High Voltage

Article	Citations
	159
Time–frequency characteristics and influencing factors of the pressure wave caused by power–frequency arc inside a closed oil tank	93
Experimental study on dynamic response characteristics of isolated‐span transmission lines after ice‐shedding	92
A new type of lipophilic hydrophobic self‐repairing cellulose insulating paper developed with ST‐110/FAS/PTFE ternary system as coating substrate	68
Broadband impedance spectrum detection of buffer layer defects in 110 kV crosslinked polyethylene cable with corrugated aluminium sheath	63
Detection of Transient Decomposition Products of CF3SO2F and C4F7N via OES Under Spark and Glow Discharges	59
Accelerated thermal ageing on performance of polypropylene‐based semiconducting screen for high voltage direct current cable applications—Effect of antioxidants	50
Observation and verification of surface electrical explosion driven by radial‐distributed pulsed current in laboratory lightning strike test	42
Improved thermal conductivity and breakdown strength of PVDF‐based composites by improving the dispersion of BN	41
Modelling and analysis of transformers considering ultra‐wide band frequency‐dependent parameters for high altitude electromagnetic pulse	36
Improve the insulation performance of air‐insulated gaps: Application of polyurea materials on the ground potential side of transmission line	36
Ag‐doped Ti3C2Tx sensor: A promising candidate for low‐concentration H2S gas sensing	34
Study on thermal cycling ageing resistance of performances of polypropylene/elastomer/boron nitride nanocomposites for high voltage direct current cable insulation	33
Detection of micro‐water in transformer oil based on ultrasonic pulse‐echo method and sparrow search algorithm‐random forest	33
SF6 catalytic degradation in a γ‐Al2O3 packed bed plasma system: A combined experimental and theoretical study	33
Electrohydraulic effect of microsecond pulsed discharge in transformer oils	33
Significantly enhanced flashover voltage of epoxy in vacuum by graded surface roughness modification	32
Electromagnetic anisotropic homogeneous model for eddy‐current field in single‐phase wound core	32
Wetting characteristics of the hydrophobic material surface through condensation	31
Decomposition mechanism of environmentally friendly insulating medium HFO1234zeE/N2 gas mixture under partial discharge	31
A new approach to the design of surface subsystems of polymeric insulators for HV and MV apparatus under AC voltage	30
Influence of thermal ageing on high‐field polarisation characteristics and conductivity behaviour of submarine polymeric cables insulation	29
Active disturbance rejection distributed secondary control for DC microgrids	28
Acoustic carrier signal transmission technology and its potential for in‐site monitoring of sliding electrical contact used in gas‐insulated switchgear/gas‐insulated transmission line	28
Polypropylene Insulation Failure Model Modification Based on Space Charge and Trap Parameters	27

The relationship between power of arc discharge in transformer oil and peak value of the shock wave	27
Research of cycloaliphatic epoxy resin and silicone rubber composite insulator interface based on four‐electrode system and temperature rise model	26
High‐strength, electrically insulated industrial meta‐aramid paper reinforced with polyethylene terephthalate microfibre pulp in a sandwich structure	26
Inhibiting liquid permeation into silicone rubber by superhydrophobic coating for prolonged service life	26
Octavinyl polyhedral oligomeric silsesquioxane on tailoring the DC electrical characteristics of polypropylene	25
Influence of micro‐water on AC breakdown characteristics of C4F7N/CO2 gas mixture under non‐uniform electric field	24
Significantly enhanced DC breakdown strength and high‐temperature resistivity of cross‐linked polyethylene through alloying polystyrene strategy	24
Insulation degradation and fracture cracks of mechanical impacted thermal‐ageing oil‐impregnated papers	23
Design of a high‐frequency transformer based on amorphous cut cores for insulation breakdown testing	23
Stress analysis and structural optimisation of insulating rods under dynamic and static loads	22
Charge transport mechanism of cross‐linked polyethylene/silicone rubber composite insulation by energy band theory	22
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Improved demodulation method for fibre optic sensors applied in transformer partial discharge detection	22
Guest Editorial: Understanding low temperature plasmas for device reliability, modulation and application to green energy strategy	22
Adsorption properties of environmentally friendly insulating medium C4F7N and its common decomposition products in NaA, NaZSM‐5, and NaX molecular sieves	21
An analysis of parameters affecting ampacity in aircraft bipolar MVDC power cables via coupled electrical, thermal, and computational fluid dynamic modelling	21
An experimental proof of concept of time‐reversal single‐sensor acoustic source localisation: Application to partial discharges	20
Effect of gamma‐ray irradiation on electrical conductivity of polypropylene composite for nuclear cable insulation	20
Detection of trace CF4 in C4F7N‐insulated gas‐insulated metal‐enclosed switchgear: Cascading specific chemical reactions with photoacoustic spectroscopy	20
Multi‐objective optimal design for AC filters in high voltage direct current system based on improved multi‐objective evolutionary algorithm based on decomposition	19
Investigation on insulation properties of HFO‐1336mzz(E) and N2/CO2 mixtures as SF6 substitutes in gas‐insulated electrical applications	19
Transient electric field of the combined insulation structure under positive periodic square waveform voltage: Analytical analysis and application	19
Fast evaluation on the fatigue level of copper contact wire based on laser induced breakdown spectroscopy and supervised machine learning for high speed railway	19
A novel characterization method for water trees based on the transmission characteristics of complementary split ring resonators	18
High voltage direct current transmission cables to help decarbonisation in Europe: Recent achievements and issues	18
Intelligent model prediction of fluctuant increase of maximum electric field in XLPE insulation using long short‐term memory network algorithm	18
Global model of plasma‐activated water over long time scale: Pulsed discharge and afterglow	18
Mechanical vibration state and its defect severity development trend prediction for gas‐insulated switchgear equipment: Attention‐bidirectional gated recurrent unit model construction and experimental	18
Dissolved gas analysis and dissipation factor measurement of mineral oil‐based nanofluids under thermal and electrical faults	18
Insulating materials for realising carbon neutrality: Opportunities, remaining issues and challenges	17
Evaluation of lightning‐induced overvoltage on a 10 kV distribution line based on electromagnetic return‐stroke model using finite‐difference time‐domain	17
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Analysis of vibration evolution and propagation characteristics due to mechanical degradation in transformer iron cores	17
A side‐effect‐free method of reducing capacitance requirement for modular multilevel converters	17
High‐performance ZnO varistor ceramics prepared by arc‐induced flash sintering with low energy consumption at room temperature	17
3D electromagnetic modelling for high‐temperature superconducting dynamo flux pumps using T‐A formulation	16
Revealing phase transitions and instabilities in pseudospark discharges	16
A passive optical fibre sensor based on Fabry‐Perot interferometry for bipolar electrostatic monitoring of insulating dielectrics	16
Experimental research on the influence of temperature on the discharge signal of void defects in GIS	16
Structural characteristics of electrohydrodynamic jets induced by a blade‐plane actuator subjected to highly non‐uniform electric fields: Parametric investigation through the particle image velocimetr	16
Mesh‐Based Charge Simulation Method and Its Applications to Electrostatic Electric Field Computation	16
Enhancing dielectric properties and energy storage performance of polyvinylidene fluoride composite by surface‐modified AgNbO3 nanoparticles	16
Self‐adaptive electrostatic discharge performance of ZnO microvaristors doped silicone rubber composites	16
Detection of characteristic component H2S in SF6 and SF6/N2 mixture using cavity ring‐down spectroscopy	15
Decay‐like fracture diagnosis of composite insulator based on small sample virtual expansion and radar graph mapping	15
Highly insulating thermoplastic blends comprising a styrenic copolymer for direct‐current power cable insulation	15
Effect of matrix resin components on properties of the semi‐conductive shielding material for high‐voltage cable	15
Analyses on an electronic voltage transformer's failure by its resonance with very fast transient overvoltage and suppression	15
Analysis for magnetic field disturbance of modular multilevel converter based high voltage direct current (MMC‐HVDC) converter valve	14
Model‐Aided State Parameter Inversion Identification of Electromagnetic Trip Device for High Voltage Circuit Breakers	14

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Analysis and suppression of voltage oscillation at DC circuit breaker terminal in DC fault transient process	14
Fast electrothermal coupling calculation method for supporting digital twin construction of electrical equipment	14
Anomalous‐Energy Runaway Electrons Originating in Fast Ionisation Wave During Pulsed Gas Breakdown	14
Experimental and numerical study on atmospheric‐pressure air dielectric barrier discharge via 50 Hz/5000 Hz dual‐frequency excitation	14
A novel current‐source management integrated circuit applied to high‐voltage integrated gate commutated thyristor gate driver	14
Thermofluidic investigations of oil natural transformer: Closed‐loop modelling and experimental validation	14
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Development of a field‐programmable gate array‐based real‐time generic solver for power electronics circuits with arbitrary configurations	13
Technique for Order Preference by Similarity to an Ideal Solution‐based comprehensive health assessment of composite insulators for overhead transmission lines	13
Dynamics of an impurity ion transport in oil‐paper insulation under various electric fields	13
Temperature rise characteristics of C5F10O/CO2 gas mixture AC high voltage switch bus	13
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Dielectric response—A nondestructive approach to probing the micro‐interface of aluminium hydroxide filled silicone rubber composites for outdoor insulation	13
Model moisture transport in oil‐paper insulation of transformer: Theory and experiment	13
Observation of an upward lightning flash with 21 upward positive leaders initiated from different wind turbines in wind farm	12
Effect of SiO2 nano film deposited on copper and aluminium electrodes on the power frequency breakdown voltage of SF6 gas	12
Theoretical connection from the dielectric constant of films to the capacitance of capacitors under high temperature	12
Microwave diagnostics of pulsed atmospheric discharge with electrolytic electrode and long‐lived luminous formation in its afterglow	12
Residual charge effects on partial discharges' response to varying sub‐kHz voltage frequencies	12
The impact of diatomaceous earth on hydrophobicity transfer characteristics	12
Analysis of conductance and interfacial polarisation behaviours of silicone rubber based on frequency domain spectroscopy	12
Converter station selection method of urban VSC‐DC intertie for grid resilience enhancement	12
Effect of solid particle type, concentration and size on DC breakdown voltage of short needle‐plate air gap: An experiment and simulation study	12
Morphology evolution and breakdown mechanism of cross‐linked polyethylene (XLPE)–silicone rubber (SiR) interface induced by silicone grease diffusion	12
Experimental and simulation study on luminous characteristics of Trichel discharge in air at picosecond time resolution	11
Properties of diffuse and volume discharges that are important for their applications	11
Electric field control by permittivity functionally graded and superficially non‐linear conductivity materials for DC‐GIS spacer	11
Non‐linear electrical conductivity of ethylene‐propylene‐diene monomer‐based composite dielectrics by tuning inorganic fillers	11
Microcosmic mechanism and correction of moisture effect on furfural diffusion and equilibrium in oil‐paper insulation	11
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Improved high‐temperature electrical properties of polypropylene insulation material by grafting styrene	11
Influence analysis of calculated horizontally layered soil parameters on grounding parameters	11
Moisture dynamics during high‐load fluctuations in transformers: Localised accumulation and interfacial transfer within oil/pressboard insulation	11
Preparation and performance improvement of a dual‐component microcapsule self‐healing system for silicone rubber insulating material	11
Revitalising high voltage cable: Exploring effective repair methods and influential factors for buffer layer defects using conductive silicone rubber	10
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Research on digital twin modelling technique for ±800 kV converter transformers scene based on hybrid attention mechanism and multiresolution hash encoding	10
Preparation of a novel cross‐linked polyetherimide with enhanced breakdown strength and high‐temperature energy storage performance	10
DC allowable electric field strength for naphthenic‐based and paraffin‐based transformer oils	10
Dynamic ageing research of cross‐linked polyethylene cable insulation based on temporal‐spatial dimension under combined electro‐thermal effect	10
Comparative studies of C4F7N‐based gas mixtures as the eco‐friendly alternative to SF6 for interrupting applications	10
Guest Editorial: Special issue on real‐time simulation and validation of modular multilevel converter‐based high‐voltage direct current systems	10
Flexible composite suppression method for ground arc in resonant grounding system	10
Effect of organophilic group of coupling agent on the electrical performance of Boron Nitride/meta‐aramid composite paper	10
Curing kinetics and residual stress modelling of gas‐insulated transmission lines tri‐post insulators	10
A novel thyristor‐based hybrid DC circuit breaker with short arcing capability	10
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Investigation of impact of DC component on breakdown characteristics for different electric fields under composite AC & DC voltage	10
Shape optimisation of basin insulator for DC gas insulated switchgear/gas insulated transmission lines based on artificial bee colony algorithm	9
Difference analysis of dissolved gas in natural ester insulating fluids under typical electrical and thermal faults: An experimental study	9
Energy harvesting technology for AC overhead insulated transmission line based on electric field induction	9
BCM‐YOLO: An improved YOLOv8‐based lightweight porcelain insulator defect detection model	9
Erratum: Octavinyl polyhedral oligomeric silsesquioxane on tailoring the DC electrical characteristics of polypropylene	9
SF6 decomposition and insulation condition monitoring of GIE: A review	9
Recent applications in dielectric barrier discharge and radio frequency plasmas‐engineered transition metal electrocatalysts for water splitting	9
The Partial Discharge Characteristics of Inner Air Gap Inside High‐Voltage Cable Termination for High‐Speed Trains	9
Modelling on thermal‐fluid field in SF6 insulated high voltage direct current bushing with its influence on electric field distribution and metal particle motion	9
Analysis of SF6 decomposed products by fibre‐enhanced Raman spectroscopy for gas‐insulated switchgear diagnosis	9
Experimental qualification and sensitivity study of antipodal patch antenna structures for orientation independent detection of partial discharges	9
Gas production analysis for the buffer layer of high‐voltage cross‐linked polyethylene cables	9
Intelligent power distribution live‐line operation robot systems based on stereo camera	9
Cumulative degradation of electrical properties in polypropylene insulation for AC cables under repeated impulse voltage stress	9
Experiment of electrothermal stress for different types of end turn grading in the inverter‐fed form‐wound windings	9
Accumulation characteristics of precipitation static on rotating wind turbine blades and its influence on the lightning attachment characteristics	9
Electrical tree degradation of MgO/epoxy resin composites at different voltage frequencies	9
Discharge characteristics of leader inception and development under 10 m long air gap—experimental observation and simulation results	8
Influence of positive DC electric field on rime icing on the insulator and its experimental verification in the natural environment	8
Effect of electric field on bubble generation and dissolution characteristics in oil–paper insulation	8
An improved second‐order kinetic model for degradation analysis of transformer paper insulation under non‐uniform thermal field	8
Thermal ageing of soft and hard epoxy resins	8
Radiation‐Induced Degradation in Polymeric Materials: Alterations in Physical–Chemical Properties and Their Effects on Electrical Performance of Insulation Systems	8
Enhanced high‐temperature energy storage density of polypropylene‐based materials by micro‐crosslinked structure design with N‐type organic semiconductor	8
Overview of recent progress in condition monitoring for insulated gate bipolar transistor modules: Detection, estimation, and prediction	8
Characteristics of pantograph‐catenary arc under low air pressure and strong airflow	8
A fast and high‐accurate commutation failure identification method for LCC‐HVDC system	8
Elliptical arrays of tunnelling magnetoresistance sensors for rectangular busbar current measurement	8
Introducing deep trap states for high dielectric strength of aramid‐based composite films	8
Analysis of micro‐discharges fine dynamics via x‐ray detection on the high voltage Padova test facility experiment	8
Effect of chemical corrosion on charge transport behaviour in epoxy/Al2O3 nanocomposite irradiated by gamma ray	8

Effect of electron beam irradiation on surface molecule and flashover voltage of epoxy composites	8
SF6 decomposition behaviour under partial discharge of typical insulation defects in gas‐solid insulated valve‐side bushing of converter transformer	8
Machine learning and microstructure design of polymer nanocomposites for energy storage application	8
Predicting transformer temperature field based on physics‐informed neural networks	8
Enhanced Corona Resistance and Insulation Properties of Enamelled Wire Insulating Varnish Induced by Constructed Dielectric Gradient Structured	8
A new technique for fault diagnosis in transformer insulating oil based on infrared spectroscopy measurements	8
Extending low‐temperature sintering technique to large‐sized whole‐wafer power semi‐conductor devices	8
Partial Discharge Localisation in Power Transformer by UHF Technique	8
Fabrication of insulation spacers for ultra‐high voltage gas‐insulated switchgear using eco‐friendly bio‐based epoxy composite material characterisation evaluation	8
Dry reforming of methane by microsecond pulsed dielectric barrier discharge plasma: Optimizing the reactor structures	7
Differences in M‐components between triggered lightning striking the ground and overhead line	7
Adhesion characteristics of carbon particles on the surface of epoxy resin in insulating oil under DC electric field and influencing factors	7
Study on the dynamic mechanical properties of winding‐block axial structure considering short circuit strain rate effect	7
High field conduction in biaxially oriented polypropylene at elevated temperature	7
Study on partial discharge and charge accumulation characteristics of oil‐pressboard insulation under DC superimposed harmonic voltage	7
Analysis for magnetic field disturbance of hybrid DC circuit breaker during breaking	7
Mitigation of Deane and Hamill phenomenon in gallium nitride high‐voltage power supply for electric propulsion system application	7
Experiments on plasma dynamics of electrical wire explosion in air	7
Simulation and experimental study on the method for reducing the pour point of pentaerythritol ester	7
New insights on thermal ageing of electrical insulating oils as revealed from photoluminescence and absorption spectroscopy	7
SO2 and SOF2 simultaneous detection by single mid‐infrared laser based on tunable diode laser absorption spectroscopy	7
Parallel diode‐clamped linear converter for withstand test and partial discharge measurement of electric equipment	7
Integrated Learning‐Based Ageing Assessment of Silicone Rubber	7
A novel transformer health state direct prediction method based on knowledge and data fusion‐driven model	7
Heat management technology for solid‐state high voltage and high repetitive pulse generators: Towards better effects and reliability	7
Experimental study on ageing characteristics of electric locomotive ethylene propylene rubber cable under mechanical–thermal combined action	6
Audible noise evaluation for six‐phase overhead lines transformed from existing three‐phase double circuit infrastructures with uprated voltages	6
Multidimensional coupled structure‐activity relationship models for replacement of SF6	6
Effect of graphene modified semi‐conductive shielding layer on space charge accumulation in insulation layer for high‐voltage direct current cable	6
Dividing and setting strategy of improving calculation efficiency for needle electrode corona discharge with a large‐scale space	6
Interface temperature evolution exposed to arc discharges occurred on the uniform moist pollution layer of composite insulators based on interface fibre Bragg gratings	6
Effect of nanofillers with different energy levels on the electrical properties of epoxy‐based nanocomposites	6
A novel linear regression density peak clustering‐based transmission line protection for line‐commuted converter‐voltage source converter hybrid high voltage direct current system	6
Enhancing Corrosion Resistance of Copper for C4F7N Based Eco‐Friendly Gas‐Insulated Equipment	6
Large‐scale plasma grafts voltage stabilizer on hexagonal boron nitride for improving electrical insulation and thermal conductivity of epoxy composite	6
Surface charge inversion algorithms based on integral equation method	6
Effect of radical scavenger on electrical tree in cross‐linked polyethylene with large harmonic superimposed DC voltage	6
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Statistical analysis and interpretation on lightning impulse breakdown voltages of ester liquids under varying field uniformity	6
Recent advances towards aqueous hydrogen peroxide formation in a direct current plasma–liquid system	6
Multiple discharges before leader inception in long air gaps under positive switching impulses	6
Space charge characteristics of silicone elastomer for device packaging under positive square wave voltage	6
Study on the evaluation method of polymerisation degree based on Raman spectroscopic plot	6
Nanoparticle‐enhanced dielectric oils for improved electrical insulation: Comparison of MgO, Al2O3, and SiO2‐based dielectric nanofluids	6
Revisiting the thermal ageing on the metallised polypropylene film capacitor: from device to dielectric film	6
A strategy for accurate prediction of dielectric permittivity and dielectric strength in polyimide	6
Synthesis of high‐purity mesoporous nanosilica microspheres from retired composite insulators based on orthogonal experiment	6
Heat Transfer Characteristics of Novel Resin Impregnated Paper Converter Transformer Valve‐Side Bushing With Two‐Phase Closed Thermosyphon	6
Design of cooling structure improvement of hybrid commutated converter valve	6
Non‐linearly conductive ZnO microvaristors/epoxy resin composite prepared by wet winding with polyester fibre cloth	6
Effect of multiphase content on temperature‐dependent electrical conductivity in silicone rubber composites	5
Behaviour and mechanisms of molecular vibrations induced by a pulsed voltage in a silicone elastomer used for device encapsulation	5
A direct bonding copper degradation monitoring method for insulated gate bipolar transistor modules: Boundary‐dependent thermal network combined with feedback control	5
Degradation of superhydrophobic aluminium overhead line conductor surfaces	5
Degree of polymerisation estimation for insulation paper immersed in silicone oil using frequency domain dielectric spectroscopy	5
Transient thermal network model for train‐induced wind cooling dry‐type on‐board traction transformer in electric multiple units	5
A review on insulation challenges towards electrification of aircraft	5
Effect of barrier thickness of Polytetrafluoroethylene on the Direct Current breakdown characteristics of liquid nitrogen	5
Microscopic mechanisms analysis of various dielectric response processes in oil‐paper insulation with different insulating states	5
KH550‐SiO2/polyimide insulating paper preparation and characterisation	5
Study on the influence mechanism of ambient humidity on the temperature rise of decay‐like composite insulators	5
Adsorption properties of Ni cluster modified TiO2 (1 0 1) towards SF6 decomposition gases	5
Study on moisture absorption characteristics of glass fibre‐reinforced epoxy resin material for composite insulators based on the 3D‐Fick model	5
A review of advanced acoustic‐chemical‐optical partial discharge monitoring techniques for ultra‐high‐voltage gas‐insulated equipment	5
Modelling and simulation study on dynamic pollution accumulation process of composite insulator	5
Improved direct current electrical properties of XLPE modified by graftable antioxidant and crosslinking coagent at a wide temperature range	5
Failure mechanism of metallized film capacitors under DC field superimposed AC harmonic: From equipment to material	5
Systematic protective scheme for mega‐city power systems against stray currents caused by metro systems	5
A high‐power electromagnetic source for disabling improvised explosive devices	5
Enhanced switching electric field and breakdown strength of epoxy composites with core‐shell silicon carbide nanoparticles	4
A method for detecting two‐dimensional plane stress distribution in basin‐type insulator based on critically refracted longitudinal wave	4
Effect of photoionisation on initial discharge in air under nanosecond pulse voltage	4
Detection of decomposition products of SF6/air gas mixture by electron attachment mass spectrometry	4
Effect of contamination and relative humidity on the function of thyristor voltage monitoring board	4
Electrical treeing behaviours in cross‐linked polyethylene cables after thermal ageing	4
The Temperature and Voltage Resistance Performance of Phenyl‐Modified Silicone Elastomers for High‐Voltage and High‐Power Semiconductor Device Encapsulation	4
Surface flashover in 50 years: II. Material modification, structure optimisation, and characteristics enhancement	4
Electromagnetic disturbance characteristic of typical high voltage switchgear interruption process in offshore wind farm based on integrated conduction model	4
The feasibility of continuous basalt fibre‐reinforced polymer application to composite cross‐arms	4
Investigation on micro‐mechanism of palm oil as natural ester insulating oil for overheating thermal fault analysis of transformers	4
Improved Prediction Model for the Corrosion of Aluminium Alloy Conductors: Considering the Influence of Electric Field and Dynamic Boundary	4
Finite element joint simulation model applied to fast mechanical switching of controlled resonance combination circuit breakers	4
Multi‐type defect detection and location based on non‐destructive impedance spectrum measurement for underground power cables	4
A Novel Method of Detecting Methanol in Transformer Oil Based on Methanol Gas Sensor With Solid‐Phase Extraction Technology	4
Study on the influencing factors to reduce the recovery time of superconducting tapes and coils for the DC superconducting fault current limiter applications	4
Analysis of multi‐objective optimisation method for main insulation structure configuration scheme of valve‐side winding of ultra‐high voltage converter transformer considering multi‐field coupling	4
Effects of nanofiller and voltage stabilizer on partial discharge resistance of polypropylene/elastomer blends: A comparison study	4
Comprehensive study on tree‐contact single‐phase‐to‐ground faults: Modelling, risk analysis, and detection recommendations	4
Effects of electrothermal ageing on dielectric performance of metallised biaxial orientation polypropylene film capacitors in strong magnetic fields	4
Positive corona discharge of rod‐plate electrodes in high‐speed airflow	4
Control strategy of novel hybrid commutated converter based on reverse blocking integrated gate commutated thyristor for commutation failure mitigation	4
Recent advances in multipactor physics and mitigation	4
Hygrothermal ageing performance of high temperature vulcanised silicone rubber and its degradation mechanism	4