Organic Chemistry Frontiers

Article	Citations
Back cover	111
Palladium-catalyzed decarboxylative domino synthesis of fused quinolin-2(1H)-one scaffolds containing a perfluoroalkyl unit	85
N-heterocyclic carbene-catalyzed decarboxylative cross-electrophile coupling to access sterically hindered ketones	79
Synthesis and antibacterial evaluation of prenylacridone alkaloids and their analogues	75
2-(1-Phenylvinyl)benzoic acid as a highly active leaving group for metal-free glycosylation	70
In situ generated cobalt(i) catalyst for the efficient synthesis of novel pyridines: revisiting the mechanism of [2 + 2 + 2] cycloadditions	67
Pd(ii) auxiliary assembling and diverse transformations via inert C(sp3)–H bond activation	65
Synthesis of challenging cyclic tetrapeptides using machine learning-assisted high-throughput continuous flow technology	62
A macrocyclic chalcogen bonding catalysis system	59
Spiroamentotaxols A–D: unprecedented 6/6/6/5/6/6/6/6 spiro-octacyclic bis-diterpene heterodimers from the endangered conifer Amentotaxus yunnanensis and their bioactivities	58
Supramolecular chiroptical sensing by achiral AIE-active thiols	57
δ-Amination of alkyl alcohols via energy transfer photocatalysis	55
Construction of axial chirality by asymmetric alpha C–H alkenylation of aryl alkenes	55
Paired electrochemical C–H bromination of (hetero)arenes with 2-bromoethan-1-ol	52
Iridium-catalyzed highly enantioselective and chemodivergent coupling reaction of vinyl azides and vinyl benzoxazinones	51
Base-induced azofluoroalkylation of unactivated alkenesviahalogen atom transfer	48
Elucidating the mechanism and origin of diastereoselectivity in scandium-catalyzed β-C(sp3)–H activation and transformation of an aliphatic aldimine	48
Enantioselective modular synthesis of α-aryl-α-heteroaryl aminonitriles with parts per million organocatalyst loading: mechanistic investigation for stereochemical origins	47
Recent advances on electrocyclic reactions in complex natural product synthesis: an update	46
Visible-light induced direct C(sp3)–H bond disulfidation of saturated N-heterocycles through a hydrogen atom transfer (HAT) process	46
Recent advances in hydrofunctionalisation of cyclopropenes via carbon–heteroatom bond formation	45
Palladium-catalyzed cross-dehydrogenative coupling of (hetero)arenes	44
Metal-free meta-halogenation of cyclic diaryliodonium salts via aryne intermediates	43
Emerging applications of acylsilanes in organic synthesis and beyond	43
A pillar[5]arene-based artificial light-harvesting system with red emission for high-resolution imaging of latent fingerprints	43

C–F bond functionalizations via fluorinated carbenes	43
Catalyst-free photoarylation reactions promoted by visible light	42
Palladium-catalyzed Catellani-type selective C–H silylation of aryl-TT salts	42
Selective deletion of one carbon atom from C60 through benzylamine mediated reactions	41
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Electrode-switchable: exploring this new strategy to achieve regiodivergent azidoiodination of alkenes	34
Chiral phosphoric acid-catalyzed enantioselective synthesis of functionalized pyrrolinones containing a geminal diamine core via an aza-Friedel–Crafts reaction of newly developed pyrrolinone ke	34
Dinuclear zinc catalyzed asymmetric [3 + 2] spiroannulation for the synthesis of diverse bispirocyclic saccharines	34
Recent developments in calix[4]pyrrole (C4P)-based supramolecular functional systems	34
Tandem Michael addition/elimination – novel reactivity of pyridinium ylides in reaction with electron-deficient alkenes	34
Furazan bis-ureas: a heterocyclic scaffold for anion binding and transport	34
“Thiol-free synthesized” and sustainable thiolating synthons for nickel-catalyzed reductive assembly of sulfides with high efficiency	34
Copper-catalyzed synthesis of cyclopropyl bis(boronates) from aryl olefins and carbon monoxide	34
A gold-catalyzed cyclization/nucleophilic addition reaction of o-alkynylanilines with ynamides: stereoselective synthesis of 3-vinylindoles	33
Gold(i)-catalyzed diastereo- and enantioselective [4 + 3] cycloadditions: construction of functionalized furano-benzoxepins	33
Recent advances in the application of ylide-like species in [4 + 1]-annulation reactions: an updated review	33
Visible-light-promoted desulfonylative radical difluoroalkylation between difluoroenol silyl ethers and difluoroalkyl sulfones to construct functionalized aryltetrafluoroethane derivatives	32
Photoinduced C–O bond cleavage for copper-catalyzed allenyl radical cyanation	32
What is the difference between mono- and biphosphine ligands? Revealing the chemoselectivity in Pd-catalysed carbenation of bromonaphthalene	32
Recent advances in the metal-catalyzed asymmetric alkene hydrogenation of cyclic conjugated carbonyl compounds	31
Cycloparaphenylene-based [2]catenanes: interlocking the carbon nanohoops	31
Photoinduced amination of iodoalkanes enabled by bifunctional O-benzoyl oxime	31
Ni-catalyzed regioselective hydrobenzylation of alkenes to afford C(sp3)–C(sp3) bonds using BH3as a reductant	31
Highly regio- and stereoselective bromochlorination and bromoazidation of 1,3-dienes	31
4,7-Diarylbenzo[c][1,2,5]thiadiazoles as fluorophores and visible light organophotocatalysts	31
Asymmetric cross Rauhut–Currier reactions of vinyl ketones with carbonylpara-quinone methidesviaphosphine catalysis	30
Stereoselective hydrodefluorination of CF3-substituted alkenes and gem-difluoroalkenes by H−	30
Synthesis of the cyclic heptapeptide core of callipeltin A	30
Electrochemical oxidative cyclization of alkenes, boronic acids, and dichalcogenides to access chalcogenated boronic esters and 1,3-diols	30
Palladium-catalysed dual ring-opening [3 + 4] annulation of isatoic anhydrides with cyclic iodoniums to build tribenzo[b,d,f]azepines and a mechanistic DFT study	30
Transition-metal-catalyst-free reaction of amides and acetonitriles: synthesis of β-ketonitriles	30
A photo-driven traceless group directed electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation tandem reaction: access to 1-allyl/benzyl-3,4-dihydroisoquinoline	29
Iron–iodine co-catalysis towards tandem C–N/C–C bond formation: one-pot regioselective synthesis of 2-amino-3-alkylindoles	29

Rhodium-catalysed regioselective [4 + 2]-type annulation of 1-H-indazoles with propargyl alcohols: direct access to 6-alkenylindazolo[3,2-a]isoquinolines	29
Kinetic vs. thermodynamic control of β-functionalized cyclic ketones: a theoretical investigation of regioselective formation of enolates	29
Visible-light-induced radical cascade reaction to prepare oxindoles via alkyl radical addition to N-arylacryl amides	29
Dearomative spiroannulation of indoles enabled by the diaza-[1,2]-Wittig rearrangement	29
Annulation of phosphole sulfides via [3 + 2] cycloaddition with nitrones	28
Aza-[4 + 2] annulations of α-vinyl Morita–Baylis–Hillman adducts for regiodivergent synthesis of exomethylene-bearing azatricyclic compounds	28
Asymmetric Sonogashira C(sp3)–C(sp) bond coupling enabled by a copper(i) complex of a new guanidine-hybrid ligand	28
Copper-catalyzed transfer methylenation via C(sp3)–C(sp3) bond cleavage of alcohols	28
Synthesis of difluoromethyl carbinols from the Friedel–Crafts reaction of electron-rich arenes with difluorovinyl arylsulfonates	28
Enantioselective sulfonylation using sodium hydrogen sulfite, 4-substituted Hantzsch esters and 1-(arylethynyl)naphthalen-2-ols	28
Enantioselective total syntheses of (−)-mitragynine, (−)-quinine and (+)-quinidine enabled by Ir-catalysed asymmetric hydrogenation of all-carbon tetrasubstituted cycloalkenes	28
Synthesis of benzothiophenes via sulfonium-[3,3]-rearrangement of aryl sulfoxides with allenenitriles	28
Mg(OtBu)2-catalyzed C–H oxidation of α-azido arylethanones using TBHP as the oxidant and carbonyl oxygen source: facile access to primary α-ketoamides	28
Catalytic C(sp)–Si cross-coupling silylation of alkynyl bromides with hydrosilanes by palladium catalysis	28
Visible light-driven copper(ii) catalyzed aerobic oxidative cleavage of carbon–carbon bonds: a combined experimental and theoretical study	27
Palladium-catalyzed intramolecular C–H amination using aluminum nitrate as the oxidant	27
Hydrogen Bonding-directed Sequential 1,6/1,4-Addition of Heteroatom Nucleophiles onto Electron-deficient 1,3-Diynes	27
dppb and TfOH promoted cascade reaction of o-nitrophenylpropiolamides to access C2-spiro-pseudoindoxyls	27
Pd/Cu catalyzed carbonylation of α-aminoaryl-tethered alkylidenecyclopropanes: synthesis of furoquinoline derivatives	27
Base-catalyzed stereoselective thiosulfonylation of ynones for the facile synthesis of thio-functionalized vinyl sulfones	27
Iron-catalyzed radical intermolecular addition of unactivated alkenes to alkenyl N-heteroarenes	27
Synthesis and immunogenicity evaluation of oligosaccharide epitopes for the development of a glycoconjugate vaccine against Streptococcus pneumoniae serotype 3	27
Straightforward α-allylation of carbonyl compounds with alkenes via α-carbonyl radical intermediates	27
Rapid mild macrocyclization of depsipeptides under continuous flow: total syntheses of five cyclodepsipeptides	27
Asymmetric total synthesis of (+)-tubingensin A	26
Synthesis of multisubstituted carbazol-4-amines from tetrahydrocarbazol-4-one oximes	26
Asymmetric Brønsted base-catalyzed aza-Michael addition and [3 + 2] cycloaddition reactions of N-ester acylhydrazones and enones	26
Isothiourea-catalysed enantioselective annulation of 2-aminobenzothiophenes with α,β-unsaturated anhydrides	26
A nickel-catalyzed carbon–sulfur cross-coupling reaction with disulfides enabled by mechanochemistry	26
Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals	26
Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization	26
Palladium-catalyzed C–Si bond formation via denitrative cross-coupling of nitroarenes with hexamethyldisilane	26
Fluoroamide-driven intermolecular hydrogen-atom-transfer-enabled intermolecular 1,2-alkylarylation of alkenes	26
Selective construction of spiro[indoline-3,5′-pyrrolo[3,4-b]azepines] and spiro[indoline-3,3′-pyrroles] via a [4 + 3]/[3 + 2] cycloaddition reaction of α,β-unsaturated aldimines and MBH	25
Synthesis of 6-azaindoles via formal electrophilic [4 + 1]-cyclization of 3-amino-4-methyl pyridines: new frontiers of diversity	25
Copper-catalyzed remote nucleophilic substitution of 5-ethynylthiophene esters	25
In situ generated aminodiborane as a reagent for deoxygenative reduction of carboxamides to amines	25
Nickel metallaphotoredox-catalyzed C–O bond activation/Csp2–Csp3 coupling enabled by phosphine	25
Phenol-mediated decarboxylative proton transfer of γ-methylidene-δ-valerolactones: an approach towards (E)-2,4-pentadienoates	25
Palladium-catalyzed aza-Wacker cyclization of O-homoallyl benzimidates: expeditious access to heteroatom-rich substituted 1,3-oxazines via alkene trifunctionalization	24
A general photoinduced oxidative strategy with molecular oxygen in water	24
Regio- and stereo-selective synthesis of β-phenylthio enamidesviaintramolecular 1,2-thiol migration	24
Palladium-catalyzed regiodivergent arylamination/aryloxygenation of allenamide	24
Insights into the mechanism and selectivity of the Rh(i)-catalyzed cycloisomerization reaction of benzylallene-alkynes involving C–H bond activation	24
Dual nickel/photoredox catalyzed carboxylation of C(sp2)-halides with formate	24
K2CO3-accelerated amidation of carboxylic acids using α-oxo ketene-N,S-acetals as amine surrogates	24
n-BuLi-promoted nucleophilic addition of unactivated C(sp3)–H bonds to diazo compounds as N-terminal electrophiles: efficient synthesis of hydrazine derivatives	24
A dearomatization–rearomatization strategy for construction of 4H-quinolizin-4-ones via C–H bond functionalization of pyridines	23
An efficient platform for decarboxylative functionalization of carboxylic acids using sulfuryl fluoride: Pd-catalyzed decarboxylative dehydrogenation of alkanecarboxylic acids and decarboxylative cros	23
C–H activation-enabled synthesis of a piperazine-embedded azadibenzo[a,g]corannulene analogue	23
Organocatalytic asymmetric [3 + 3] annulations of 3-carboxamide oxindoles with β,γ-unsaturated α-keto esters: facile access to chiral spiro-δ-lactam oxindoles	23
Iridium-catalyzed asymmetric hydrogenation of 5-hydroxypicolinate pyridinium salts under batch and flow: stereodefined access to cis-configurated hydroxypiperidine esters	23
Sequence-sorted redox-switchable hetero[3]rotaxanes	23
TBHP-promoted multicomponent reaction to access 2-aminobenzoxazinones using sodium chlorodifluoroacetate as the C1 synthon	23
Copper-catalyzed aerobic nitrogen-migration cyanation and oxygenation of unsaturated ketoximes via the CC bond cleavage: facile access to 4-oxobutanenitriles	23
Thermodynamics regulated organic hydride/acid pairs as novel organic hydrogen reductants	23
Fused-ring molecules based on B ← N and imide units with low energy levels	23
Bis(pentafluorophenyl)borane-catalyzed E-selective isomerization of terminal alkenes to internal alkenes	23
Recent development of allyl–allyl cross-coupling and its application in natural product synthesis	23
Formamidation of a wide range of substituted and functionalized amines with CO and a base	23
Cyclocondensation reactions of racemic diastereomers of dimethyl-2-oxocyclohexanepropionic acids with (R)-phenylglycinol: access to both enantiomers of dimethylcis-decahydroquinolines	23
Advanced 19F-NMR studies shed new light on encapsulation of isosteric guests in the hexameric capsules of resorcin[4]arenes and pyrogallol[4]arenes	23
Visible-light-induced [1,3]-brook rearrangements of α-ketoacylsilanes and their subsequent trapping in a tandem annulation with 1,3,5-triazinanes and azomethine imines	23
Efficient synthesis of benzophosphole oxides via Ag-promoted radical cycloisomerization	23
Electrochemically mediated synthesis of trifluoromethylallenes	22
Dynamic covalent chemistry constrained diphenylethenes: control over reactivity and luminescence both in solution and in the solid state	22
Synthesis of cyclopenta[b]benzofurans via biomimetic oxidative phenol–enamine [3 + 2] cycloaddition	22
(Pre)association as a crucial step for computational prediction and analysis of the catalytic activity of σ-hole donating organocatalysts	22
DNA-compatible functional group transformations via K2RuO4-mediated oxidation	22
Pd-catalyzed site-selective C(sp2)–H chalcogenation of amino acids and peptides using a picolinamide auxiliary	22
Sustainable synthesis of long-acting local anesthetics ropivacaine and levobupivacaine under batch and continuous flow via asymmetric hydrogenation	22
An oxanorbornene-fused nanocage consisting of hexaazatrinaphthylene and pyrene units	22
Quantification of the PO⋯HN hydrogen bond in the binding of creatinine with phosphonate calix[4]pyrroles	22
Molecular rotor based on an oxidized resorcinarene	22
Copper-catalyzed oxidative sulfenylation and alkylation of indolin-2-ones for direct construction of sulfur-substituted quaternary carbons	22
OrganocatalyticN-formylation of amines by CO2in batch and continuous flow	22
Prediction of the enantiomeric excess value for asymmetric transfer hydrogenation based on machine learning	22
Samarium(ii)-electrocatalyzed chemoselective reductive alkoxylation of phthalimides	21
Paired electrolysis enables weak Brønsted base-promoted amination of arenes with N,N-dialkyl formamides as the amine source	21
Copper-catalyzed asymmetric alkynylation of pyrazole-4,5-diones using chloramphenicol base-derived hydroxyl oxazoline ligands	21

Regio-, diastereo- and enantioselectivity in the photocatalytic generation of carbanions via hydrogen atom transfer and reductive radical-polar crossover	21
Electrochemically controlled dearomative 2,3-difunctionalization of indoles to synthesize oxoindoline derivatives	21
A copper-catalyzed B–H bond insertion reaction of azide–ynamide with borane adductsviaα-imino copper carbenes	21
Homoallenylboration of carbonyl compounds using inert 2-pinacolateboryl 1,3-butadienes via in situ generated borinic–TFA mixed anhydrides: efficient synthesis of homoallenyl alcohols	21
Synthesis of reverse glycosyl fluorides via organophotocatalytic decarboxylative fluorination of uronic acids	21
I2–DMSO mediated multicomponent convergent synthesis of imidazo[2,1-a]isoquinoline derivatives via a triple in situ cross-trapping strategy	21
Providing direction for mechanistic inferences in radical cascade cyclization using a Transformer model	21
Electrochemically driven metal-free synthesis of benzylic thioethers via C–S cross-coupling	21
Alkene insertion enables ring-opening of vinyl epoxides: a theoretical perspective	21
Palladium-catalyzed [4 + 4] cycloadditions for highly diastereo- and enantioselective synthesis of functionalized benzo[b]oxocines	21
Electrochemical oxidative dearomatization of 2-arylthiophenes	21
Asymmetric living supramolecular polymerization of an achiral aza-BODIPY dye by solvent-mediated chirality induction and memory	21
Copper-catalyzed 1,2,2-trifunctionalization of maleimides with 1,7-enynes and oxime esters via radical relay/1,5-hydrogen-atom transfer	21
Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives	20
Rhodium-catalyzed N-alkenylation of ketimines: one-pot synthesis of polysubstituted pyrroles	20
Convenient and flexible syntheses of gem-dimethyl carboxylic triggers via mono-selective β-C(sp3)–H arylation of pivalic acid with ortho-substituted aryl iodides	20
Application of a transient directing strategy in cyclization reactionsviaC–H activation	20
Metal-free Lewis-acid-catalyzed divergent trifluoromethylselenolation of alkynes: construction of α-trifluoromethylselenolated ketones and alkynes	20
Amine-catalyzed site- and stereo-selective coupling of epoxy amines and carbon dioxide to construct oxazolidinones	20
Palladium-catalyzed regio- and chemoselective double-alkoxycarbonylation of 1,3-diynes: a computational study	20
N-Heterocyclic carbene catalyzed base assisted C–C bond cleavage of cyclopropenones: an approach towards diastereoselective synthesis of azetidinones and benzoxazepines	20
I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls	20
Direct decarboxylative C–N coupling with dioxazolones mediated by a base	20
Impact of boron desymmetrization on supramolecular polymerization of BODIPY dyes	20
α-Vinyl azide–cysteine click coupling reaction enabled bioorthogonal peptide/protein modification	20
Triphenylamine-functionalized aza-BODIPY dyes: synthesis, characterization, and their application as hole transport materials in perovskite solar cells	20
The regioselectivity of the sulfonylation of tetrazoles: a theoretical view	20
Ion-pairing assemblies of anion-responsive helical PtII complexes	19
Autocatalytic photoinduced oxidative dehydrogenation of pyrido[2,3-d]pyrimidin-7(8H)-ones: synthesis of C5–C6 unsaturated systems with concomitant formation of a long-lived radical	19
Phosphine-catalyzed divergent reactivity of alkynoates with acid anhydrides: chemo- and stereoselective synthesis of polysubstituted olefins and dienes	19
Catalytic asymmetric synthesis of chiral sulfilimines via S–C bond formation	19
Tandem C–N coupling/Boulton–Katritzky rearrangement reactions of 3-aminoisoxazoles or 1,2,4-oxadiazol-3-amines with 2-pyridyl trifluoromethanesulfonate: a rapid access to [1,2,4]triazolo[1,5-a]	19
Facile single-step synthesis of pentaaryl-substituted pyrano[3,2-b]pyrrol-5(1H)-ones showing aggregation-induced emission	19
Cascade C–C bond cleavage/reformation and cycloaddition for the synthesis of 4-acyl 1,2,3-triazoles from β-alkyl nitroalkenes and organic azides	19
Selective C3–H nitration of 2-sulfanilamidopyridines withtert-butyl nitrite	19
Photoredox-catalyzed intramolecular oxy- and aminoacylation of alkenes with acyl oxime esters: facile synthesis of acylated saturated heterocycles	19
Reversibly photoswitchable catalysts for high regioselectivity and enantioselectivity in polymerization of allenes	19
Copper-mediated three-component synthesis of 2-trifluoromethyl benzimidazoles	19
A donor strapped perylene bisimide macrocycle and its lemniscate dimer with extended charge separation	19
Iminophosphorane in perylenediimide chemistry: Staudinger reaction and a visible-light-driven competitive reaction of the Cadogan cyclization	19
Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate	19
Asymmetric synthesis of pyrrolo[1,2-a]indoles via bifunctional tertiary amine catalyzed [3 + 2] annulation of 2-nitrovinylindoles with azlactones	19
Visible light-mediated syntheses of unsymmetrical methylene-bridged bis-heterocycles via an alkoxy radical relay reaction	19
Palladium-catalyzed synthesis of indene-1-acetates via sequential double carbopalladation and aryloxycarbonylation	19
Rhodium-catalyzed coupling-cyclization ofo-alkynyl/propargyl arylazides oro-azidoaryl acetylenic ketones with arylisocyanides: synthesis of 6H-indolo[2,3-b]quinolines, dibe	18
Electrocatalytic oxidative C–H cycloamination towards tricyclic [1,2,4]triazolo-[3,4-i]purine nucleosides mediated by bromide ions	18
1,3-Dipolar cycloaddition of azomethine ylides and imidoyl halides for synthesis of π-extended imidazolium salts	18
Halogen bonding and mechanochemistry combined: synthesis, characterization, and application of N-iodosaccharin pyridine complexes	18
Total synthesis of (±)-villosin C and (±)-teuvincenone B	18
Regioselective oxidative C–H heptafluoroisopropylation of heteroarenes with heptafluoroisopropyl silver	18
Visible light-induced Ni-catalyzed C–heteroatom cross-coupling of aryl halides via LMCT with DBU to access a Ni(i)/Ni(iii) cycle	18
Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons	18
Tandem synthesis of enantioenriched spirolactones via one-pot Heck–Matsuda reactions directly from nitroarenes	18
Synthesis of dihydropyrazoles enabled by Pd-catalyzed carboamination of alkenyl hydrazones with alkenyl and aryl halides	18
Palladium-catalyzed enantioselective decarboxylative allylic alkylation of α-benzyl cyanoacetates: access to chiral acyclic quaternary carbon stereocenters	18
Synthetic routes to bicyclo[1.1.1]pentylamines: booming toolkits for drug design	18
Copper-catalyzed alkynyldisulfuration of arynes: efficient access to unsymmetrical disulfides	18
External oxidant-free and selective thiofunctionalization of alkenes enabled by photoredox-neutral catalysis	18
Multi-step chirality transfer and racemization kinetics of pillar [5]arenes by tuning the halogen substituents on the rims	18
Twisted organic TADF triads based on a diindolocarbazole donor for efficient photoisomerization of stilbene and photo-arylation of heteroarenes	18
Excited-state cobaloxime catalysis enabled scalable oxidant-free dehydrogenative C–H phosphinoylation of undirected heterocycles	18
Photocatalytic hydrotrichloromethylation of unactivated alkenes with chloroform	18
Stereoselective synthesis of functionalized azepines via gold and palladium relay catalysis	18
Probing intersystem crossing in multi-brominated eumelanin through transient absorption and surface hopping dynamics	18
Chiral ruthenium porphyrin-catalyzed asymmetric cyclopropanation of 1,3-dienes with tert-butyl 2-cyano-2-diazoacetate as the carbene source	18
A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones	18
Hierarchical amplification of chirality in anion-coordinated tetrahedral cages	18
Electrochemical (radio)-halodesilylation of aromatic silanes	18
Photocatalyzed cascade hydrogen atom transfer for the construction of α-CF3-1,4-diketones	17
Transition metal free C(sp3)–C(sp3) coupling between alcohols and N-heteroarenes via a dehydrogenative SET/HAT process	17
A de novo synthesis of the bisindole alkaloid geissolosimine: collective synthesis of geissoschizoline, akuammicine, (16S)-deshydroxymethylstemmadenine and Aspidospermatan alkaloi	17
Synthesis of a luminescent macrocycle and its crystalline structure-adaptive transformation	17
Synthesis of spirocyclopropylpyrazole derivatives via the cascade reaction of alkylidenecyclopropanes with pyrazolidinones and trifluoroethanol	17
Cu-catalyzed decarboxylative annulation of proline derivatives: multi-component synthesis of functionalized chromeno[2,3-c]-pyrrol-9(1H)-one derivatives	17
Photoredox/Cu dual catalyzed 1,4-cyanosulfonylation enabled by remote cyano migration	17
Divergent synthesis of polythioindoles using elemental sulfur as the polysulfur source under metal-free conditions	17
Gold-catalyzed formal (3 + 2) and (4 + 2) cycloadditions of alkynes to highly functionalized dihydropyrroles and tetrahydropyridines	17
Visible light photoredox-catalyzed deoxydisulfuration of alcohols	17
Copper-catalyzed direct monofluoroalkenylation of C(sp3)–H bondsviadecarboxylation of α-fluoroacrylic acids	17
A visible light-mediated deoxygenation protocol for the synthesis of dipeptides, amides and esters without racemization	17
Playing with the cavity size of exTTF-based self-assembled cages	17
One-step synthesis of polycyclic thianthrenes from unfunctionalized aromatics by thia-APEX reactions	17
Skeletal editing of benzodithiol-3-ones for the assembly of benzo[d][1,3]oxathiin-4-ones	17
DBU-catalyzed dearomative annulation of 2-pyridylacetates with α,β-unsaturated pyrazolamides for the synthesis of multisubstituted 2,3-dihydro-4H-quinolizin-4-ones	17
Palladium-catalyzed multi-component Heck alkynylcarbonylation of unactivated alkenes for synthesis of β,γ-alkynoates	17
Chiral phosphoric acid-catalyzed chemo and enantioselective 1,2-addition of isatin-derived β,γ-unsaturated α-ketoesters with 4-aminoindoles at the C7 position	17
Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition	17
Electrochemical switching in mechanically interlocked molecules (MIMs)	17
Bromide-catalyzed oxo-amination of alkenes towards the synthesis of α-amine ketones under photoelectrocatalysis conditions	17
Biswulfenioidins A–E, dioxygen-bridged abietane-type diterpenoid dimers with anti-Zika virus potential from Orthosiphon wulfenioides	17
Efficient enantioselective synthesis of CF2H-containing dispiro[benzo[b]thiophene-oxindole-pyrrolidine]s via organocatalytic cycloaddition	17
Construction of sulfonated spiro[5,5]trienones from sulfur dioxide via iron-catalyzed dearomative spirocyclization of biaryls	16
Photoredox-catalyzed hydrogenation of alkenes assisted by an in situ generated PPh3(OH) radical and acetic acid	16
Photocatalytic redox-neutral arylation of cyclopropanols with cyanoarenes via radical-mediated C–C and C–CN bond cleavage	16
Base-promoted ring-opening/recyclization of naphthoquinones to access benzo[5,6][1,4]thiazino[4,3-b]isoquinoline-7,12-diones at room temperature	16