OOIR: Observatory of International Research

Papers

(The TQCC of ACS Catalysis is 27. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2021-04-01 to 2025-04-01.)

Article	Citations
Issue Publication Information	366
Issue Editorial Masthead	343
Lowering the Kinetic Barrier via the Synergistic Catalysis of N-CNTs Supported RhP Subnanoclusters and Confined Co Nanoparticles for Olefins Hydroformylation	318
Triethoxysilane-Catalyzed Single and Sequential Regioselective Hydroboration of Terminal Alkynes: Sustainable Access to E-Alkenylboronate and Alkyl Gem-Diboronate Esters by Non-Covalent	316
Mechanistic Insights into Potassium-Assistant Thermal-Catalytic Oxidation of Soot over Single-Crystalline SrTiO₃ Nanotubes with Ordered Mesopores	310
Construction of Chiral C2-Quaternary Indolines via Palladium-Catalyzed Decarboxylative Asymmetric Amination	301
Constructing Ordered Oxophilic Tin Sites on Platinum to Achieve a High-Performance and Anti-CO Poisoning Hydrogen Oxidation Reaction under an Alkaline Electrolyte	301
Discovery and Synthetic Applications of a NAD(P)H-Dependent Reductive Aminase from Rhodococcus erythropolis	291
Origin of Stereoselectivity in Ring Opening Metathesis Polymerization with Cationic Molybdenum Imido Alkylidene CAAC Complexes	285
Synthesis of Axially Chiral Vinyl Halides via Cu(I)-Catalyzed Enantioselective Radical 1,2-Halofunctionalization of Terminal Alkynes	284
Issue Editorial Masthead	258
Engineering the Atomic Configurations of Surface-Active Sites for Retuning the Photoreduction CO₂ Selectivity	257
Suzuki–Miyaura Cross-Couplings of Alkylboranes: Transmetalation Studies and Synthesis of Model Organopalladium Pretransmetalation Species	251
Descriptors for Electrochemical CO₂ Reduction in Imidazolium-Based Electrolytes	248
Molybdenum-Catalyzed Reductive Ortho-Allylation of Nitroarenes with 1,3-Dienes	235
Water-Stable Perovskite Nanocrystals to Overcome the Photocatalysis–Stability Trade-Off in Aqueous Photo-RAFT Polymerization	231
Regulation of the Properties of Hydrogen Dissociation and Transfer in the Presence of S Atoms for Efficient Hydrogenations	217
Variable Mechanisms for Cobalt-Catalyzed Alkyne Dimerization Pinpointed by Quasi-Classical Trajectory Simulations	216
Issue Editorial Masthead	211
Unified Enantioselective Allylations and Vinylogous Reactions Enabled by Visible Light-Driven Chiral Lewis Acid Catalysis	211
Repurposing Amide Bond-Forming Enzymes for Non-native Protein Modification	208
Confined Ru Nanoclusters for the Low-Temperature Cyclization of Diamines to Piperidines/Pyridines	207
Issue Publication Information	207
Manganese-Catalyzed Electrochemical Oxidation of Tryptophan-Containing Peptides and Indole Derivatives by O₂	203
Unraveling the Common Nature of O and S Doping in Improving Electrochemical O₂ Reduction Reaction Performance of FeN₄C	203

Highly Efficient CO₂ Hydrogenation to Linear α-Olefins on FeZnK Catalysts with Balanced Zn–O–Fe Interfaces and Fe₅C₂ Species	201
Ir-Catalyzed, Nitrogen-Directed C(sp³)–H and C(sp²)–H Borylation with a Spiro-Fluorene-Indenoindenyl Ligand	194
Visible-Light-Driven Catalytic Dehalogenation of Trichloroacetic Acid and α-Halocarbonyl Compounds: Multiple Roles of Copper	192
Activity Regulation of a Glutamine Amidotransferase Bienzyme Complex by Substrate-Induced Subunit Interface Expansion	191
Effective CO_x Suppression by a Na₄Mg(WO₄)₃ Promoter in Chemical Looping Oxidative Dehydrogenation of Ethane	188
Ruthenium-Catalyzed γ-Selective Intermolecular Amidation of Nonactivated Distal Methylene C–H Bonds of Terminal Alkenes via Olefin Chain-Walking Isomerization	188
Ag Size/Structure-Dependent Effect on Low-Temperature Selective Catalytic Oxidation of NH₃ over Ag/MnO₂	186
Single Cobalt Atoms Induced Molecular O₂ Activation for Enhanced Photocatalytic Biomass Upgrading on ZnIn₂S₄ Nanosheets	183
Catalytic Synergy Using Al(III) and Group 1 Metals to Accelerate Epoxide and Anhydride Ring-Opening Copolymerizations	182
Topology of DNA G-Quadruplexes Can Be Harnessed in Holliday Junction-Based DNA Suprastructures to Control and Optimize Their Biocatalytic Properties	181
Unraveling the Impact of Niobia Promotion on Pt/Al₂O₃ for Enhanced Catalytic Performance in Benzyltoluene Reactions	181
Dynamic Kinetic Resolution of Indole-Based Sulfenylated Heterobiaryls by Rhodium-Catalyzed Atroposelective Reductive Aldol Reaction	180
Electrochemical NADH Regeneration Mediated by Pyridine Amidate Iridium Complexes Interconverting 1,4- and 1,6-NADH	179
Overcoming the Activity–Stability Trade-Off in Heterogeneous Electro-Fenton Catalysis: Encapsulating Carbon Cloth-Supported Iron Oxychloride within Graphitic Layers	179
Different Oxidative Addition Mechanisms for 12- and 14-Electron Palladium(0) Explain Ligand-Controlled Divergent Site Selectivity	178
Role of Bimetallic Interactions in the Enhancement of Catalytic CO₂ Reduction by a Macrocyclic Cobalt Catalyst	176
Nickel-Catalyzed Deoxygenative Disulfuration of Alcohols to Access Unsymmetrical Disulfides	176
Chlorine-Decorated Ceria Nanocubes for Facilitating Low-Temperature Cyclohexane Oxidative Dehydrogenation: Unveiling the Decisive Role of Surface Species and Acid Properties	175
Enantioselective Synthesis of Unnatural Carbamate-Protected α-Alkyl Amino Esters via N–H Bond Insertion Reactions	175
Simultaneous Engineering of the Thermostability and Activity of a Novel Aldehyde Dehydrogenase	174
Computational Discovery of Codoped Single-Atom Catalysts for Methane-to-Methanol Conversion	172
Tailoring Surface and Penetrating Carbon in Fe-Based Catalysts to Balance the Activity and Stability of Fischer–Tropsch Synthesis	171
Predoped Oxygenated Defects Activate Nitrogen-Doped Graphene for the Oxygen Reduction Reaction	170
Designing a Bifunctional Pt/Cu-SSZ-13 Catalyst for Ammonia-Selective Catalytic Oxidation with Superior Selectivity	170
Surface Defect Engineering on Constructing High-Performance Noble Metal Active Sites: A Simple and Cost-Effective Path to High-Performance Oxidation Catalysts	168
Issue Publication Information	167
Issue Publication Information	166
Issue Editorial Masthead	163
Ligand-Controlled Nondirected meta- or para-C–H Olefination of Silyl-Protected Phenols	160
Optimizing Catalysis by Combining Molecular Scaling Relationships: Iron Porphyrin-Catalyzed Electrochemical Oxygen Reduction as a Case Study	158
Rh(II)-Catalyzed Enynal Cycloisomerization for the Generation of Vinyl Carbene: Divergent Access to Polycyclic Heterocycles	156
Break-In Bad: On the Conditioning of Fuel Cell Nanoalloy Catalysts	156
Hydrogen Bond Effects: A Strategy for Improving Controllability in Organocatalytic Photoinduced Controlled Radical Polymerization Targeting High Molecular Weight	156
Radical Reactions with N-Heterocyclic Carbene (NHC)-Derived Acyl Azoliums for Access to Multifunctionalized Ketones	154
Insights into Active Sites and Mechanisms of Benzyl Alcohol Oxidation on Nickel–Iron Oxyhydroxide Electrodes	153
Cobalt Hydride-Catalyzed Hydroalkynylation of Alkenes with Alkynyl Trifluoroborates	153
P-Stereogenic Ir-MaxPHOX: A Step toward Privileged Catalysts for Asymmetric Hydrogenation of Nonchelating Olefins	152
Reformulating Reactivity Design for Data-Efficient Machine Learning	150
Visible-Light-Mediated Ruthenium-Catalyzed para-Selective Alkylation of Unprotected Anilines	150
Elucidating the Roles of Nafion/Solvent Formulations in Copper-Catalyzed CO₂ Electrolysis	147
Selective Electrocatalytic Reduction of NO to NH₃ by Iron Porphyrins at Physiologically Relevant Potentials	147
Photoredox-Driven Three-Component Coupling of Aryl Halides, Olefins, and O₂	146
Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols with gem-Difluorinated Cyclopropanes	146
Investigations via Kinetics and Multivariate Linear Regression Models of the Mechanism and Origins of Regioselectivity in a Palladium-Catalyzed Aryne Annulation	146
Atroposelective Synthesis of N–N Axially Chiral Indoles and Pyrroles via NHC-Catalyzed Diastereoselective (3 + 3) Annulation Strategy	146
Local Magnetic Effect-Induced Electron Configuration Regulation: Spin Flipping of Iron Centers for Molecular Catalysis	145
Enantioselective Metal-Catalyzed Reductive Coupling of Alkynes with Carbonyl Compounds and Imines: Convergent Construction of Allylic Alcohols and Amines	144
Photocatalytic Reduction of Carbon Dioxide to Methane at the Pd-Supported TiO₂ Interface: Mechanistic Insights from Theoretical Studies	144
Evidence and Governing Factors of the Radical-Ion Photoredox Catalysis	143
Electrocatalytic Radical-Polar Crossover Hydroetherification of Alkenes with Phenols	143

Rate-Limiting Spin Crossover and Cp Ligand Involvement During Ir(III) Retro-Hydroformylation Catalysis	141
Issue Editorial Masthead	141
Discovery of Key Cytochrome P450 Monooxygenase (C20ox) Enables the Complete Synthesis of Tripterifordin and Neotripterifordin	141
Cycloiridated Helicenes as Chiral Catalysts in the Asymmetric Transfer Hydrogenation of Imines	141
Evolutionary Specialization of a Promiscuous Designer Enzyme	140
Efficient Photoelectrocatalysis of Glycerol to Dihydroxyacetone and Synergistic Hydrogen Generation via Dual Oxidation Pathways Using Co-LDH/Bi₂O₃/TiO₂ Ternary Array	140
Time-Domain NMR: Generating Unique Insights into the Characterization of Heterogeneous Catalysis in Liquid Phase	139
Visible-Light-Induced Energy-Transfer-Mediated Hydrofunctionalization and Difunctionalization of Unsaturated Compounds via Sigma-Bond Homolysis of Energy-Transfer Acceptors	136
Dual-Isolation Effect of Bismuth in Non-Noble BiNi Alloys for Enhanced Performance in H₂O₂ Electrosynthesis	136
Modulation of Schottky Barrier Height and Electronic Structure in Transition-Metal@Nitrogen-Doped-Carbon Core–Shell Cocatalysts Loaded with Mn_xCd_1–xS Nanorods for E	135
Enhanced Three-Component Chloro-/Azido-Fluoroalkylation of Unactivated Alkenes via the Proximity Effect in a Heterogenous Metallaphotocatalyst	135
Ligand-Controlled Copper-Catalyzed Regiodivergent Sulfonylation of Yne-Vinyl Allylic Esters with Sodium Sulfinates	134
Cobalt-Catalyzed Chemoselective π–σ–π-Type Tandem Reductive Coupling to Access Isoquinolines via Carbocobaltation of Nitriles	134
Local Electric Field Modulation of Surface Vacancies Enhances CO₂ Methanation in Pure Water	130
Machine Learning Potentials for Heterogeneous Catalysis	130
Water-Controlled Coking Dynamics during High-Pressure Methanol-to-Olefins Reaction over SAPO-34	130
Atomically Dispersed Cu Atoms Anchored on N-Doped Porous Carbon as an Efficient Catalyst for C–C Bond Cleavage of Ketones toward Esters	130
Molecular Design of Perylene Diimide Derivatives for Photocatalysis	129
Synergistic Catalyst–Mediator Pairings for Electroreductive Cross-Electrophile Coupling Reactions	129
Encapsulating Ru Nanoclusters for Reductive Imination of Biomass-Based Furfural by Shape-Selective Catalysis	129
Cesium and Phenoxide Interaction Enabled by Rh Overrides the Innate Solvent-Mediated Chemoselectivity	128
Improving C–N–FeO_x Oxygen Evolution Electrocatalysts through Hydroxyl-Modulated Local Coordination Environment	127
Acrolein Hydrogenation Catalyzed by Pt(111): Effect of Carbonaceous Deposits on Kinetics	127
Directed Evolution of an Artificial Hydroxylase Based on a Thermostable Human Carbonic Anhydrase Protein	127
Carbon Dioxide Fixation in RuBisCO Is Protonation-State-Dependent and Irreversible	126
Pd^II-Catalyzed γ-C(sp³)–H (Hetero)arylation of Ketones Enabled by Transient Directing Groups	126
Proton Transfers at the Water/Solid Interface of α-Al₂O₃–Supported Ni Clusters under Steam Reforming Conditions: An AIMD Study	125
Asymmetric Hydroxymethylative Etherification of 1,3-Dienes with Isatins and Alcohols via Pd(0)-π-Lewis Base Catalysis	124
Engineering Durable Anion Exchange Membrane Water Electrolyzers through Suppressed Electrochemical Corrosion of a NiFe–Graphitic Carbon Shell Anode Catalyst	123
Ligand Effects on Isomerization/Bond-Formation Networks in Stereodivergent Pd/Cu Dual Catalysis Involving Stereochemically Dynamic Allylpalladium Intermediates	122
Exploration of the Synergistic Effect in a One-Component Lewis Pair System: Serving as a Dual Initiator and Catalyst in the Ring-Opening Polymerization of Epoxides	122
Predicting Adhesion Energies of Metal Nanoparticles to Support Surfaces, Which Determines Metal Chemical Potential versus Particle Size and Thus Catalyst Performance	121
Late-Stage Functionalization and Diversification of Peptides by Internal Thiazole-Enabled Palladium-Catalyzed C(sp³)–H Arylation	121
Micellar N-Heterocyclic Carbene-like Organic Catalysis from Polymeric Nanoreactors Immobilizing Benzimidazolium Acetate Motifs in Their Core	121
Reconstitution of Myoglobin with Iron Porphycene Generates an Artificial Aldoxime Dehydratase with Expanded Catalytic Activities	121
Halogen-Bond-Based Organocatalysis Unveiled: Computational Design and Mechanistic Insights	120
Chemical Transformations in Supramolecular Hydrogels	120
Manganese-Catalyzed Synthesis of Polyketones Using Hydrogen-Borrowing Approach	120
Gold(I)-Catalyzed Highly Diastereo- and Enantioselective Constructions of Bicyclo[3.2.1]oct-6-ene Frameworks via (4 + 3)-Cycloadditions	119
Alkene Isomerization Catalyzed by a Mn(I) Bisphosphine Borohydride Complex	119
Cooperation of Pt and TiO_x in the Hydrogenation of Nitrobenzothiazole	119
Versatile and Facile One-Pot Biosynthesis for Amides and Carboxylic Acids in E. coli by Engineering Auxin Pathways of Plant Microbiomes	119
Cp*Rh^III/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes	118
Copper(I)-Catalyzed Asymmetric Synthesis of α-Allenylamines and β-Lactams through Regioselective Mannich-Type Reactions	118
[2 + 2] Photocycloadditions to Form Cyclobutanes and Bicyclo[2.1.1]hexanes Employing Copper-Based Photocatalysis	118
Convergent Active Site Evolution in Platinum Single Atom Catalysts for Acetylene Hydrochlorination and Implications for Toxicity Minimization	117
Iron-Carbene Initiated O–H Insertion/Aldol Cascade for the Stereoselective Synthesis of Functionalized Tetrahydrofurans	117
Geometrically Constrained Cofacial Bi-Titanium Olefin Polymerization Catalysts: Tuning and Enhancing Comonomer Incorporation Density	117
Selective Acrolein Hydrogenation over Ligand-Protected Gold Clusters: A Venus Flytrap Mechanism	116
Expanding the Reaction Network of Ethylene Epoxidation on Partially Oxidized Silver Catalysts	116
Ni-Catalyzed Desymmetric Radical Cross-Coupling Reaction to Access Axially Chiral Biaryls	116
Bifunctional NHC-Promoted C2-Alkylation of Pyridine via Ni–Al Bimetallic-Catalyzed Hydroarylation of Unactivated Alkenes	115
Unusual Facet-Dependent Sintering in Pd–TiO₂ Catalysts Revealed by Theory and Experiment	114
Structurally Informed Mutagenesis of a Stereochemically Promiscuous Aldolase Produces Mutants That Catalyze the Diastereoselective Syntheses of All Four Stereoisomers of 3-Deoxy-hexulosonic Acid	113
Nonlinear Acid Promotion of Oxidation Reactions by Mononuclear Nonheme Iron(III)-Aqua Complexes	113
Cooperativity in Diiron(III)porphyrin Dication Diradical-Catalyzed Oxa-Diels–Alder Reactions: Spectroscopic and Mechanistic Insights	113
Enhancing Ethanol Coupling to Produce Higher Alcohols by Tuning H₂ Partial Pressure over a Copper-Hydroxyapatite Catalyst	113
Mechanistic Studies and Identification of Catalyst Deactivation Pathways for Pyridine(diimine) Iron Catalyzed C(sp²)–H Borylation	112
Alcohol Solvent Assisted Synthesis of Metallic and Metal Oxide Catalysts: As-Prepared Cu/ZnO/Al₂O₃ Catalysts for Low-Temperature Methanol Synthesis with an Ultrahigh Yield	112
Visible-Light-Induced Excited-State Copper Catalysis: Recent Advances and Perspectives	112
Enantioselective Catalytic Hantzsch Dihydropyridine Synthesis	111
Flipping the Switch on Palladium-Catalyzed Carboiodination: Accessing Kinetic and Thermodynamic Products	111
Engineering Reaction Pathway to Harmonize the Competition between NRR and HER for Efficient Photocatalytic Ammonia Synthesis	111
The Interplay between Hydroxyl Coverage and Reaction Selectivity of CO Conversion over the MnOH_x/Pt Catalyst	110
Pd(0)-Catalyzed Diastereoselective and Enantioselective Intermolecular Heck–Miyaura Borylation of Internal Enamides for the β-Aminoboronate Ester Synthesis	109
One-Step Excitation Overall Water Splitting over a Modified Mg-Doped BaTaO₂N Photocatalyst	108
Homotropic Cooperativity in Iron-Catalyzed Alkyne Cyclotrimerizations	108
Aurated Aryl Cations as Halogen Abstractors – Easy Access to 1-Halogenated Naphthalenes	108
Tuning Metal-Free Hierarchical Boron Nitride-like Catalyst for Enhanced Photocatalytic CO₂ Reduction Activity	108
Microkinetic Modeling of Propene Combustion on a Stepped, Metallic Palladium Surface and the Importance of Oxygen Coverage	108
Improved Near-Neutral Hydrogen Evolution Reaction Kinetics through Electrolyte Engineering with the Efficient Hydrogen Source NH₄⁺	108
Correction to “Mixed Silver–Bismuth Oxides: A Robust Oxygen Evolution Catalyst Operating at Low pH and Elevated Temperatures”	107
Molecular Understanding of the Impact of Saline Contaminants and Alkaline pH on NiFe Layered Double Hydroxide Oxygen Evolution Catalysts	107
New Mechanistic Insights into CO₂/CO Electroreduction to Acetate by Combining Computations and Experiments	107
Size and Composition Dependence of Oxygen Reduction Reaction Catalytic Activities of Mo-Doped PtNi/C Octahedral Nanocrystals	107
Regulating the Metal–Support Interaction: Double Jump to Reach the Efficiency Apex of the Fe–N4-Catalyzed Fenton-like Reaction	107
Photochemical, Nickel-Catalyzed C(sp³)–C(sp³) Reductive Cross-Coupling of α-Silylated Alkyl Electrophiles and Allylic Sulfones	107
Effect of Perovskite-Fluorite Phase Transition on the Catalytic Activity of Pt/CeFeO_x	107
Cascade Reductive Friedel–Crafts Alkylation Catalyzed by Robust Iridium(III) Hydride Complexes Containing a Protic Triazolylidene Ligand	107
Perovskite Oxide Materials for Solar Thermochemical Hydrogen Production from Water Splitting through Chemical Looping	106

Interfacial Chemistry in the Electrocatalytic Hydrogenation of CO₂ over C-Supported Cu-Based Systems	106
Substrate Trapping in Polyketide Synthase Thioesterase Domains: Structural Basis for Macrolactone Formation	106
Shield Machine-like Substrate Walking Strategy-Based Pocket Engineering of F-Amine Dehydrogenase for Accessing Structurally Diverse Fused-Ring and Linked-Ring Aryl Ketones	105
Facile Synthesis of Vinyl Boronate Esters via Dehydrogenative Borylation of Alkenes Enabled by a Co-MOF Catalyst: An Additive-Free Approach	105
Homogeneous Tungsten Catalysis for Controllable Selective Oxidation of Anilines via the W(O)(η²-O₂)₂ Intermediate	105
Oxyl Character and Methane Hydroxylation Mechanism in Heterometallic M(O)Co₃O₄ Cubanes (M = Cr, Mn, Fe, Mo, Tc, Ru, and Rh)	105
Photoexcited Direct Amination/Amidation of Inert Csp³–H Bonds via Tungsten–Nickel Catalytic Relay	104
Black Gold-Based “Antenna–Reactor” To Activate Non-Plasmonic Nickel: Photocatalytic Hydrodechlorination and Hydrogenation Reactions	104
Mechanochemical Coupling of Catalysis and Motion in a Cellulose-Degrading Multienzyme Nanomachine	104
Size-Dependent Adsorption and Adhesion Energetics of Ag Nanoparticles on Graphene Films on Ni(111) by Calorimetry	104
Effect of Redox-Active Quinoline on the Reactivity and Mechanism of Hydrogen Evolution Reaction (HER) with Pentadentate Polypyridyl-Quinolyl Ligand-Coordinated Cobalt Complex	104
How and When Does an Enzyme React? Unraveling α-Amylase Catalytic Activity with Enhanced Sampling Techniques	104
Three-Dimensional Activity Volcano Plot under an External Electric Field	104
Enzymatic C3-Methylation of Indoles Using Methyltransferase PsmD─Crystal Structure, Catalytic Mechanism, and Preparative Applications	103
Revealing the Behavior of Interfacial Water in Te-Doped Bi via Operando Infrared Spectroscopy for Improving Electrochemical CO₂ Reduction	103
Mechanistic Insights into Superoxide Dismutation Driven by Dinuclear Manganese Complexes: The Role of the Mn₂-Core	103
Pt/B-SiO₂ as a Facile and Efficient Heterogeneous Catalyst for Enantioselective Hydrogenation: Effect of Support Modification with Boron	103
Design of Ancestral Sortase E that is Applicable in Protein Biomaterial Synthesis	103
Catalytic Enantioselective Construction of an α-Thio-Substituted α-Aminonitriles-Bearing Tetrasubstituted Carbon Center	103
Enhanced Light Alkane Oxidation under Impurity-Containing Conditions by Low-Coordinated Co–O Structures Boosting C–H Bond Activation	103
Iron-Catalyzed 5-Endo-Dig Synthetic Approach to Indenes and Its Bidirectional Extension to Narrow Bandgap π-Systems	103
Chiral Phosphate-Catalyzed Enantiodivergent Oxa-Diels–Alder Reaction of Trifluoropyruvate and Simple Dienes	102
Photoinduced Regioselective Sulfonylsulfination of Alkenes	102
Single-Atom Manganese-Based Catalysts for the Oxidative Dehydrogenation of Propane	100
Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals	100
Rhodium-Catalyzed Asymmetric Conjugate Addition to γ-Substituted α,β-Unsaturated γ-Lactams through Dynamic Kinetic Resolution: Asymmetric Synthesis of trans-β,γ-Disubstituted γ-Lactams	100
Applications of X-ray Absorption Fine Structure Spectroscopy in the Photocatalytic Conversion of Small Molecules	100
On-Demand Metal-to-Metal Electron Donation during Zr–Ru Heterodinuclear-Catalyzed Amine–Borane Dehydrogenation	99
Bifunctional Ruthenium Catalysts for endo-Selective Cycloisomerization of Nucleophile-Functionalized Terminal Alkynes	99
9-(4-Halo-2,6-xylyl)-10-methylacridinium Ion as an Effective Photoredox Catalyst for Oxygenation and Trifluoromethylation of Toluene Derivatives	99
Divergent and Synergistic Photocatalysis: Hydro- and Oxoalkylation of Vinyl Arenes for the Stereoselective Synthesis of Cyclopentanols via a Formal [4+1]-Annulation of 1,3-Dicarbonyls	99
Insights into the Multisymmetric Tailoring of Julichrome Compounds by the Oxygenases JuiN and JuiO: Enzymatic Processing around the Biaryl C–C Axis	98
Serial Femtosecond Crystallography Reveals the Role of Water in the One- or Two-Electron Redox Chemistry of Compound I in the Catalytic Cycle of the B-Type Dye-Decolorizing Peroxidase DtpB	98
Visible-Light-Driven α-Allylation of Carboxylic Acids	97
CGC-Scandium-Mediated Copolymerization of Ethylene with Amine-Functionalized Cyclic Olefins	97
Entropic Control of HD Exchange Rates over Dilute Pd-in-Au Alloy Nanoparticle Catalysts	97
Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex	97
Traceless Acetal-Directed Catalytic Hydrosilylation of Propargyl Acetates Harnessing the π-Acidic Catalyst	97
Kinetics and Mechanism of Integrated Catalytic Ammonolysis and Dehydration from Methyl Salicylate over ZnAl₂O₄ Spinel	96
Lewis Acid/Brønsted Base-Assisted Palladium Catalysis: Stereoselective Construction of Skeletally Diverse Spiro-Ketolactams from Vinylethylene Carbonates	96
Electroless Pb Monolayer Deposition—Prelude for Further Advances in Catalyst Monolayer Synthesis via Surface Limited Redox Replacement Reaction	96
True Catalytically Active Structure in Mo–V-Based Mixed Oxide Catalysts for Selective Oxidation of Acrolein	96
GH47 and Other Glycoside Hydrolases Catalyze Glycosidic Bond Cleavage with the Assistance of Substrate Super-Arming at the Transition State	95
Highly Selective Semihydrogenation via a Wettability-Regulated Mass Transfer Process	94
Biosynthesis of Guatrypmethine C Implies Two Different Oxidases for exo Double Bond Installation at the Diketopiperazine Ring	94
Elucidation of the Stereochemical Mechanism of Cystathionine γ-Lyase Reveals How Substrate Specificity Constrains Catalysis	94
Deactivation by Potassium Accumulation on a Pt/TiO₂ Bifunctional Catalyst for Biomass Catalytic Fast Pyrolysis	94
Synergistic Effects of Boron and Oxygen Interaction Enabling Nickel-Catalyzed Exogenous Base-Free Stereoselective Arylvinylation of Alkynes through Vinyl Transposition	94
Solution-State Catalysis of Visible Light-Driven Water Oxidation by Macroanion-Like Inorganic Complexes of γ-FeOOH Nanocrystals	93
Combined Computational and Experimental Investigation on the Mechanism of CO₂ Hydrogenation to Methanol with Mn-PNP-Pincer Catalysts	93
Designing Reactive Bridging O^2– at the Atomic Cu–O–Fe Site for Selective NH₃ Oxidation	93
Heteronuclear Dual Single-Atom Catalysts for Ambient Conversion of CO₂ from Air to Formate	92
Cu-Catalyzed C_(sp3)–N Coupling and Alkene Carboamination Enabled by Ligand-Promoted Selective Hydrazine Transfer to Alkyl Radicals	92
MOF-Derived RuCo Catalyzes the Formation of a Plasticizer Alcohol from Renewable Precursors	92
Hierarchical BEA Zeolite with Trimodal Micro-/Meso-/Macroporosity as a Selective and Long-Lived Catalyst for Isobutane/2-Butene Alkylation	92
Elucidating the Mechanism of Ambient-Temperature Aldol Condensation of Acetaldehyde on Ceria	92
Catalytic Asymmetric Hydroalkylation of α,β-Unsaturated Amides Enabled by Regio-Reversed and Enantiodifferentiating syn-Hydronickellation	91
Capturing the Elusive [Ru^V═O]⁺ Intermediate in Water Oxidation	91
Mapping of the Reaction Trajectory Catalyzed by Class I Ketol-Acid Reductoisomerase	90
Dual Nickel/Photoredox-Catalyzed Aryl Etherification Enabled by an Oxidative Near-Infrared-to-Blue Triplet–Triplet Annihilation Upconversion System Leveraging Spin-Forbidden Excitation	90
Metal–Support Interactions within a Dual-Site Pd/YMn₂O₅ Catalyst during CH₄ Combustion	90
Following the Kinetics of Undercover Catalysis with APXPS and the Role of Hydrogen as an Intercalation Promoter	89
Hydroalkylation of Alkenes with 1,3-Diketones via Gold(III) or Silver(I) Catalysis: Divergent Mechanistic Pathways Revealed by a DFT-Based Investigation	89
Identification of a Nitrenoid Reductive Elimination Pathway in Nickel-Catalyzed C–N Cross-Coupling	89
Ruthenium-Catalyzed C–F Bond Arylation of Polyfluoroarenes: Polyfluorinated Biaryls by Integrated C–F/C–H Functionalization	89
Discovery and Biosynthesis of Pseudoamides Reveal Enzymatic Cyclization of the Polyene Precursor to 5–5 Bicyclic Tetramate Macrolactams	88
Direct Construction of Julolidines via Reductive Annulation of Quinolines and Conjugated Enones by a MOF-Derived Hierarchically Porous Iridium Catalyst	88
Photochemical Reductive Carboxylation of N-Benzoyl Imines with Oxalate Accelerated by Formation of EDA Complexes	88
Mechanism of Two-Component Mono-Oxygenases Involved in Anthracycline 1-Hydroxylation	88
Observing Chemical and Morphological Changes in a Cu@TiO_x Core@Shell Catalyst: Impact of Reversible Metal-Oxide Interactions on CO₂ Activation and Hydrogenation	88
Linear-Structure Single-Atom Gold(I) Catalyst for Dehydrogenative Coupling of Organosilanes with Alcohols	88
Metal-Free Intermolecular Allylic C–H Amination of Alkenes Using Primary Carbamates	87
How a Formate Dehydrogenase Responds to Oxygen: Unexpected O₂ Insensitivity of an Enzyme Harboring Tungstopterin, Selenocysteine, and [4Fe–4S] Clusters	87
Asymmetric Hydroboration of Ketones by Cooperative Lewis Acid–Onium Salt Catalysis: A Quantum Chemical and Microkinetic Study to Combine Theory and Experiment	87
Cobalt-Molybdenum Oxides for Effective Coupling of Ethane Activation and Carbon Dioxide Reduction Catalysis	86
Four-Carbon Segmented Discrete Hydrocracking of Long-Chain Paraffins in MTT Channels Following a Pore-Mouth Mechanism	86
Csp³–Csp² Coupling of Isonitriles and (Hetero)arenes through a Photoredox-Catalyzed Double Decyanation Process	86
Issue Editorial Masthead	85
Mechanism of Alternating Poly(lactic-co-glycolic acid) Formation by Polymerization of (S)- and (R)-3-Methyl Glycolide Using an Enantiopure Aluminum Complex	85
Heterogeneous Low-Valent Mn Catalysts for α-Alkylation of Ketones with Alcohols through Borrowing Hydrogen Methodology	85
An Enzyme with High Catalytic Proficiency Utilizes Distal Site Substrate Binding Energy to Stabilize the Closed State but at the Expense of Substrate Inhibition	85
Diastereodivergent Synthesis of Chiral α-Aminoketones via a Catalytic O–H Insertion/Barnes–Claisen Rearrangement Reaction	85
Mechanism and Kinetics of Propane and n-Butane Dehydrogenation over Isolated and Nested ≡SiOZn–OH Sites Grafted onto Silanol Nests of Dealuminated Beta Zeolite	85
Rhodium-Catalyzed [5 + 1 + 2] Cycloaddition of Yne-3-acyloxy-1,4-enynes (YACEs) and Carbon Monoxide: Reaction Development and Mechanism	85
Ruthenium-Catalyzed Enantioselective Addition of Carboxylic Acids to Allenes	84
Friedel–Crafts Alkylation of Toluene by Methyl Mercaptan: Effect of Topology and Acidity of Zeolite Catalysts	84
Quasi-Two-Dimensional Intermetallic Electride CeRuSi for Efficient Alkaline Hydrogen Evolution	84
Issue Editorial Masthead	84
Redox Dynamics of Pt and Cu Nanoparticles on TiO₂ during the Photocatalytic Oxidation of Methanol under Aerobic and Anaerobic Conditions Studied by In Situ Modulated Excitation X-ray Absorp	84
Regulation of Oxygen Activation Pathways to Optimize Photocatalytic Methane Oxidative Coupling Selectivity	84
Issue Publication Information	84
Catalyst Deactivation and Its Mitigation during Catalytic Conversions of Biomass	84
Design, Synthesis, and Insights into the Redox Mechanism of Highly Efficient One-Pot Cu-ZSM-5 Catalysts for the Reduction of NO_x by NH₃-SCR at Low Temperatures	83
Promoted Surface-Interface Catalysis over Mn–Cr Incorporated Cu-Based Catalysts for Efficient Hydrogen Production from Methanol Decomposition	83
Single Metal Atom Catalysts and ORR: H-Bonding, Solvation, and the Elusive Hydroperoxyl Intermediate	83