselective Nitration of 3‐Alkylidene‐2‐oxindoles30
Enantioselective Synthesis of Five to Eight‐Membered P‐Stereogenic Benzo‐Fused Heterocycles via Copper‐Catalyzed Dynamic Kinetic Resolution30
Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects30
Visible Light Promoted Chan‐Lam Reaction and Cycloaddition to Prepare Chromeno[4,3‐c]isoxazolidines in One‐Pot Reaction30
First Bromide‐Catalyzed Selenylation of 2‐Alkyn‐1‐One O‐Methyloximes Enabled the Synthesis of 4‐Selenylated Isoxazoles30
Ir(I)‐Catalyzed C−H Glycosylation for Synthesis of 2‐Indolyl‐C‐Deoxyglycosides29
29
Regio‐ and Stereospecific Desulfinylative Chlorination of Spiroaziridine Oxindoles at Spiro‐Center for Formal [3+2]‐Cycloaddition with CS2: Sequential One‐Pot Synthesis of (−)‐Spirobrassini29
Direct Asymmetric Addition of Heteroatom Nucleophiles to Imines29
Tandem Asymmetric Cycloaromatization/ Intramolecular Pictet‐Spengler‐Type Reaction. An Entry to Polycyclic Pyrroles29
A Combined Halogen‐ and Chalcogen‐Bonding Organocatalyst28
One Pot Synthesis of 1,2‐Disubstituted Ethanones by Base‐Mediated Reductive Homocoupling of Aldehydes28
N−H Trifluoroethylation of Indoles and other Aromatic N‐Heterocycles with CF3CHCl2 by Copper‐Mediated Cross‐Coupling Reaction27
Renewable Platform Chemicals: The Bulk Chemicals of the Future27
Construction of α‐Pyrones and Enamine Derivatives via Divergent Transformations of β‐Aminoacrylates27
Indazolones Directed Rh(III)‐Catalyzed C−H Amidation of Arenes27
One‐Pot Synthesis of Quinazolines via Elemental Sulfur‐Mediated Oxidative Condensation of Nitriles and 2‐(Aminomethyl)anilines27
Diarylprolinol with Trifluoromethyl Substituents and Diphenylprolinol‐Derived Perfluoroalkanesulfonamide as Organocatalysts in the Cross‐Aldol Reaction of Aldehydes27
Rh(I)‐Catalyzed Decarboxylative Arylation of Alkynyl Cyclic Carbonates: Divergent Access to Substituted α‐Allenols and 1,3‐Butadienes27
Umpolung Strategy for Arene C−H Etherification Leading to Functionalized Chromanes Enabled by I(III) N‐Ligated Hypervalent Iodine Reagents27
Organocatalytic Asymmetric Synthesis of Cyclic Acetals with Spirooxindole Skeleton27
Stereoselective Synthesis of Contiguous Cyclopropylaziridines: Enabling the Construction of Versatile Chiral Molecules Including γ‐Lactams via Ring‐Opening Reactions26
2‐Bromo‐3,3,3‐Trifluoropropene: A Versatile Reagent for the Synthesis of Fluorinated Compounds26
Nickel/Copper Co‐catalyzed Enantioselective Reductive Coupling of Oxabenzonorbornadienes with Vinyl Bromides26
Interrupted CuAAC‐Thiolation for the Construction of 1,2,3‐Triazole‐Fused Eight‐Membered Heterocycles from O‐/N‐Propargyl derived Benzyl Thiosulfonates with Organic Azides26
Multifaceted Domino Knoevenagel‐Cyclization Reactions; Four Movements for 2H‐Chromenes and Chromans26
Flexible Construction of Functionalized‐Pyrroles under Palladium or Copper Catalysis in the Presence of BF3 ⋅ Et2O26
An Organocatalytic Route to endo‐Vinylene Carbonates from Carbon Dioxide‐Based exo‐Vinylene Carbonates25
Total Synthesis of the Myrioneuron Alkaloid (−)‐Schoberine B and Its Enantiomer (+)‐Schoberine B25
Cobalt(III)‐Catalyzed Aerobic Diamination of α‐Alkyl Styrenes with Anilines25
Functionalized Alkylidenecyclobutanes from a Cyclopent‐2‐enone Substrate via a Tandem Photochemical Transformation and an Allylic Substitution Protocol25
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Palladium Catalysis: Dependence of the Efficiency of C−C Bond Formation on Carboxylate Ligand and Alkali Metal Carboxylate or Carboxylic Acid Additive. Part C: The Domino Diarylation and Annelation Re25
Synthesis of Dihydropyrazoles via Palladium‐Catalyzed Cascade Heterocyclization/Carbonylation/Arylation of β,γ‐Unsaturated N‐Tosyl Hydrazones25
Front Cover Picture: Redox‐Neutral Vicarious‐Type Nucleophilic Amination of Heterocyclic N‐Oxides with Organic Azides (Adv. Synth. Catal. 19/2024)25
Remote Giese Radical Addition by Photocatalytic Ring Opening of Activated Cycloalkanols25
A Mild Metal‐Free Approach for the Direct Synthesis of Carbamoyl Azides from Carboxylic Acid Redox Active Esters25
Enantioselective Nitro‐Michael Addition Catalyzed by N‐Terminal Guanidinylated Helical Peptide25
Gold‐Catalyzed Redox‐Neutral Reaction of Nitriles with Quinoline N‐Oxides25
Special Issue Dedicated to Miquel A. Pericàs25
Phosphine‐Catalyzed (4+2) Annulation of Alkenes with Acidic Hydrogen‐Tethered Allylic Carbonates24
Catalyst‐Free and Oxidant‐Free Cascade Difluoroalkylation and Controllable C−F Bond Activation of Aryl Enol Acetates for the Synthesis of β‐Fluoroenones and β‐Enaminones24
Iron‐Catalyzed Oxyphosphorylation of Styrenes to Access β‐Ketophosphonates and α, β‐Unsaturated Ketones24
DABCO‐Promoted Selective Photochemical C−N Coupling: Access to Unsymmetrical Azahelicenes24
Photoinduced Annulation of N‐Phenylbenzamides for the Synthesis of Phenanthridin‐6(5H)‐Ones24
Catalyst‐Free Csp−Csp3Cross‐Coupling of Bromodifluoroacetamides with 1‐Iodoalkynes under Visible‐Light Irradiation24
An Umpolung Route to Amides from α‐Aminonitriles under Metal‐Free Conditions24
N,N’‐Difluoro‐2,2’‐bipyridinium Bis(tetrafluoroborate): a New Terminal Oxidant for Iodoarene‐catalyzed Fluorination Reactions24
Bidentate NHC‐Containing Ligands for Copper Catalysed Synthesis of Functionalised Diaryl Ethers23
Copper‐Catalyzed Domino Synthesis of Spiropyrazoline Oxindoles via Condensation of Indolin‐2‐One and Phenylhydrazine Derivatives23
Visible‐Light Induced Ag‐Palladacycle‐Complex‐Mediated Regioselective C−H Arylation23
K2S2O8‐Mediated Access to Alkylsulfonated Spiro[4,5] Trienones from N‐Arylpropiolamides with the Insertion of Sulfur Dioxide23
Stereoselective Synthesis of Aliphatic α‐Amino Acids by Chemo‐Enzymatic Hydroamination‐Hydrodesulfurisation23
Copper‐Catalyzed Cross Coupling Reaction of Alkyl Bromides with (DMPU)2Zn(Rf)2 Reagent: A Method for the Synthesis of Perfluoroalkylated Compounds23
The Chemistry of α‐Enolizable Alkynones: A Comprehensive Review23
Pd‐Catalyzed Ring‐Opening Defluorinative Arylation of gemDifluorocyclopropanes with Arylsilanes22
Enantioselective Vinylogous Mannich Reaction of Acyclic Vinylketene Silyl Acetals with Acyclic Ketimines22
22
Optimizing the Iodide/Iodonium/O2 Oxidation Cycle Enhances the Scope, Selectivity, and Yields of Hydroiodic Acid‐Catalyzed Multicomponent Cyclocondensation Reactions22
Synthesis of Heterospirocycles through Gold‐(I) Catalysis: Useful Building Blocks for Medicinal Chemistry22
2‐Aminoindoles and 2‐Iminoindolines as Viable Precursors of Indole‐Fused Nitrogenated Polyheterocycles22
Silver‐Mediated In‐Situ Generation of Alkynyl Selenium Intramolecular AAC Click Reactions22
K3PO4–Mediated Synthesis of Chromeno–[3,4‐c]isoxazole from 3–Nitro–2H–chromene and α–Chloro Aldehyde via Michael Addition/C−Cl Bond Cleavage/Deformylation as22
Corrigendum: Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur22
Palladium‐Catalyzed Stereoselective Intramolecular Heck Dearomative Silylation of Indoles22
Ring‐Opening Amino Esterification of Cyclic Ketones to Access Distal Amino Acid Derivatives22
Asymmetric Synthesis of Highly Substituted Spiro[2H‐pyrrole‐2,3‐Succinimide] Derivatives by Copper‐Catalyzed Post‐Ugi Reactions22
Gold‐Catalyzed Annulation of Ynamides with Aminocarbonyls as a Route to 2‐Aminoquinolines Diversely Substituted at the 4th‐Position22
Phospholanes via Twofold C‐H‐Addition to Phospholes22
Recent Progress of Electron‐Withdrawing‐Group‐Tethered Arenes Involved Asymmetric Nucleophilic Aromatic Functionalizations22
Au(I) and HOTf‐Catalyzed Cascade [5+1]‐Annulations between Allenylacetals and Diazo Esters To Form 1,3‐ and 2,3‐Disubstituted Naphthoates, Respectively22
Photo‐Catalyzed Stereospecific Synthesis of Trisubstituted Alkenes Incorporating 3,3‐Difluoro‐γ‐Lactams from Morita‐Baylis‐Hillman Acetates and N‐Allylbromodifluoroacetamides22
Copper‐Catalyzed α‐Indolmethylation of 2‐Pyridylacetates with 3‐Indoleacetic Acids via Alkylideneindolenine Intermediates21
21
Enantioselective 1,6‐Conjugate Addition of Dialkyl α‐Diazo Methylphosphonate to para‐Quinone Methides21
Asymmetric Conjugate Addition of 3‐Hydroxychromen‐4‐Ones to Electron‐Deficient Olefins Catalyzed by Recyclable C2‐Symmetric Squaramide21
Hydroaminoalkyl Functionalization of Pyrimidin‐2(1H)‐ones by Visible Light Organophotocatalysis: A Radical Approach to Biginelli‐Type Dihydropyrimidines21
Asymmetric Synthesis of Chiral α‐CF2H Spiro[Indoline‐3,3′‐Thiophene] via Phase‐Transfer Catalyzed Sulfa‐Michael/Michael Domino Reaction21
Mechanistic Insight into Palladium‐Catalyzed Asymmetric Alkylation of Indoles with Diazoesters Employing Bipyridine‐N,N’‐dioxides as Chiral Controllers21
Front Cover Picture: Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands (Adv. Synth. Catal. 7/2024)21
Copper(I)‐Catalyzed Intramolecular Cyclization of o‐Propargyloxy Diketopiperazines to Access Diverse Diazabicyclic and Spiro‐Diketopiperazinochromanes21
In Situ Generation of Copper Nanoparticle‐Graphitic Carbon Nitride Composite for Stereoselective Transfer Semihydrogenation of Alkynes: Evaluation of Catalytic Activity Using Fluorescence‐Based21
Visible Light Induced EDA‐mediated Deaminative C‐2 Alkylation of Heterocyclic‐N‐Oxides using Katritzky salts21
Dibenzoylperoxide as a Versatile Oxidant for Oxidative Azidations of Phenols Using Quaternary Ammonium Iodides or Bromides.21
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Asymmetric Hydrogenation of Tetrahydro‐γ‐Carboline Derivatives with Phosphine‐Free Ruthenium Diamine Catalysts21
Protein Engineering of d‐Succinylase from Cupriavidus sp. for d‐Amino Acid Synthesis and the Structural Implications21
Asymmetric CH Functionalization Enabled by a Traceless Oxidizing Chiral Auxiliary21
Directed Palladium‐Catalyzed pseudo‐Anomeric C−H Functionalization of Glycal‐Type Substrates: Access to Unsymmetrical gem‐Diarylmethyl C‐Glycosides20
Diradical Polar Reactivity Induced by Electricity‐Mediated Ground State Triplet Nitrenium Species20
Well‐Defined [Cp*Co(N,O)I]‐Catalysts for Site‐Selective Intramolecular C−H Amidation20
Transition‐Metal‐Catalyzed Selective Alkynylation of C−H Bonds20
Directed Nickel‐Catalyzed pseudo‐Anomeric C−H Alkynylation of Glycals as an Approach towards C‐Glycoconjugate Synthesis20
Recent Advance in Transition Metal‐Catalyzed Carboxylic Acid Guided B−H Functionalization of Carboranes20
Ru(II) Catalyzed Oxidative Dehydrogenative Annulation and Spirocyclization of Isoquinolones with N‐Substituted Maleimides20
Photoredox and Copper‐Catalyzed Sulfonylphosphorothiolation of Alkenes toward β‐Sulfonyl Phosphorothioates20
Mechanochemically Induced Cross Dehydrogenative Coupling Reactions under Ball Milling20
Palladium‐Catalyzed Chemoselective Borylation of (Poly)halogenated Aryl Triflates and Their Application in Consecutive Reactions20
Synthesis of Oxadihydrophenanthroquinolizidinones by Photoinduced Rearrangement of 3‐Biphenyl‐1‐hydroxypropyl‐pyridin‐2(1H)‐ones20
Arylation of Secondary Phosphines with Diaryliodonium Salts under Metal‐Free and Non‐Photochemical Conditions19
Multicomponent Annulative SO2 Insertion of Heteroatom‐Linked 1,7‐Diynes for Accessing Tricyclic Sulfones19
Preparation of Mesoporous Cu2O Nanospheres for Green Synthesis in the Enantioselective Boron Conjugate Addition of α,β‐Unsaturated Chiral Compounds in Aqueous Phase19
Update on the Synthesis of N‐Heterocycles via Cyclization of Hydrazones (2017–2021)19
Thianthrenium Salts to Arynes: Base Promoted C−N Bond Construction19
Molybdenum‐Catalyzed Direct Synthesis of Pyrroles from Nitroarenes with Glycols as Reductants19
DMAP‐promoted [4+2]/[3+3] Annulation Cascade Reaction of Morita–Baylis–Hillman Carbonates with Conjugated Imines to Access Functionalized Benzo[c][2,7]naphthyridine Skeletons19
Stereoselective Organocatalyzed Glycosylation of Glycosyl Trichloroacetimidate Donors: Thiouracil as Brønsted Acid Catalyst19
1,3‐Iodoesterification of 2‐Substituted Indoles via Csp2−H/Csp3−H Retained Dual Functionalization Using Hypervalent Iodine(III)19
Synthesis of 1‐Aryl Isoquinolinones or o‐Diaryl Pyrimidines via Bismuth Triflate‐Mediated Intermolecular Annulation of Arylacetic Acids with Nitroarylaldehydes or Trimethoxybenzene in the Prese19
Brønsted Acid‐Catalyzed Enantioselective and Para‐Selective Addition of Phenols to 1‐Alkynylnaphth‐2‐Ols19
A Mild Reductant NHC‐ligated Borane for N‑Formylation of Amines with CO2 under Ambient Conditions19
Stereoconvergent Access to Z‐Allylborons from E/Z‐Mixed 1,3‐Dienes via Cu‐Guanidine Catalysis19
Synthesis of Deoxysugars from Aliphatic α‐Ketoacids and Aldoses Catalyzed by Thermostable Transketolase Variants from Geobacillus stearothermophilus19
Pincer‐Ruthenium Catalyzed Oxygen Mediated Dehydrative Etherification of Alcohols and Ortho‐Alkylation of Phenols19
Modular Chiral Bithiophene‐2NO Ligands: Synthesis and Application in Asymmetric Palladium(II)‐Catalysed Friedel‐Crafts Alkylation19
One‐Pot Tandem Cyclization of β‐Oxoamides, Primary Amines, and 3‐bromo‐1,1,1‐trifluoroacetone: Synthesis of 2/4‐trifluoromethyl‐substituted dihydropyrrol‐2/4‐ols19
Photocatalytic Atom‐Transfer Radical Addition of Activated Chlorides to Alkenes19
Bromo Radical‐Mediated Photoredox Aldehyde Decarbonylation towards Transition‐Metal‐Free Hydroalkylation of Acrylamides at Room Temperature19
Amide Synthesis via Transaminative Amidation of Aromatic Aldehydes/Ketones: An Entry to 15N Isotopologs19
Front Cover Picture: (Adv. Synth. Catal. 10/2025)19
Direct Site‐Selective Deoxygenation of Benzylalcohol Derivatives19
Pyrrolidine‐Catalyzed Annulations of Quinone Monoacetals with Naphthols: Synthesis of 2‐Oxabicyclo[3.3.1]nonane Skeletons, Transformations and Reaction Mechanism18
Unexpected Stereoselective Access to 2‐Aminooxazolines from Propargyl Ureas by Silver Salts under Mild Conditions18
Synthesis of 2‐Aryl‐2H‐1,2,3‐triazoles via P(OMe)3‐Promoted Intramolecular Transannulation of 4‐Diazenylisoxazol‐5(4H)‐ones18
Synthesis of SCF3‐Substituted Sulfonium Ylides from Sulfonium Salts or α‐Bromoacetic Esters18
Synthesis of Difluorocyclopropanes via Visible‐Light‐Mediated [1+2] Cycloaddition of Diazo Esters with gem‐Difluoroalkenes and Evaluation of their Antifungal Activity18
Visible‐Light‐Enabled Photosensitizer‐ and Additive‐Free Decarboxylative Coupling Cyclization of Enaminone withN‐Arylglycine for 3‐Aminoalkyl Chromones18
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Use of Iridium‐Catalyzed Transfer Vinylation for the Synthesis of Bio‐Based (bis)‐Vinyl Ethers18
Photocatalyzed Aerobic Dearomatization of Naphthylamines under Visible‐Light Irradiation18
Multicomponent Heteroarylphosphorothiolation of Alkenes for Accessing β‐Phosphorothiolated Quinoxalinones18
Front Cover Picture: Mechanochemical Ni‐Catalysed Arylation of ortho‐Hydroxyarylenaminones: Synthesis of Isoflavones (Adv. Synth. Catal. 20/2022)18
Reaction of Indole‐2‐Carboxylates/Carboxylic Acids with Propargylic Alcohols: Dearomative Ring Expansion/Spirocyclization vs Fused Pentacyclics18
Cobalt Catalyst‐Controlled Selective Dioxygenation of Styrenes Using N‐Hydroxyphthalimide with Molecular Oxygen18
Synthesis of Functionalized 3‐(1H‐Isochromen)‐chromones via Ag2O‐Catalyzed Cascade Cyclization Reaction of o‐Hydroxyarylenaminones with o‐Alkynylbenzaldehydes18
Water‐Facilitated Nitromethane‐Mediated Cyclization of 2‐(Phenylvinyl)benzhydrols: Access to 1,3‐Diphenyl‐1H‐indenes with Antitumor Activity18
Iron Catalyzed Radical Alkylation of Cyclic Ketimines with Olefins via Metal Hydride Atom Transfer18
Peroxidation and Skeletal Rearrangement for the Synthesis of Dioxole‐2‐Carboxamide Derivatives under Continuous‐Flow Conditions18
Controllable Access to Furans and Dihydrofurans through Cyclization/Coupling of Internal Acetylenic β‐Ketoesters with Aryl Bromides18
Visible‐Light‐Induced Oxidative Carboazidation of Arylacrylamides18
Transition‐Metal‐Free Regioselective Direct C2, C4 Difunctionalization and C2, C4, C6 Trifunctionalization of Pyridines18
Electrochemically‐Driven Organocatalytic Enantioselective Oxidative Coupling of Tetrahydroisoquinolines and Acrylaldehyde18
Corrigendum: Mechanistic Insights on the Enantioselective (4+3) cycloaddition between Oxyallylcations and Furans Catalyzed by BINOL‐based Phosphoramides18
Selective Access to Sultams and Spirocyclic Sultams by the Divergent Annulations of (N‐Aryl)‐Alkynyl Sulphonamides17
An Acid Promoted, Domino Approach for the Selective Synthesis of Spirocyclic Systems#17
Facile Access to 2‐Substituted‐1,2,3,4‐Tetrahydroquinoxalines via Borane‐Catalyzed One‐Pot Tandem Cyclization/Hydrosilylation17
Asymmetric Boracarboxylation of Styrenes Using Carbon Dioxide17
Manganese‐Mediated Electrooxidative Ring‐Opening Azidation of Cyclobutanol Derivatives with TMSN317
Iron‐Catalyzed C−C and C−N Bond‐Forming Tandem Amidation Offering Access to 3‐Amino‐3‐Aminomethyl‐2‐Oxindole Frameworks17
Copper‐Catalyzed Olefinic C(sp2)−H Activation/Carbene Insertion/Ester Hydrolysis/Cyclization with Aryl Diazo Esters for the Synthesis of Multisubstituted Furanones17
TEMPO Mediated Cyclopropanols Ring Opening C−N Cross‐Coupling with Nitrogen Nucleophiles17
Rhodium(III)‐Catalyzed Redox‐Neutral Synthesis of Indenones from 2‐Aryl‐3‐nitrosoindoles with Alkynes17
Maleimide‐Controlled Formation of Indanonylpyrrolinediones and Spiroindanonylpyrrolinediones via Rh(III)‐Catalyzed C−H Activation of Sulfoxonium Ylides17
Auxiliary‐Free Remote Dearomatizative Nitrenoid Transfer for Enantioselective Construction of Spirolactams17
Silver‐Catalyzed [3+2] Cycloaddition for the Diastereoselective Synthesis of anti‐3‐Substituted Hydroindolin‐2‐Imines17
17
Modular Photochemical Flow Synthesis of Structurally Diverse Benzyne and Triazine Precursors17
Three‐Component Allylic Alkylation Reaction of α‐Diazo Ketones with Water and Allyl Carbonates for Construction of Homoallylic Alcohols17
C−N Coupling between Aryl Azides and Cyclopropanols by Photoredox/Copper Dual Catalysis17
Regioselective Construction of Indolylated Cyclic Tetrasubstituted Carbon Centers through Brønsted Acid‐Catalyzed Dearomative Skeletal Rearrangement of Azofurans17
Electrochemical α‐Functionalization of N‐Aryl‐Activated Tertiary Amines17
Iron‐Catalyzed Alkene Trifluoromethylation in Tandem with Phenol Dearomatizing Spirocyclization: Regioselective Construction of Trifluoromethylated Spirocarbocycles16
Ruppert‐Prakash Reagent (TMSCF3)‐Catalyzed Chemoselective Esterification of Weinreb Amides16
Bu4NHSO4‐Catalyzed Direct N‐Allylation of Pyrazole and its Derivatives with Allylic Alcohols in Water: A Metal‐Free, Recyclable and Sustainable System16
Synthesis of Functionalized Benzo[f]chromanes and Hydroxyalkyl Naphthols: Catalytic Coupling of Naphthols and Allylic Alcohols16
Modular Synthesis of 2,3,4,6‐Tetrasubstituted Thieno[2,3‐c]furans Based on Formal [3+2] Cycloaddition Utilizing [1,2]‐Phospha‐Brook Rearrangement / Brønsted Base‐Mediated Cyclization Strategy16
Accessing 2‐(Chalcogen)benzothiazoles via Electrochemical Intermolecular Cyclization of Isocyanides with Thiols or Diselenides16
Recent Advances in the 1,2‐Diarylation of Alkenes16
Photoinduced Transition‐Metal‐Free Chemodivergent Phosphorylation‐Peroxidation and Oxyphosphorylation of Alkenes16
Molecular Oxygen‐Induced Transamidation of Unactivated Amides in Diethyl Carbonate in the Presence of a Palladium Catalyst16
A Solely Fe‐Catalyzed Sonogashira‐Type Coupling of non‐Activated Secondary Alkyl Iodides with Terminal Alkynes16
Visible‐Light Photoredox‐Catalyzed Tandem One‐Pot Construction of C4‐Difluoroalkylated Phthalazin‐1(2H)‐Ones16
Noncovalent‐Interaction‐Dictated Product Selectivity in Intermolecular and Intramolecular Controllable Oxidation of Aromatic Amines Using 2,2′‐Diperoxyphenic Acid16
Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands16
Advances of Chiral Metal Complexes as Standalone Photocatalyst for Asymmetric Organic Transformations16
[(5+1)−1] Cyclization of Nitroepoxides to Pyridinium 1,4‐Zwitterionic Thiolates for the Synthesis of Indolizine Derivatives16
Visible‐Light‐Induced Stereoselective C(sp3)−C(sp3)−H Glycosylation for the Synthesis of C‐Glycoamino Acid Derivatives16
Synthesis of Indoline‐Fused 2,5‐Diketopiperazine Scaffolds via Ugi‐4CR in the Basic Mediated Tandem Consecutive Cyclization16
γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N‐Oxides and Nitroarenes16
Recent Advances in Cyclization Reactions of 1,6‐Enynes16
Synthesis of Monofluorocyclohexene via Photocatalytic Defluorinative [4+2] Annulation of gem‐Difluoroalkenes with Unactivated Alkenes16
One‐Pot Synthesis of 1,2,3‐Triazolo Polycyclic Systems via Copper‐Catalyzed/TsOH‐Promoted Tandem Annulation of 1,6‐Allenynes with Organic Azides16
Oxoammonium Salt‐Mediated Vicinal Oxyazidation of Alkenes with NaN3: Access to β‐Aminooxy Azides16
Synthesis of 4‐Phosphinylpyrrolidin‐3‐ones via [3+2] Cycloaddition of Nitrones with Phosphinylallenes16
Electrosynthesis of 2,5‐Disubstituted Furans through a CC Double Bond Cleavage Radical Cascade16
Controllable Synthesis of Oxa‐/Thia‐Spirohydroquinolines by [3+(2+1)] Annulation of Aromatic Amines with Bimolecular O/S‐Heterocyclic Ketones16
Copper‐Catalyzed Tandem Cyclization of 2‐(Alkynylaryl)Acetonitriles and Amines: Access to 3‐Hydroxyisoindolinones16
Strategies and Methods for the Synthesis of 2‐Pyrazolines: Recent Developments (2012–2022)16
Carboxylic acids as enabling directing groups in C−H activation and functionalization: A decade review16
Synthesis of 3‐Arylazoindoles through Iron(III)‐Catalyzed C−H Azolation of Indoles and Arylhydrazines16
Electrochemical Decarboxylative Coupling of N‐Substituted Glycines under Air: Access to C3‐Aminomethylated Imidazo[1,2‐a]pyridines16
Metal‐Free Cascade 1,4‐Conjugate Addition/Selective Annulation Strategy for Divergent Synthesis of Polysubstituted Imidazoles and 4‐Alkenylquinazolines15
Front Cover Picture: Metal‐Free, Base‐Promoted, Tandem Pericyclic Reaction: A One‐Pot Approach for Cycloheptane‐Annelated Chromones from γ‐Alkynyl‐1,3‐Diketones (Adv. Synth. Catal. 2/2022)15
RuHCl(CO)(PPh3)3‐Catalyzed Isomerization of Homoallyl Silyl Ethers and Carbonates to Allyl Silyl Ethers and Carbonates15
On‐off Pulsed Ultrasound Promote Asymmetric Noncovalent Organocatalysis “on Water”: An Investigation in Michael Addition and Diels‐Alder Reactions15
Visible Light‐Assisted Direct C−H Acyloxylation of Polycyclic Aromatic Hydrocarbons using Carboxylic Acids15
Synthesis of Secondary Trifluoromethyl Boronic Esters through Visible Light Induced Decarboxylative Alkylation Reactions15
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