Advanced Synthesis & Catalysis

Article	Citations
Ruthenium(II)‐Catalyzed Selective C(sp2)−H Acyloxylation of 2‐Aroyl‐Pyridine Derivatives with Sodium Carboxylate	134
Front Cover Picture: Synthesis of Benzo[a]fluorene, Benzo[c]fluorene, and Benzo[j]fluoranthene via a Lewis Acid‐Catalyzed Prins‐Type Cycloaromatization: Application to the Total S	121
Organocatalytic, Organic Oxidant Promoted, Enamine C−H Oxidation/Cyclopropanation Reaction	117
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Base/DMSO‐Promoted Synthesis of Benzo[4,5]imidazo[2,1‐a]isoquinolines via C−C Bond Formation	93
Front Cover Picture: Organocatalytic Enantioselective Syntheses of Flavonoids and Cannabinoids (Adv. Synth. Catal. 5/2024)	86
Solvent‐ and Temperature‐Switched Chemoselectivity: Controlled Synthesis of Diverse Pyrazolo[5,1‐a]isoquinolines	83
FeCl3/KI‐Catalyzed Tandem Oxidative Cyclization for Switchable Total Synthesis of Luotonin A, B and Derivatives	82
Weak‐Chelation Assisted Regioselective Indole C(4)‐Alkynylation via Six‐Membered Cobaltacycle Intermediate	78
Photoinduced Catalytic Alkylation of Active Methine Compounds with Nonactivated Alkenes Using Yttrium Triflate as a Lewis Acid Catalyst	72
Photoinduced Synthesis of Polycyclic γ‐Sultines by a Radical‐Polar Crossover Cyclization	62
Phosphorus Fluoride Exchange (PFEx) Click Chemistry: 2‐Substituted‐Alkynyl‐1‐Cyclotriphosphazene (SACP) Hubs for Diversity Oriented Clicking	62
Electrochemical Oxidative C−C Bond Functionalization of Methylenecyclopropanes with Diselenides/Ditellurides Leading to 2‐Substituted‐3,4‐Dihydronaphthalenes	59
Nickel‐Catalyzed Reductive Coupling of Carboxylic Acids with Disulfides to Access Thioesters	58
Chiral Iron Complexes in Asymmetric Organic Transformations	57
Unveiling the Potential of a Cobalt‐Based Metal‐Organic Framework in Carbodiimide Synthesis	52
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Formate Salts: The Rediscovery of Their Radical Reaction under Light Irradiation Opens New Avenues in Organic Synthesis	50
Transition‐Metal‐Catalyzed Transformations Involving the Heck Reaction	46
Multi‐Length Scale Communication Effects in Catalysis: Thinking Big and Acting Small	46
Access to 2‐Sulfonyl‐4‐arylphenols and 2,6‐Bis‐sulfonyl 5‐Aryl‐4‐arylidene‐2‐cyclohexenones via Metal Triflates‐Catalyzed Domino Cyclocondensation of 1,3‐Bis‐sulfonylacetones and 3‐Arylacroleins	45
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Stereospecific Indium(III)‐Catalysed Tandem Cycloisomerization of Functionalized 1,6‐enynes: Scope and Mechanistic Insights	43
Nickel‐Catalyzed Hydroborylative Polycyclization of Allenynes: an Atom‐Economical and Diastereoselective Synthesis of Bicyclic 5–5 Fused Rings.	43
Au(I)‐Catalyzed Regiodivergent Hydroarylation of Allenes for the Synthesis of Tetrahydrodiazepines or Tetrahydrodiazonines	43
Front Cover Picture: Palladium‐Catalyzed Regioselective C−H Arylation of 4‐Azaindazole at C3, C5 and C7 Positions (Adv. Synth. Catal. 16/2021)	43
Miquel Pericàs and the Creation of ICIQ	41
Aryne‐Based Synthesis of Cyclobutadiene‐Containing Oligoacenes and Related Extended Biphenylene Derivatives	41
Scalable Electrochemical Dehalogenative Carboxylation without a Sacrificial Metal Anode	41
Pd(0)‐Catalyzed‐Mediated Synthesis of Vitamin D Compounds	40
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Gold‐Catalyzed Annulation Between 1‐[2‐(Dimethoxymethyl)phenyl]prop‐2‐yn‐1‐yl Acetates and α‐Diazo Esters or Anilines to Form Substituted Naphthoates and Indeno[1,2‐b]quinoline, Respectively	38
Chemoselective Oxypalladation of (o‐Alkynylaryl)amide‐Triggered Site‐Selective C−H Annulation for Stereoselective Synthesis of Succinimide‐Fused Polycycles	37
Photoredox Hydroacylative Dearomatization of Indoles with Aromatic Carboxylic Acids	37
Phosphonamidates of Camphorsultam: Versatile Building Blocks for the Synthesis of P‐Chiral Phosphorous(V) Compounds	37
One‐Pot Synthesis of Sulfonylated 5‐Aroyl‐2‐Arylpyridines via Ruthenium‐Catalyzed and K2S2O8‐Mediated Domino Annulation of β‐Ketosulfones with DMF	37
Combined Gold and Photoredox Catalysis: Synthesis of 3‐Alkenyl‐2H‐Indazoles from 2‐Alkynylazobenzenes	36
Asymmetric Addition of Allomaltol to Chalcones and Bis(arylidene)acetones: En Route to Chiral Drugs	36
Magnesium and Calcium Bisguanidinates: Catalytic Activity in the Hydroboration of Unsaturated Molecules	36
Divergent Reactivity of E/Z‐Azobenzene‐Based Phosphine‐Gold Catalysts: Toward an ON‐ON Catalytic Photoswitch Process	35
Pyridine‐Boryl Radical‐Catalyzed [3 + 2] Cycloadditions of Alkyne‐Tethered Cyclopropyl Ketones	35
Multifunctionalization of N‐Heterocyclic Carbene Boranes by a Single Metal‐free Photocatalyst	34
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Direct Intramolecular Coupling of Primary/Secondary Alcohols with Secondary Alcohols for Macrocyclic Alkenylation Using Ni‐Zeolite Catalyst Under Continuous‐Flow Conditions	33
Copper‐Catalyzed Dearomative Cyclization of Indolyl Ynamides for Synthesis of Pentacyclic Spiroindolines	33
Synthesis of Rutaecarpine Analogues by Borrowing Hydrogen Strategy	32
Synergistic Pd/Cu Catalyzed Allylation of Cyclic Ketimine Esters with Vinylethylene Carbonates: Enantioselective Construction of Trisubstituted Allylic 2H‐Pyrrole Derivatives	31
Silver‐Catalyzed Decarboxylative Acylfluorination of Two Alkenes with Ketonic Acids	31
N‐Oxide‐Catalyzed Six‐Membered Ring Bromo‐Etherification of ϵ‐Alkenyl Alcohols	31
Synthesis of 3‐Organoselenyl Quinolines through the Reduction of Alkynes Mediated by Electrophilic Organoselenium Compounds	31
Cover Picture: Bench‐Stable Electrophilic Reagents for the Direct Di‐ and Trifluoroethylthiolation of Indoles (Adv. Synth. Catal. 20/2023)	31
Synthesis of Chiral Vicinal Amino Alcohol Derivatives via Lewis Acid‐Catalyzed Asymmetric Ring Opening of Aziridines with Alcohols and Carboxylic Acids	31
Synthesis of Triaminocyclopentadienyl Iron(II) Tricarbonyl Complexes and Application to the Synthesis of Aminophosphines	30
tert‐Butyl Nitrite Promoted Visible‐Light‐Induced Steric‐Hindrance‐Regulated Concurrent Cross‐Coupling and Regioselective Nitration of 3‐Alkylidene‐2‐oxindoles	30
Front Cover Picture: Catalytic Asymmetric Arylations of Ketimines (Adv. Synth. Catal. 12/2024)	30
Unusual Ring Opening of Bicyclic Terpenes During Pd‐Catalyzed Coupling with Aromatic Halides	30
Brønsted Acid‐Catalyzed Markovnikov Hydroarylation of Arylcyclobutene: A Route to gem‐Diaryl‐Substituted Cyclobutanes	30
Direct Synthesis of (E)‐β‐(Thiocyanato)vinyl Sulfones by 1,2‐Difunctionalization of Alkynes with Sulfinic Acids and Potassium Thiocyanate	29
Advances in α‐Hydroxylation of β‐Dicarbonyl Compounds	29
Iodine Mediated Annulation of Triethylamine, Aldehydes and 2‐Aminopyridines for the Synthesis of 3‐Formyl‐Imidazo [1,2‐a]pyridine Derivatives	29
Rapid Access to γ,γ‐Dichloroketones via Radical‐Induced Dichloromethylation and Concomitant 1,2‐Aryl Migration of Allylic Alcohols with CHCl3	28
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Organocatalytic Vinylogous Michael Addition/Cyclization Cascade of 2‐Alkylidene Indane‐1,3‐diones with Enals: A Regio‐ and Stereocontrolled Diversity‐Oriented Route to Indane‐1,3‐dione Derivatives	28
Cobalt‐Catalyzed Selective Transformation of Levulinic Acid and Amines into Pyrrolidines and Pyrrolidinones using Hydrogen	28
Synthesis of Trifluoromethylthiolated Quinolinones via Trifluoromethanesulfanamide‐Induced Electrophilic Intramolecular Cyclization of N‐Arylpropynamides	28
Synthesis of Furfural Sulfides and 4‐Alkylthiopyridines via Heterocyclization of α‐Acyl Ketene Dithioacetals	28
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Synthesis of 1,2′‐Spirobi[indene]‐1,3‐diones by Pd(II)‐Catalyzed C−H Activation and Alkynes Annulation Reaction	27
Hybrid Catalysts in Photoredox Arylation of Sodium Arylsulfinates	27
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Synthesis of Sulfonyl Arenes via Hydroxy/Amino‐Benzannulation of Sulfonyl Enynals	27
Front Cover Picture: Merging Organolithium Chemistry and Stereoselective Biocatalysis: Transformation of Aromatic Nitriles into Chiral Alcohols (Adv. Synth. Catal. 14/2024)	27

Enantioselective Syntheses of Multiply Functionalized Six‐Membered Carbocycles from Nitroalkenes and γ,δ‐Unsaturated ß‐Ketoesters using Chiral Catalysts Derived from Cobalt(III) and 1,2‐Diphenylethyle	26
Tandem Enantioselective Cycloaromatization/Intramolecular Friedel–Crafts Desymmetrization of Cyclohexadienones	26
Chiral Brønsted Acid Catalysed Kinetic Resolution of Secondary and Tertiary 3‐Amido Allylic Alcohols	26
Anhydrous Carbene Insertion Reactions: A Synthetic Platform for DNA‐Encoded Library	26
Desilylation‐Promoted Phosphine Catalysis: Intramolecular Annulation/Nucleophilic Addition Sequence of Trimethylsilylethynyl Benzoxazinanones with N‐Tosyl Imines	26
Brønsted‐Acid Mediated Synthesis of Symmetrical and Unsymmetrical Indolo[2,3‐a]carbazoles from Indoles and α‐Functionalized Ketones	26
Sequential [3+2] and [4+4] Annulation of Diynone and o‐Hydroxyaryl Azomethine Ylide: Construction of Dihydropyrrole Fused Eight‐Membered Ring Scaffold	26
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Continuous‐Flow Synthesis of β‐Ketoesters and Successive Reactions in One‐Flow using Heterogeneous Catalysis	25
Copper‐Enabled Photo‐Sulfonylation of Aryl Halides Using Alkylsulfinates	25
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Indolizine Synthesis through Annulation of Pyridinium 1,4‐Thiolates and Copper Carbenes: A Predictive Catalysis Approach	25
Cover Picture: Copper(I)‐Catalyzed Decarboxylative N‐Phosphorylation: Modular Preparation of N‐Acyl Iminophosphoranes Using Dioxazolones and Phosphines (Adv. Synth. Catal. 24/2023)	25
Front Cover Picture: Stereoselective Cyclopropanation of Boron Dipyrromethene (BODIPY) Derivatives by an Organocascade Reaction (Adv. Synth. Catal. 5/2022)	25
Nucleophilic Cyanation of Enones and Imines with Formamide as the Cyano Source	25
Synthesis of 2‐Aminopyridines via Cobalt‐Catalyzed Cycloaddition of Diynes with N‐Substituted and N‐Unsubstituted Cyanamides	25
Atroposelective Total Synthesis of (+)‐Isokotanin A via Combined Metal and Enzyme Catalysis	25
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Biocatalytic Application of a Membrane‐Bound Coumarin C‐Glucosyltransferase in the Synthesis of Coumarin and Benzofuran C‐Glucosides	24
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Copper‐Catalyzed Aerobic Benzylic C(sp3)−H Oxidation of Unprotected Aniline Derivatives for the Synthesis of Phenanthridines	24
Cobalt/Salox‐Catalyzed Stereoselective C−H Functionalization: Enantioselective Construction of Axially Chiral Cyclic Phosphinamides with P‐Stereogenic Center	24
Ag(I)‐Catalyzed Synthesis of 2‐Aminoquinolines from 1‐Aminobutadiynes and Anilines	24
Selective Formation of 2,3,5‐Trisubstituted Furans from 1,3‐Dicarbonyls and Hydroxyketones	24
Enantioselective Synthesis of Five to Eight‐Membered P‐Stereogenic Benzo‐Fused Heterocycles via Copper‐Catalyzed Dynamic Kinetic Resolution	24
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Asymmetric Metal‐Templated Approach to Amino Acids with a CF3‐Containing 3,2’‐Pyrrolidinyl Spirooxindole Core via a Michael/Mannich [3+2]‐Cycloaddition Reaction	24
Combined Electrooxidation and Proline Catalysis for Asymmetric Formal Cross‐Dehydrogenative Coupling of Benzylic Alcohols with Ketones	24
Cationic [1,5]‐Aryl Migrations of Propargyl Benzyl Ethers – A Stereospecific Approach to E‐ and Z‐Tetrasubstituted Olefins	24
Construction of Spirocyclic Compounds via Electrochemical Intramolecular Dearomatization of Benzene Derivatives	23
Iron‐Catalyzed Transfer Hydrogenation: Divergent Synthesis of Quinolines and Quinolones from ortho‐Nitrobenzyl Alcohols	23
Remote Asymmetric Bisvinylogous [4+2] Cycloaddition Reaction to Synthesize Spirocyclic Frameworks	23
One‐Pot Rh(III)‐Catalyzed Twofold C−H Activation/Oxidative Annulation of N‐Arylpyrroles with Alkynes to Fluorescent Ullazines	23
Synthesis of 2‐Amino‐3‐arylindoles and their Fused Analogues via Intramolecular C‐Arylation	23
Asymmetric Organocatalyzed Phospha‐Michael Addition for the Direct Synthesis of Biologically Active Chromenylphosphonates	23
Continuous Synthesis of Epoxides from Alkenes by Hydrogen Peroxide with Titanium Silicalite‐1 Catalyst Using Flow Reactors	23
Catalytic Asymmetric Dearomative Arylation of 2‐Naphthols Enabled by o‐Quinone Diimides	23
Copper‐Catalyzed Alkenylation and Alkenyloxylation with‐Alkenyl(phenyl)iodonium Salts	23
Halogenation/Cyanation vs. Cyanation/Halogenation of Alkenes Using ICN and BrCN	23
CORRIGENDUM: 1‐Oxa‐2,6‐Diazaspiro[3.3]‐heptane as a New Potential Piperazine Bioisostere – Flow‐Assisted Preparation and Derivatisation by Strain‐Release of Azabicyclo[1.1.0]butanes	22
Visible Light‐Induced Cyanomethyl Radical Triggered Cascade Cyclization of Phenyl‐Linked 1,6‐Enynes with a‐Halogenated Acetonitriles	22
C−C Bond Formation by Dual Pyrrolidine and Nickel Catalysis: Allylation of Ketones by Allylic Alcohols	22
Divergent Synthesis of (CF3)‐Indazolo[3,2‐a]Isoquinolines with Potent Photophysical Property and Anticancer Activity from 3‐Aryl‐1H‐Indazoles and Sulfoxonium Ylides	22
Harnessing Visible Light for the Synthesis of N‐Aryl Oxazolidines: Organocatalyzed Tandem Decarboxylation‐Cyclization	22
Electrochemical Approach Toward Mesoionic 1,2,3‐Triazole 1‐Imines	22
Expanding the Toolbox of Heterogeneous Asymmetric Organocatalysts: Bifunctional Cyclopropenimine Superbases for Enantioselective Catalysis in Batch and Continuous Flow	22
Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides	21
PTC in the Polyenolate‐Mediated [10+2]‐Cycloaddition for the Synthesis of α,α‐Disubstituted Amino Acid Precursors	21
Total Synthesis of Laetevirenol A via Regioselective Gold‐Catalyzed and Acid‐Promoted Cyclizations	21
Photochemical Synthesis of 1,4‐Dicarbonyl Containing Quinoxalin‐2(1H)‐Ones through Consecutive Photoredox Catalysis	21
TMSOTf‐Mediated Aminocyclization/[1,3]‐Sulfonyl Migration of N‐Homopropargyl Hydroxylamines for the Stereoselective Synthesis of 3‐Sulfonyl Cyclic Nitrones	21
Asymmetric [3+3] Cycloaddition of N‐Vinyl Oxindole Nitrones with 2‐Indolylmethanols to Prepare Spirooxindole[1,2]oxazines	21
Synthesis of Benzo[a]fluorene, Benzo[c]fluorene, and Benzo[j]fluoranthene via a Lewis Acid‐Catalyzed Prins‐Type Cycloaromatization: Application to the Total Synthesis of Viridistr	21
1,3‐Propanediol, an Exemplary Bio‐Renewable Organic Platform Chemical	21
Visible Light Mediated Cyclization of Ynones for the Synthesis of 3‐Alkyl N‐Fused Indoles via Csp3−H Bond Functionalization	21
Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole‐Derived Sulfide Reagent	21
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Nickel‐Catalyzed Isotopic Labeling: Synthesis of Oxygen‐18‐Labeled Esters from Amides	21
Developments for Converting Renewables to Platform Chemicals	21
Catalytic Synthesis of Atropoisomers via Non‐Canonical Friedel‐Crafts Reactions	20
Cascade Reaction of o‐Haloaryl Ynone and 2‐Hydroxy‐2‐Methylchromene: Synthesis of Chromone Derivative Enabled by Oxygen‐Migration	20
Recent Advances in the Total Synthesis of Aspidosperma and Kopsia Alkaloids Using Tetracyclic Pyridocarbazoles as Versatile Building Blocks	20
Electrochemical Stereoselective Synthesis of (Z)‐Allyl Aryl Selenides and Sulfides from Baylis‐Hillman Acetates	20
Aromatization of 1,3‐Cyclohexanedione: Modular Synthesis of 2,3‐DisubstitutedPhenols	20
Application of Sulfoxonium Ylides or Iodonium Ylides in Rhodium‐Catalyzed Synthesis of Phenanthrenes	20
Aldehyde‐Directed C(sp2)−H Functionalization under Transition‐Metal Catalysis	20
Photochemical Preparation of (Aza‐)Indolines: Diastereoselective Synthesis and Polarity Reversal Strategy	20
Enabling Regioselective Synthesis of α‐Methyl BODIPYs via H2O2/DMSO‐Promoted Direct Methylation	20
Asymmetric Catalytic Synthesis by Synergistic Chiral Phosphoric Acid Photoredox Catalyzed Reactions	20
Efficient synthesis of amino lactones vía copper‐catalysed al‐kene aminooxygenation	20
Witnessing the Birth of Directed Evolution of Stereoselective Enzymes as Catalysts in Organic Chemistry	20
Ylide‐Functionalized Diisopropyl Phosphine (prYPhos): A Ligand for Selective Suzuki‐Miyaura Couplings of Aryl Chlorides	20
Palladium‐Catalyzed Synthesis of Carbazoles by Perester	19
Gold(I)−Catalyzed Synthesis of Cyclic Sulfamides via an Intramolecular Dehydrative Amination of Allylic Alcohols: A Strategy for 1,3‐Diamine Synthesis	19
Functionalized α‐Fluorinated Amines from Imines and Enol Ethers	19
Palladium‐Catalyzed γ‐Arylation of Acylketene Synthons with Aryl Chlorides Enabled by Ylide‐Functionalized Phosphines (YPhos)	19
Selective 5‐Exo‐Dig versus 6‐Endo‐Dig Cyclization of Benzoimidazole Thiols with Propargyl Alcohols	19
Well‐Defined Ni−SNS Complex Catalysed Borrowing Hydrogenative α‐Alkylation of Ketones and Dehydrogenative Synthesis of Quinolines	19
Oxidative Cleavage of Indoles Mediated by Urea Hydrogen Peroxide or H2O2 in Polar Solvents	19

Recent Advances in the Synthesis of Fluoroalkylated Alkenes and Alkynes via Fluoroalkyl Radical Substitution Reactions	19
Oxidative Rearrangement Approach for the Ring Contraction of N−H Piperidines to Pyrrolidines	19
Cu‐Catalyzed Reaction of Trifluoromethylated β‐Keto Diazos and Nitriles Proceeding via H2O Addition to Nitrile Ylides	19
Harnessing Indole‐Derived Hydrazones for Enantioselective Synthesis of Pyrroloindolones via NHC‐Catalyzed Formal [3+2]‐Cycloaddition	19
Recent Developments in Selenylation and Thiolation of Alkenes via Three‐component Reactions	19
Front Cover Picture: Synthesis of Fluoroalkylated Pyrrolidines through Neat Reaction of Fluoroalkyl Iodides with N, N‐Diallylamines (Adv. Synth. Catal. 18/2023)	19
Tandem Asymmetric Cycloaromatization/ Intramolecular Pictet‐Spengler‐Type Reaction. An Entry to Polycyclic Pyrroles	19
Synthesis of Chiral Diazabicycloalkanes via Organocatalytic aza‐Michael/Aldol Reaction	19
Benchmarking Methanophosphocines as Versatile PIII/PV Redox Organocatalysts	19
Enzyme Cascade with Four Enzymes in One Pot for the Synthesis of L‐Phosphinothricin	19
Advancements in Asymmetric Catalytic Approaches Involving Benzoxazinone Derivatives	18
Synthesis of Chiral Nine‐Membered N‐Heterocycles through Silver(I)‐Promoted Cycloaddition and Rearrangement from N‐Vinyl‐α,β‐Unsaturated Nitrones with Chiral 3‐Propioloyloxazolidin‐2‐Ones	18
One Pot Access to 2′‐Aryl‐2,3′‐Bithiophenes via Twofold Palladium‐Catalyzed C−X/C−H Coupling Associated to a Pd‐1,4‐Migration	18
Synthesis of Perdeuterated Linoleic Acid‐d31 and Chain Deuterated 1‐Palmitoyl‐2‐linoleoyl‐sn‐glycero‐3‐phosphocholine‐d62	18
One‐Step Synthesis of Arylacetaldehydes from Aryl Aldehydes or Diaryl Ketones via One‐Carbon Extension by Using the System of DMSO/KOH/Zinc	18
Cobalt(II)‐Catalyzed Transfer Hydrogenation of Simple Alkenes	18
Regioselective Dearomatization of N‐Alkylquinolinium and Pyridinium Salts under Morita‐Baylis‐Hillman Conditions	18
Visible Light Promoted Chan‐Lam Reaction and Cycloaddition to Prepare Chromeno[4,3‐c]isoxazolidines in One‐Pot Reaction	18
The Synthesis of 5,6‐dihydrobenzo[4,5]imidazo[2,1‐a]isoquinoline Derivatives via Metal‐Free Radical Cascade Pathway	18
Copper‐Catalyzed Oxidative 1,2‐Alkylarylation of Styrenes with Unactivated C(sp3)‐H Alkanes and Electron‐Rich Aromatics via C(sp3)‐H/C(sp2)‐H Func	18
A Promoter‐free Protocol for the Synthesis of Selenophosphates and Thiophosphates via a Spontaneous Process at Room Temperature	18
Molecular Oxygen‐Mediated Radical Cyclization of Acrylamides with Boronic Acids	18
Site‐Selective C(sp3)‐H Alkenylation Using Decatungstate Anion as Photocatalyst	18
Expanding the Scope of Enantioselective Halohydrin Dehalogenases – Group B	18
Construction of Indole‐Fused Heterocycles Starting from 2‐Thioxoindolines, Iminoindolines, and Their Derivatives	18
Carbene Catalyzed Access to 3,6‐Disubstituted α‐Pyrones via Michael Addition/Lactonization/Elimination Cascade	18
Modification of the Enantioselectivity of Biocatalytic meso‐Desymmetrization for Synthesis of Both Enantiomers of cis‐1,2‐Disubstituted Cyclohexane by Amidase Engineering	18
Zinc Chelate Complexes of N‐Acyl Hydrazones as Substrates for Addition of Alkyl and Fluorinated Radicals	18
Asymmetric Synthesis of Tricycle‐Fused Dispirooxindoles via Organocatalyzed Three‐Component Cascade Reactions of 2‐Pyrones and Trifluoroethylisatin Ketimines	18
Vinylogous Hydrazone Strategy in Stereoselective Synthesis of 2,3‐Dihydro‐1H‐pyrrolizines – An Organocatalytic, Metal‐Free Route to Ketorolac	18
Transition‐Metal‐Free Synthesis of Unsymmetrical Disulfides via Three‐Component Reaction of Thiosulfonates, Thiourea and Alkyl halides	17
Front Cover Picture: Rhodium(III)‐Catalyzed Divergent C−H Functionalization of N‐Aryl Amidines with Iodonium Ylides: Access to Carbazolones and Zwitterionic Salts (Adv. Synth. Catal. 11/2023)	17
Regio‐ and Stereospecific Desulfinylative Chlorination of Spiroaziridine Oxindoles at Spiro‐Center for Formal [3+2]‐Cycloaddition with CS2: Sequential One‐Pot Synthesis of (−)‐Spirobrassini	17
Aerobic Cu(I)‐Catalyzed Site‐Selective 1,3‐Difunctionalization of Indazole through Cascade C−N and C−O Bond Formation	17
Solid Phase‐Mediated Asymmetric Palladium‐Catalyzed Hydroalkoxylation of Alkoxyallene	17
Gold(I)‐Catalyzed Carbothiolation via Rearrangement of S‐Propargyl Group: An Access to 3‐Allenyl or 3‐Indenyl Benzo[b]thiophenes	17
Asymmetric Tandem Conjugate Addition and Reaction with Carbocations on Unsaturated Heterocycles	17
Palladium‐Catalyzed Reaction of 2,3‐Allenols with Amines: Synthesis of [3]Dendralenes and 1,3‐Dienes Containing Allylic Amino and Hydroxy Groups	17
Visible‐light Induced Cerium‐catalyzed N‐Demethylation of N‐Methyl Amides under Air Conditions	17
Diastereoselective Synthesis of Chromenopyrrole Derivative Enabled by Multicomponent Reaction of Isocyanide, Allenoate, and Phenol	17
Catalyst‐Free, One‐Pot, Three‐Component Synthesis of 3‐Arylsulfonylated Thioflavones	17
Front Cover Picture: Direct Suzuki‐Miyaura Coupling of Naphthalene‐1,8‐diaminato (dan)‐Substituted Cyclopropylboron Compounds (Adv. Synth. Catal. 5/2023)	17
HAT‐Promoted Electrochemical Amination: C(sp2)−H/N−H Cross Dehydrogenative Coupling	17
Intramolecular Arylation of 2‐Bromobenzenesulfonamides Using DMSO/HCOONa ⋅ 2H2O System: An Access To Dibenzosultams	17
Rhodium(III)‐Catalyzed Aldehyde C−H Activation and Functionalization with Dioxazolones: An Entry to Imide Synthesis	17
Divergent Reaction of Allenoates: Synthesis of Polysubstituted Pyrazoles and N‐Alkylated Hydrazones	17
Recent Advances for Alkylation of Ketones and Secondary Alcohols Using Alcohols in Homogeneous Catalysis	17
Selective Intermolecular Dual Amino‐Trifluoromethylation of Alkenes by High‐Valent Cu(III)−CF3Compounds	17
Mechanochemical Transformation of CF3 Group: Synthesis of Amides and Schiff Bases	17
Rhodium‐Catalyzed Asymmetric Hydrohydrazonemethylation of Styrenes: Access to Chiral Hydrazones, Hydrazides, Hydrazines and Amines	17
Direct Synthesis of Indolines via Cyclization of Tertiary Aryl Amines with Iodonium Ylides under Sole Visible Light Irradiation	17
Radical Bicyclization of 2‐Cyanoaryl Acrylamides with Dicumyl Peroxide	17
One‐Pot Reaction of (β‐Amino‐α,α‐difluoroethyl)phosphonates with Trifluoromethylated Ketones via Aza‐Wittig Reagents	17
Filling the Gaps in the Challenging Asymmetric Hydrogenation of Exocyclic Benzofused Alkenes with Ir−P,N Catalysts	17
C−H Silylation of 2‐Arylpyridine Derivatives by Using Iridium Catalyst and Phosphine‐Borane Ligand	17
A Gold(I)‐Catalyzed Cyclization/Semipinacol Rearrangement Cascade of 1,6‐Enynes to Access Spiro[4.5]decanes and 7‐Azaspiro[4.5]decanes	17
Stereoselective Three‐Component Construction of Conjugated 1,3‐Dienes via Palladium‐Catalyzed Alkene/Allene/Carbenoid Insertion Cascade	17
Copper‐Catalyzed Acylhalogenation of 3‐Methylanthranils with Acid Halides: Synthesis of N‐(2‐(2‐Haloyl)phenyl)amides	17
A Mechanistic Probe into 1,2‐cis Glycoside Formation Catalyzed by Phenanthroline and Further Expansion of Scope	16
Synthesis of C‐3‐Functionalized Imidazo[1,2‐a]pyridines via Direct para‐Position Arylation of Electron‐Rich Anilines under Transition‐Metal‐Free Conditions	16
Silver‐Catalyzed Tandem Reaction of β‐Alkynyl Ketones toward Spiro[isochromene‐1,4′‐quinoline] with Anticancer Activities	16
Ligand Promoted and Cobalt Catalyzed Electrochemical C−H Annulation of Arylphosphinamide and Alkyne	16
Electrochemical Deoxygenative Hydrogenation and Deuteration of Aldehydes/Ketones by Protic Acids in Water	16
Photoinduced Radical Cyclization of 1,6‐Diynes: Rapid Access to Highly Substituted Carbocyclic and Heterocyclic Compounds	16
A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes	16
Substituent‐Controlled Divergent Cascade Cycloaddition Reactions of Chalcones and Arylalkynols: Access to Spiroketals and Oxa‐Bridged Fused Heterocycles	16
Direct Access to 9/6‐Fused Cycles via Sequential Hydride Shift Mediated Double C(sp3)−H Bond Functionalization	16
Site‐Selective Direct Intermolecular C(sp3)−H Alkylation of Saccharides and Switching of Reaction Sites by Changing Photocatalysts	16
One‐Pot Synthesis of Diazirines and 15N2‐Diazirines from Ketones, Aldehydes and Derivatives: Development and Mechanistic Insight	16
Photoinduced Arene C−H Amination with Ammonia: A Practical and Regioselective Strategy for Primary Amines	16
Recent Developments in Enantioselective Domino Reactions. Part A: Noble Metal Catalysts	16
Asymmetric Epoxidation of Olefins Catalyzed by Substituted Aminobenzimidazole Manganese Complexes Derived from L‐Proline	16
Asymmetric Synthesis of Spirocyclopentane Oxindoles via [2+3] Annulation with 2‐(2‐Oxoindolin‐3‐yl)malononitriles as 1,2‐Carbon Bisnucleophiles	16
Regioselective Synthesis of Emission Color‐Tunable Pyrazolo[1,5‐a]pyrimidines with β,β‐Difluoro Peroxides as 1,3‐Bis‐Electrophiles	16
Palladium‐Catalyzed Tandem γ‐Arylation/Aromatization of Cyclohex‐2‐En‐1‐One Derivatives: A Route to 3,4‐Dihydroanthracen‐1(2H)‐Ones	16
Cascade Cross‐Coupling/Spirocyclization/Formal [4+2] Cycloaddition Reactions of 3‐(2‐Isocyanoethyl)Indoles with Aromatic Azides: Access to Polycyclic Spiroindolines Bearing A Pentasubstituted Guanidin	16
Gold(I)‐Catalyzed Cascade Cyclization of Nitrogen or Oxygen Containing Nucleophile Tethered‐Vinylidenecyclopropanes to Pyrrole, Furan, Pyrrolidine and Piperidine Skeletons	16
Dehydrogenative Fluorination of gem‐Difluoroalkenes to Access Multi‐Substituted Trifluoromethylalkenes	16
Rapid Oxidation Indoles into 2‐Oxindoles Mediated by PIFA in Combination with n‐Bu4NCl ⋅ H2O	16
Harnessing Additional Capability from in Water Reaction Conditions: Aldol versus Knoevenagel Chemoselectivity	16
Gold‐Catalyzed One‐Pot Cycloisomerization/Nucleophilic Addition/Rearrangement of Acenaphthylene Carbaldehyde Derivatives	16
Synthesis of Chiral α‐Amino Ketones via Transition Metal Catalyzed or Photoredox Cross‐Coupling and Olefin Photo‐Cleavage Reaction Sequence	16
Regio‐ and Stereoselective, Intramolecular [2+2] Cycloaddition of Allenes, Promoted by Visible Light Photocatalysis	16
Triphenylcarbenium Tetrafluoroborate‐Catalyzed 1,6‐Addition of 1‐Aminobenzotriazole to p‐Quinone Methides: Synthesis of Diarylmethylamines	16
Pd‐Catalyzed Cyclization of Alkynyl Norbornene Derivatives for the Synthesis of Benzofused Heteroarenes	16
Oxidative Annulation of Aldehydes, 5‐Aminopyrazoles, and Nitriles: Synthesis and Applications of Pyrazolo[3,4‐d]Pyrimidines	16
Front Cover Picture: Chiral Binaphthyl‐Based Iodonium Salt (Hypervalent Iodine(III)) as Hydrogen‐ and Halogen‐Bonding Bifunctional Catalyst: Insight into Abnormal Counteranion Effect and Asymmetric Sy	15
Catalytic Enantioselective Oxidative Homocoupling of 2‐Acyl Imidazoles	15
Electrochemical‐In‐Situ‐Oxidative Sulfonylation of Phenols with Sulfinic Acids as an Access to Sulfonylated Hydroquinones	15
Front Cover Picture: Asymmetric Organocatalyzed Friedel–Crafts Reaction of Trihaloacetaldehydes and Phenols (Adv. Synth. Catal. 13/2022)	15
Mechanochemical Defluorinative Acylation of ortho‐Hydroxyarylenaminones by CF3‐Compounds: Synthesis of 3‐Acylchromones	15
Palladium‐Catalyzed Direct Cross‐Dehydrogenative Alkynylation of Selenophenes	15
Ruthenium‐Catalyzed Vinylene Carbonate Annulation by C−H/N−H Functionalizations: Step‐Economical Access to Indoles	15
Metal‐Catalyzed Reactivity Reversal in the Sulfonylation Reaction of α‐Allenols: Controlled Synthesis of 4‐(Arylsulfonyl)‐2,5‐Dihydrofurans	15
Silver‐Catalyzed Oxyphosphorylation of Unactivated Alkynes	15