Organic Chemistry Frontiers

Article	Citations
Pd-catalyzed site-selective C(sp 2 )–H chalcogenation of amino acids and peptides using a picolinamide auxiliary	109
Cyclocondensation reactions of racemic diastereomers of dimethyl-2-oxocyclohexanepropionic acids with ( R )-phenylglycinol: access to both enantiomers of	103
Organocatalytic asymmetric [3 + 3] annulations of 3-carboxamide oxindoles with β , γ -unsaturated	101
Construction of fluorinated tertiary allylamines via three-component photocatalytic defluorinative aminoalkylation of gem	86
Regio- and stereo-selective synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration	80
Exploring N-centered umpolung reactivity in photoredox-catalyzed amidation with an α-iminoester	77
Visible-light-promoted desulfonylative radical difluoroalkylation between difluoroenol silyl ethers and difluoroalkyl sulfones to construct functionalized aryltetrafluoroethane derivatives	77
Isothiourea-catalyzed acylation of paracyclophanols for the construction of planar chirality: the mechanism and origin of stereoselectivity	73
Rh-catalysed divergent synthesis of polysubstituted pyrroles from α,β-unsaturated ketones via selective single or double insertion of isocyanides	70
Visible light-promoted Pd-catalyzed regioselective 1,4-dicarbofunctionalization of 1,3-butadiene with unactivated bromides and malononitriles	69
Electrochemical [3 + 2]/[4 + 2] cyclization to indole-fused polycyclics	68
Computational investigation of palladium-catalyzed allene–allene cross-coupling	67
Reductive activation of arenes by potassium metal with potassium salts	66
Radical reactivity of aryl thianthrenium salts	66
The lateral lithiation of pyrazoles: direct, transition-metal-free access to pyrazolopyridinones and pyrazolopyranones	65
A gold-catalyzed cyclization/nucleophilic addition reaction of o -alkynylanilines with ynamides: stereoselective synthesis of 3-vinylindoles	63
An efficient platform for decarboxylative functionalization of carboxylic acids using sulfuryl fluoride: Pd-catalyzed decarboxylative dehydrogenation of alkanecarboxylic acids and decarboxylative cros	60
Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons	60
Gold-catalyzed formal (3 + 2) and (4 + 2) cycloadditions of alkynes to highly functionalized dihydropyrroles and tetrahydropyridines	58
Enantioselective total syntheses of (−)-mitragynine, (−)-quinine and (+)-quinidine enabled by Ir-catalysed asymmetric hydrogenation of all-carbon tetrasubstituted cycloalkenes	58
N-Heterocyclic carbene catalyzed base assisted C–C bond cleavage of cyclopropenones: an approach towards diastereoselective synthesis of azetidinones and benzoxazepines	55
Metal-free meta -halogenation of cyclic diaryliodonium salts via aryne intermediates	53
Carboxylation of C(sp 2 )–H bonds in quinolone derivatives with CO 2 : facile synthesis of quinolo	53
Hierarchical amplification of chirality in anion-coordinated tetrahedral cages	52
Contents list	52

N-Heterocycle-fused Ni( ii ) porphyrin dimers upon heating of meso -amino Ni(	52
Dihydroquinazolinones as photocatalyst-free carbamoyl radical precursors for ynamide formation	51
Repurposing trichloroacetonitrile as a sustainable radical synthon for regiodivergent photocatalytic alkene amination	49
CPL-tunable BN-embedded supramolecular macrocycles	49
Inside front cover	49
A de novo synthesis of the bisindole alkaloid geissolosimine: collective synthesis of geissoschizoline, akuammicine, (16 S	49
Rapid construction of the [5–6–6] tricyclic core of sinudenoids B–D enabled by a tandem oxidation-intramolecular Diels–Alder reaction	48
Paired electrochemical C–H bromination of (hetero)arenes with 2-bromoethan-1-ol	47
Inside front cover	46
Copper-catalyzed anti -stereoselective 1,2-silylamination of alkynes	46
Bis(pentafluorophenyl)borane-catalyzed E -selective isomerization of terminal alkenes to internal alkenes	44
Direct synthesis of gold( iii )-annulated perylene diimides via multiple C–H aurations	44
Intramolecular exciplex formation between pyrene and tetraazapyrene in supramolecular assemblies	44
Visible-light induced C(sp 3 )–S cross-coupling via electron donor–acceptor complexes and 1,2-hydrogen	44
Syntheses of 3 H -1,2,4-triazol-3-ones by copper-promoted oxidative N–N bond formation of amidines with isocyanates	42
Fe-Catalyzed B–H and N–H insertion reactions of iodonium ylides	42
Back cover	41
Palladium-catalyzed Catellani-type selective C–H silylation of aryl-TT salts	41
Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals	41
Iminophosphorane in perylenediimide chemistry: Staudinger reaction and a visible-light-driven competitive reaction of the Cadogan cyclization	41
Bromide-catalyzed oxo-amination of alkenes towards the synthesis of α-amine ketones under photoelectrocatalysis conditions	40
Photoredox-catalyzed intramolecular oxy- and aminoacylation of alkenes with acyl oxime esters: facile synthesis of acylated saturated heterocycles	40
A Cu/Cd-cocatalysed cascade reaction for constructing nitrogen-tethered 1,6-enynes enabled by 1,5-hydride transfer	40
Supramolecular chiroptical sensing by achiral AIE-active thiols	40
Back cover	40
Copper-catalyzed alkynyldisulfuration of arynes: efficient access to unsymmetrical disulfides	39
Dual photoredox/copper-catalyzed 1,4-sulfonylalkylation of alkenes	39
Synthesis of a cross-chain bridging cryptand	39
A visible light-mediated deoxygenation protocol for the synthesis of dipeptides, amides and esters without racemization	39
Fused-ring molecules based on B ← N and imide units with low energy levels	39
Elucidating the mechanism and origin of diastereoselectivity in scandium-catalyzed β-C(sp 3 )–H activation and transformation of an aliphatic aldimin	39
Bifunctional near-ultraviolet emitting materials based on hybridized local and charge-transfer (HLCT) excited states for efficient electro-fluorescence and phosphorescent OLEDs	39
Visible light-mediated syntheses of unsymmetrical methylene-bridged bis -heterocycles via an alkoxy radica	39
Iridium-catalyzed highly enantioselective and chemodivergent coupling reaction of vinyl azides and vinyl benzoxazinones	38
A nickel-catalyzed carbon–sulfur cross-coupling reaction with disulfides enabled by mechanochemistry	38
An unexpected Lewis acid-catalyzed cascade reaction of bicyclo[1.1.0]butanes with triazinanes toward biscyclobutenyl amines	38
A photo-driven traceless group directed electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation tandem reaction: access to 1-allyl/benzyl-3,4-dihydroisoquinoline	38
Modular construction of sulfinimidate esters: expanding chemical space and enabling late-stage diversification	38
The synthesis and isolation of three states of naphthalene dianhydride: radical ion, red-emissive and electron-rich zwitterion, and highly electron-deficient switchable states	38
Recent advances in trifluoroethylation reaction	38
Benzophenone-mediated deconstructive cross-coupling of secondary alcohols with data-driven mechanistic insights	37
Regiodivergent gold( i )-catalysed rearrangements in indole synthesis	37
Front cover	37
Visible light metallaphotoredox catalysis in the late-stage functionalization of pharmaceutically potent compounds	36
N-heterocyclic carbene-catalyzed decarboxylative cross-electrophile coupling to access sterically hindered ketones	36
A “sacrificial reagent” strategy for tailoring adaptive aromaticity in pyrrole rings with its application to singlet fission: a combined DFT and unsupervised machine learning study	36
One-step synthesis of polycyclic thianthrenes from unfunctionalized aromatics by thia-APEX reactions	36
Asymmetric oxidative rearrangement of indoles enabled by dual catalysis with in situ generated acyl hypoiodite and chiral phosphoric acid	35
N-Heterocyclic nitrenium-catalyzed photoreductive radical polar crossover of two distinct alkenes	35
Electrochemical switching in mechanically interlocked molecules (MIMs)	35

Emerging applications of acylsilanes in organic synthesis and beyond	35
Metal-free reductive acyldifluoroalkylation of alkenes through cooperative NHC and organophotocatalysis	34
Calix[4]pyrrole bis-crowns as ion pair receptors: cation selectivity modulated by counter anions	34
Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained	33
Interception of RCONCl 2 : late-stage hydrolysis and esterification of primary amides	33
Mechanisms of Cu/DMAP-cocatalyzed and DMAP-catalyzed C–N decarboxylative cross-coupling reactions	33
Copper( i )-catalyzed multicomponent interrupted click reaction: modular synthesis of triazole sulfides from elemental sulfur	33
Front cover	33
Inside front cover	33
Garynthone A–I, PPAPs with diverse skeletons isolated from Garcinia yunnanensis and their immunosuppressive activity	32
Mechanistic insights into the rhodium catalysed dehydrogenative cycloaddition of cyano-yne-allene substrates	32
Mechanistic insight into Ni( i )-catalyzed regioselective alkene hydroarylation: is it carbonickelation or hydronickelation?	32
Synthesis of structurally diverse silicon-incorporated indolines via silyl radical-triggered radical cascade reactions	32
Front cover	32
Photocatalyzed dehalogenative deuteration with silacarboxylic acids as halogen-atom transfer agents	32
Hydroxylation of organoborons via uranyl photocatalysis	31
Cobalt-catalyzed regioselective hydroazidation of 1-aryl-1,3-dienes: facile access to allylic azides	31
The α-alkylation of carbonyl sulfoxonium ylides: studies and applications in the synthesis of new sulfur heterocycles	30
Visible light-enabled alkylation of enol acetates with alkylboronic acids for the synthesis of α-alkyl ketones	30
Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions	30
Synthesis of fluorinated allylic alcohols via photoinduced decarboxylative cross-coupling of α-fluoroacrylic acids and alcohols	30
Inside front cover	30
Formal [5 + 2] cycloaddition of ortho -indolizinyl anilines with cyclopentenediones: access to planar indolizine-fused azepines	30
Carbene-catalyzed imine reductive reaction: a new application of Breslow intermediates	30
Aqueous-phase tunable multi-color luminescent supramolecular assemblies based on cucurbit[10]uril-enhanced intermolecular charge-transfer interactions	30
H 2 O/D 2 O as the only H/D source for photocatalytic phosphine-mediated radical transfer hydrogen	29
The synthesis of isoxazolines and dihydrooxazines by Pd-catalyzed oxyalkynylation alkenyl oximes with alkynyl bromides	29
Oxetane as a part of modern medicinal chemistry toolbox: the advanced synthesis of 3,3-disubstituted building blocks	29
Upper-rim functionalised calix[4]arenes for chemoselective Au 3+ detection	29
Inside front cover	29
Access to phosphorus-containing cyclopenta[ b ]benzofuranols via a serendipitous cascade reaction promoted	29
The stereochemistry of substitution at S( vi )	29
Front cover	28
Selective halide ion binding templation effect for a quadruple-stranded-helicate enabling the activation of C–Br bonds	28
Alkali ion-controlled chemoselective indolation of allylic alcohols by base catalysis	28
Theoretical insight: dual roles of electron-pair donors and acceptors in activating and mediating iodine atom transfer	28
New chemistry of alkynyl trifluoroborates under transition metal catalyst-free conditions	28
Back cover	28
Polyfluorinated reagents for peptide stapling	28
Tetraphenylethylene[3]arene: synthesis, structure, and sensing of I −	28
Brønsted acid-catalyzed synthesis of trifluoromethylated azulenes via cyclization of 1-phenyl-2-CF 3 -	27
t BuOK-mediated selective 1,2-silacarboxylation of arylalkenes with Si–B/Si–Si/Si–Li reagents and CO	27
Visible-light-driven, catalyst-free intramolecular crossed and straight [2 + 2] cycloaddition	27
Distal iodine migration of arylalkynes via cyclic monoaryliodonium salts	27
Transition metal-catalyzed redox-neutral 1,3-dienylation of propargylic esters and divergent synthesis	27
Sulfonamide synthesis: unlocking new pathways with aryl triflates via photocatalytic coupling	27
Conjugated figure-of-eight macrocycles derived from the anthracene photodimer: synthetic execution through intramolecular cyclization and topological manipulation through ring expansion	27
Aryl imidazoisoindoles for intrinsic 10π pericyclic photochromism with nonlinear acid responsiveness	27
Pd( ii )-catalyzed B(9)-alkynylation of o / m -carboran	27
Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones	27
Strategic convergent synthesis en route to Veratrum steroidal alkaloids	26
Photoelectrochemical hydroxymethylation and cyclization of N -aryl-2-CF 3 -acrylamides with TMSCH	26
Front cover	26
Pd-catalyzed double Heck and Heck–Suzuki cascade reaction of N -( o -bromo aryl) CF	26
Generation and application of carbodiimide anions: efficient construction of 2-aminopyrimidines via a cascade [4 + 2] annulation/aromatization sequence	26
Dithiocarbamate-mediated thioamidation of arylglyoxylic acids by decarboxylative–decarbonylative C–C bond formation reactions	26
Pyridine-based tricarboxamides: complementary monomers for supramolecular copolymerization with C 3 -symmetric oligophenyl	26
Metal-free assembly of diverse polysubstituted pyridines via an efficient cascade approach using tertiary enaminones and α,β-unsaturated sulfonylketimine	26
Facile access to indolo[2,3- b ]quinoline alkaloids via DMSO-mediated cascade cyclization: unveiling their	26
Visible-light-induced radical cascade cyclization of 2-isocyanobiaryls via 1,5-hydrogen atom transfer (1,5-HAT)	26
Access to enantioenriched dihydroquinoxalinones via Cu-catalyzed propargylic substitution	26
Back cover	26
TFPN-mediated racemization/epimerization-free amide and peptide bond formation	26
Inside front cover	26
Benzylic C–H bond functionalization through photo-mediated mesyloxy radical formation	26
Access to chiral sulfones with an all-carbon quaternary stereocenter from sulfur dioxide	26
Mechanistic insights into rhodium-catalyzed C–H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1 H )-ones	26
HBF 4 -mediated direct alcoholysis of amides under mild conditions	25
Transition-metal catalyzed reactions of diazo compounds and N , N -dialkylnitrosoamines	25
Synthesis of axially chiral biaryl-2-carboxamides through Pd( ii )-catalyzed atroposelective C–H olefination	25
Iron( ii )-catalyzed annulation to construct novel quinone-fused cyclopenta[2,1- b ]indoles: a promisi	25
BF 3 -enabled unusual (3 + 2) cycloaddition of bicyclobutanes with aldimine ester: access to 2-azabicyclo[2.1.1]hexanes	25
Palladium-catalyzed allylation of stable glycal boronates to access multi-substituted C 1-glycals: en route	25
Correction: syn -Selective carboacylation of terminal alkynes via organic photoredox and nickel catalysis	25
Electrochemical 1,2-hydrogen atom transfer functionalizations of N -(benzyloxy)phthalimides	25
Rapid and modular 1,2-carboheterofunctionalization of diverse alkenes via photoredox and RLT catalysis	25
The “cobra effect” in the imidazolinone series: how a donor can disable the nucleophilicity	24
Photocatalytic anti-Markovnikov hydroalkylation of 2-aryl enamides via 1,2-hydrogen atom transfer of amidyl radicals	24
One-pot and sustainable liquid-phase peptide extension for synthesis of C-terminal amidation peptides aided by small molecular tags	24
C–H bond halogenation: unlocking regiodivergence and enhancing selectivity through directing group strategies	24

Asymmetric total synthesis of norzoanthamine and formal synthesis of zoanthenol	24
Copper( ii )-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[ b ]indoles	24
Unveiling the mechanisms of gold/copper bimetallic catalysis in the synthesis of complex heterocyclic compounds	24
Dearomative difunctionalization of arenes via highly selective radical relay reactions	24
A simple method for N -arylation of secondary amides/amines through a NaH-initiated aryne generation strategy	24
Syntheses of 1,2,3-functionalized naphthols and phenols by decarboxylative cycloaddition/aromatization reactions of α-oxygenated lactones with allenoates or electron-deficient alkynes	23
Unraveling steric and dispersion effects in gold catalysis: a DFT study of asymmetric cyclization/Mannich reactions	23
Photocatalytic ketone synthesis: recent advances in radical-based approaches from carboxylic acids and derivatives	23
Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation	23
Modular access to bicyclo[1.1.1]pentyl alkylamines enabled by dual photoredox and tether-tunable distonic radical anion catalysis	23
Front cover	23
Formal allylic C(sp 3 )–H alkylation of α-alkylstyrenes by rearrangement of intermediate alkenyl sulfonium salts	23
NHC–amine Ru complex catalyzed selective mono- N -methylation of amines with methanol: understanding the effect of amine ligands	23
Metal-, oxidant- and base-free direct C–H amination of maleimides enabled by versatile benzohydroxamic acids	23
Modular synthesis of conjugated enamidines and cascade annulation toward benzofuran-3-oxoacetate	23
Contents list	23
From nature to synthetic analogues: recent advances in the design and synthesis of natural product-based libraries	23
Regioselective construction of 2-substituted indolines enabled by a rhodium-catalyzed decarboxylation–hydroacylation sequence	23
Recent advances in the diverse transformations of trifluoromethyl alkenes	23
Enantioselective dearomative [3 + 2] cycloaddition to access chiral spiro hydrobenzofuranpyrrolidine–benzothiophenes	23
Inside front cover	23
Front cover	22
Ir-catalyzed asymmetric transfer hydrogenation of racemic quinolinyl-substituted tertiary alcohols	22
2,7-Dinitrophenanthrene-9,10-dione as a photosensitizer for the dehydrogenative lactonization of 2-arylbenzoic acids	22
Enantioselective Mannich reaction of ketone enolates with imines through cooperative B/Cu catalysis	22
Gold catalysed regio- and chemoselective azo coupling of 1,2- and 1,4-diazoquinones with 1 H -indoles	22
Controllable synthesis of N–H or N -Me C7-substituted indazoles via a cascade reaction of α-diazo esters w	22
Electrochemical synthesis and transformation of organoboron compounds	22
Transition metal-free transfer of iodoarenes by organohypervalent iodine compounds	22
Atom-controlled divergent synthesis of spiro and fused rings via base-catalyzed chemoselective annulation	22
Enantioselective [3 + 2] annulation of tryptanthrin-derived ketimines and 2-naphthols: access to polycyclic indolo[2,1- b ]quinazoline derivatives	22
Rapid synthesis of benzofulvenes from α-bromodiarylethylenes based on a 1,4-palladium shift strategy	22
Carboxylic acid-assisted sterically demanding reductive cross-coupling between cycloalkenyl and alkyl bromides	22
Enantioselective construction of spirodihydrofuran oxindoles via one-pot organo-/iodine sequential catalysis	22
An umpolung mechanism of B(pin)-mediated Cu/B rearrangement and origin of regioselectivity for NHC-Cu-catalyzed allylation of imines	22
Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene	22
Influencing optical and charge transport properties by controlling the molecular interactions of merocyanine thin films	22
A straightforward approach to long forgotten acetophenone-derived bis-Mannich bases: synthesis, mechanistic studies, pharmacophore potential and unique trapping of N	22
Photocatalytic coupling of phenols with imines via polarity reversal	22
Visible-light-induced copper-catalyzed regiodivergent C(sp 3 )-sulfonylation of oxime esters with sodium sulfinates	22
Lewis acid-catalyzed regiodivergent N -alkylation of indazoles with donor–acceptor cyclopropanes	22
Front cover	22
N-heterocyclic nitrenium charge transfer catalysis via inner-sphere electron transfer in concert with halogen-atom dissociation	22
Transition metal-free synthesis of polyfluoroaryl sulfides via S -transfer reaction	22
Kinetic resolution of trifluoromethylated heterobenzhydrols via hydrogen-acceptor-free Ir-catalyzed heteroaryl-selective C–H silylation	22
The construction of aromatic rings by photocatalytic radical-induced cyclization reactions	22
Base-promoted transition metal-free phosphorylation/acylation of 2-vinyl pyridines with Ph 2 PCl and carboxylic acids	22
Enabling C–C bond-forming strategies for tailored derivatisation of heptazine frameworks	21
Rapid modular synthesis of indole ethers via dehydrogenative cross-coupling reaction of indoles and alcohols	21
Bridgehead epoxide iso-euphoranin E from β-caryophyllene oxide via sequential cationic formation and scission of [4.3.2]propellane	21
Catalytic alkane C–H functionalization by carbene insertion into unactivated C(sp 3 )–H bonds	21
Photo-induced redox cascade reaction of nitroarenes and amines	21
Photoredox catalyzed release of carbon-based radicals from 2-substituted-1,3-imidazolidines	21
Water-enabled α -C(sp 3 )–H amination via [1,6]-hydride	21
Facile synthesis of 5α-functionalized pyrroles via multicomponent reactions of vicinal tricarbonyl compounds, enamines, and nucleophiles	21
Direct C(sp 2 )–H activation of allenes via hydrogen-atom transfer (HAT) in organic synthesis	21
Front cover	21
Transition-metal free oxidative carbo-carboxylation of alkenes with formate in air	21
Experimental and computational studies on the palladium-catalyzed intramolecular dearomatization, electrophilic addition, intermolecular coupling sequence	21
Conformation-tunable hydrogen-bonded calix[2]aramide macrocycles: bridging aggregation-induced emission and charge-transfer host–guest chemistry	21
Imine induced metal-free C–H arylation of indoles	21
Regioselective difluoroallylation of alkylidene malonates with trifluoromethyl alkenes: synthesis of gem -difluoro-1,5-dienes and their [2 + 2] photocycl	21
Site selective Heck arylation of N -vinyl-7-azaindole engineered by N -oxide activation: scope and mechani	21
A domino [3 + 2] cycloaddition/deamination/imine hydrolysis reaction of cyclopropyl spirooxindoles with thiourea for access to spiro-γ-thiolactone oxindoles	21
A photoswitchable tetra-azo macrocycle enabling light-controlled host-in-host binding and release of cucurbit[5]uril	21
Synthesis of chiral spiro-heterocyclic azides via asymmetric [4 + 2]-cycloaddition of conjugated vinyl azides	21
Dendron-mediated control over self-assembly of chlorophyll rosettes into columnar vs. discrete aggregates	21
Contributors to the Organic Chemistry Frontiers Emerging Investigator Series 2022–2023	21
Successive energy-transfer catalytic dearomative reactions of quinolines with bicyclo[1.1.0]butanes for the synthesis of pyridine-fused 3D complicated molecules	21
Transition-metal-free synthesis of bipyridines from pyridyl pyrimidylsulfones	21
A strategy for regioselective B–H functionalization of o -carboranes via base metal catalysis	20
Diverse C(sp 3 )–H functionalizations through electrochemical benzylic oxygenation	20
A catalyst- and solvent-free visible-light-promoted bromination and chlorination of tertiary C(sp 3 )–H bonds	20
Electrochemical oxidative carbonylation of hydrazides for the synthesis of 1,3,4-oxadiazole-2(3 H )-ones	20
Electrochemical synthesis of phosphorylated Glycine-containing oligopeptides	20
A visible-light-induced cascade cyclization strategy for the synthesis of N,S-containing polycyclic compounds	20
Palladium-catalyzed bicyclization of alkynyl aryl iodide with allenyl malonates	20
Iridium-catalyzed meta-selective C–H borylation of phenol derivatives	20
Synthesis of 3,3-dialkyl-substituted isochroman-1,4-diones via copper/photoredox dual-catalyzed carbolactonization of alkenes	20
Photo-induced 1,2-alkylarylation/cyclization of alkenes, alkyl halides and N -alkylindoles via an EDA-comp	20
Cyclopropanation of N -vinylimides via a redox-neutral photocatalysed radical addition/anionic cyclisation	20
Long visible-light-driven bilin-based rotary molecular systems: from batch to microfluidic techniques	20
Higher-order dearomative [10 + 2] cycloaddition of 2-nitrobenzofurans and 2-alkylidene-1-indanones to access pentacyclic scaffolds	20
One-pot access to quinoline–chalcone hybrids via the iron-catalyzed aerobic oxidative sp 3 C–H activat	20
Decatungstate-mediated desulfonylative allylation and diacrylation using aldehydes/alkanes and allylic sulfones	20
A metal-free sigmatropic rearrangement/cyclization/aromatization cascade reaction of hydroxy/aminophenyl propargyl alcohols with fluoroalkanesulfinyl chlorides: synthesis of 3-fluoroalkanesulfonyl ben	20
Nickel-catalysed C–N cross-coupling of organoboronic acids and isoxazoles	20
Photocatalytic anti-Markovnikov addition of carboxylic acids to alkenes: an ionic mechanism under radical conditions	20
A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles	20
Physical organic origin of ligand-controlled β/γ-regiodivergence in NiH-catalyzed hydroalkylation	20
Photoinduced cross-coupling of aryl halides enabled by n -tetrabutylphosphonium phthalate	20
BX 3 -mediated borylation for the synthesis of organoboron compounds	20
N -Sulfenyl phthalimide enabled Markovnikov hydrothiolation of unactivated alkenes via ligand promoted cobalt catalysis	20
Guest-dependent folding and tunable charge transfer of an NDI-pentamer	19
Green synthesis of a 4-hydroxydithiocoumarin-imidazole bis-heterocycle scaffold, and its antiproliferative study and unusual single-crystal XRD pattern	19