Chem

Article	Citations
S-Scheme Heterojunction Photocatalyst	2077
Challenges for photocatalytic overall water splitting	359
Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update	328
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation	328
Triplet Energy Transfer Photocatalysis: Unlocking the Next Level	317
Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?	290
Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design	263
Catalytic processing of plastic waste on the rise	251
High-Performance n-Type Polymer Semiconductors: Applications, Recent Development, and Challenges	244
Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material	242
Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity	230
A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide	216
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications	212
Synthesis of CaCO3-Based Nanomedicine for Enhanced Sonodynamic Therapy via Amplification of Tumor Oxidative Stress	207
Late-Stage Functionalization	183
Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations	179
Redox Comediation with Organopolysulfides in Working Lithium-Sulfur Batteries	179
Electrochemical Synthesis of H2O2 by Two-Electron Water Oxidation Reaction	178
Porous materials for hydrogen storage	165
Molten Salt-Directed Catalytic Synthesis of 2D Layered Transition-Metal Nitrides for Efficient Hydrogen Evolution	164
A Realistic Methodology for 30% Efficient Perovskite Solar Cells	164
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis	161
Unconventional Mn Vacancies in Mn–Fe Prussian Blue Analogs: Suppressing Jahn-Teller Distortion for Ultrastable Sodium Storage	160
Reducing Voltage Losses in the A-DA′D-A Acceptor-Based Organic Solar Cells	160
Critical effects of electrolyte recipes for Li and Na metal batteries	158

Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis	154
Catalysis for Selected C1 Chemistry	153
Light-free Generation of Singlet Oxygen through Manganese-Thiophene Nanosystems for pH-Responsive Chemiluminescence Imaging and Tumor Therapy	153
Exploring and Understanding the Roles of Li2Sn and the Strategies to beyond Present Li-S Batteries	152
A Structure-Based Platform for Predicting Chemical Reactivity	152
Highly Selective Hydrogen Peroxide Electrosynthesis on Carbon: In Situ Interface Engineering with Surfactants	150
Outlook on K-Ion Batteries	147
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions	146
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window	139
Open-Shell Graphene Fragments	138
Advances in higher alcohol synthesis from CO2 hydrogenation	136
Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics	136
CO2 Hydrogenation to Ethanol over Cu@Na-Beta	135
Covalent-Organic-Framework-Based Composite Materials	134
Main-group elements boost electrochemical nitrogen fixation	132
Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles	131
Tailoring Polymer Dispersity by RAFT Polymerization: A Versatile Approach	128
Geminal Dimethyl Substitution Enables Controlled Polymerization of Penicillamine-Derived β-Thiolactones and Reversed Depolymerization	124
Ion-Solvent Chemistry-Inspired Cation-Additive Strategy to Stabilize Electrolytes for Sodium-Metal Batteries	122
A Directional Synthesis for Topological Defect in Carbon	122
Hydrogen-bonded organic frameworks: Chemistry and functions	122
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts	121
Perovskite Solution Aging: What Happened and How to Inhibit?	118
Designing highly active nanoporous carbon H2O2 production electrocatalysts through active site identification	118
Dissipative Self-Assembly: Fueling with Chemicals versus Light	117
Pollutant removal with organic macrocycle-based covalent organic polymers and frameworks	116
Catalysis, FLPs, and Beyond	116
Selectivity Control in Photocatalytic Valorization of Biomass-Derived Platform Compounds by Surface Engineering of Titanium Oxide	116
Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization	113
2D/3D perovskite engineering eliminates interfacial recombination losses in hybrid perovskite solar cells	113
Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction	112
Radiation Controllable Synthesis of Robust Covalent Organic Framework Conjugates for Efficient Dynamic Column Extraction of 99TcO4−	111
Constructing an Ion Pathway for Uranium Extraction from Seawater	110
An analysis of the electrochemical mechanism of manganese oxides in aqueous zinc batteries	109
Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization	105
Nickel-Catalyzed C−H Functionalization Using A Non-directed Strategy	103
Covalent Organic Frameworks: An Amazing Chemistry Platform for Designing Polymers	102
Transition-metal-catalyzed C–H allylation reactions	102
Reaction: Rational Design of Highly Active Photocatalysts for CO2 Conversion	99
Extremely Stable Anthraquinone Negolytes Synthesized from Common Precursors	99
Boosting Electrocatalytic Ammonia Production through Mimicking “π Back-Donation”	96
Digital Reticular Chemistry	96
Emergent behavior in nanoconfined molecular containers	96
Designer DNA nanostructures for therapeutics	95
Two-Dimensional Nanomaterials with Unconventional Phases	95
Chemistry and Biology of SARS-CoV-2	95
Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks	94
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	94
Electrochemical CO2 reduction in membrane-electrode assemblies	94
Prospects and Challenges in Anion Recognition and Transport	93

Porous Ligand Creates New Reaction Route: Bifunctional Single-Atom Palladium Catalyst for Selective Distannylation of Terminal Alkynes	93
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2	93
Rational design and atroposelective synthesis of N–N axially chiral compounds	92
Li-ion battery recycling challenges	92
Hybrid monomer design for unifying conflicting polymerizability, recyclability, and performance properties	90
Design principles for intrinsically circular polymers with tunable properties	89
Tuning the spin state of Fe single atoms by Pd nanoclusters enables robust oxygen reduction with dissociative pathway	88
Recent Advances in Using Transition-Metal-Catalyzed C–H Functionalization to Build Fluorescent Materials	88
Protein-directed, hydrogen-bonded biohybrid framework	87
The concept and examples of type-III photosensitizers for cancer photodynamic therapy	87
DFT-Guided Phosphoric-Acid-Catalyzed Atroposelective Arene Functionalization of Nitrosonaphthalene	86
Encapsulated Nanodroplet Crystallization of Organic-Soluble Small Molecules	85
Hydrazones as New Molecular Tools	85
Surface Chemistry Can Unlock Drivers of Surface Stability of SARS-CoV-2 in a Variety of Environmental Conditions	83
Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion	83
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Developing in situ responsive force probes for polymeric materials	82
Programmable synthesis of radially gradient-structured mesoporous carbon nanospheres with tunable core-shell architectures	81
An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries	80
Confinement as a Unifying Element in Selective Catalysis	80
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage	80
In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries	78
Nanoscale CaH2 materials for synergistic hydrogen-immune cancer therapy	78
Redox-Neutral Photocatalytic C−H Carboxylation of Arenes and Styrenes with CO2	78
Hierarchical Defect Engineering for LiCoO2 through Low-Solubility Trace Element Doping	77
Light-Promoted Bromine-Radical-Mediated Selective Alkylation and Amination of Unactivated C(sp3)–H Bonds	77
Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction	77
Magnetic-Field-Regulated TiO2 {100} Facets: A Strategy for C-C Coupling in CO2 Photocatalytic Conversion	77
Neutrophil-Membrane-Directed Bioorthogonal Synthesis of Inflammation-Targeting Chiral Drugs	76
Endohedral functionalization of chiral metal-organic cages for encapsulating achiral dyes to induce circularly polarized luminescence	76
Striding the threshold of an atom era of organic synthesis by single-atom catalysis	76
Rechargeable anion-shuttle batteries for low-cost energy storage	75
Optical processes in carbon nanocolloids	75
The chemical states of conjugated coordination polymers	74
Dynamic molecular weaving in a two-dimensional hydrogen-bonded organic framework	74
Anion chemistry enabled positive valence conversion to achieve a record high-voltage organic cathode for zinc batteries	73
Catalytic Decarboxylative Radical Sulfonylation	73
Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis	72
Indoor Surface Chemistry: Developing a Molecular Picture of Reactions on Indoor Interfaces	72
Pumps through the Ages	71
Recent advances in radical chemistry proceeding through pro-aromatic radicals	71
Dual key co-activated nanoplatform for switchable MRI monitoring accurate ferroptosis-based synergistic therapy	71
Breaking the trade-off between selectivity and adsorption capacity for gas separation	70
Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future	70
Progress in anion receptor chemistry	70
Borane-Catalyzed Stereoselective C–H Insertion, Cyclopropanation, and Ring-Opening Reactions	70
Gigantic Porphyrinic Cages	69
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites	68
Development of direct conversion of syngas to unsaturated hydrocarbons based on Fischer-Tropsch route	67
Modern strategies for C–H functionalization of heteroarenes with alternative coupling partners	67
Theory-Guided Machine Learning Finds Geometric Structure-Property Relationships for Chemisorption on Subsurface Alloys	67
Unraveling the physical chemistry and materials science of CeO2-based nanostructures	67
Multi-scale Imaging of Solid-State Battery Interfaces: From Atomic Scale to Macroscopic Scale	67
Oxygen-controlled photo-reforming of biopolyols to CO over Z-scheme CdS@g-C3N4	66
Molecules in Confined Spaces: Reactivities and Possibilities in Cavitands	66
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	66
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	65
Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study	64
Creep-Enabled 3D Solid-State Lithium-Metal Battery	64
Catalytic strategies for upvaluing plastic wastes	64
Size sensitivity of supported Ru catalysts for ammonia synthesis: From nanoparticles to subnanometric clusters and atomic clusters	64
Strategies for the Synthesis of Enantiopure Mechanically Chiral Molecules	64
Thermally Gated Bio-orthogonal Nanozymes with Supramolecularly Confined Porphyrin Catalysts for Antimicrobial Uses	64
Learning to Make Chemical Predictions: The Interplay of Feature Representation, Data, and Machine Learning Methods	63
Porous Liquids: The Next Frontier	63
An axial-to-axial chirality transfer strategy for atroposelective construction of C–N axial chirality	63
Artificial transmembrane ion transporters as potential therapeutics	62
Tuning the gating energy barrier of metal-organic framework for molecular sieving	62
Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one	61
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	61
Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation	60
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	60
Precise recognition of palladium through interlaminar chelation in a covalent organic framework	60
Confinement Self-Assembly of Metal-Organic Cages within Mesoporous Carbon for One-Pot Sequential Reactions	59
Selective Conversion of CO2 into Propene and Butene	59
Progress in carbon dioxide capture materials for deep decarbonization	59
Molecular Configuration Fixation with C–H···F Hydrogen Bonding for Thermally Activated Delayed Fluorescence Acceleration	59
Shale gas revolution: Catalytic conversion of C1–C3 light alkanes to value-added chemicals	59
A general N-alkylation platform via copper metallaphotoredox and silyl radical activation of alkyl halides	59
Quantum dots enable direct alkylation and arylation of allylic C(sp3)–H bonds with hydrogen evolution by solar energy	59
Programmable ATP-Fueled DNA Coacervates by Transient Liquid-Liquid Phase Separation	59

Interfacial Active Sites for CO2 Assisted Selective Cleavage of C–C/C–H Bonds in Ethane	58
Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation	58
Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes	58
Engine-Trailer-Structured Nanotrucks for Efficient Nano-Bio Interactions and Bioimaging-Guided Drug Delivery	58
Exceptionally active and stable RuO2 with interstitial carbon for water oxidation in acid	58
Bridging the Gap between Reality and Ideality of Graphdiyne: The Advances of Synthetic Methodology	58
Anisotropic Microparticles from Microfluidics	58
A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates	57
Single-atom engineering of metal-organic frameworks toward healthcare	57
Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound	57
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries	57
Shape-Induced Selective Separation of Ortho-substituted Benzene Isomers Enabled by Cucurbit[7]uril Host Macrocycles	56
Reversibly modulating a conformation-adaptive fluorophore in [2]catenane	56
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	56
When MOFs meet wood: From opportunities toward applications	56
Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation	55
Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp/sp 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes	55
Electrochemical Aziridination of Internal Alkenes with Primary Amines	54
Folding and Assembly of Metal-Linked Peptidic Nanostructures	54
Atomically precise electrocatalysts for oxygen reduction reaction	53
Perspectives for antimicrobial nanomaterials in cultural heritage conservation	53
Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics	53
Enhanced electroreduction of CO2 to C2+ products on heterostructured Cu/oxide electrodes	53
Strain-Induced Corrosion Kinetics at Nanoscale Are Revealed in Liquid: Enabling Control of Corrosion Dynamics of Electrocatalysis	53
Dual-Active-Sites Design of Co@C Catalysts for Ultrahigh Selective Hydrogenation of N-Heteroarenes	52
A Fluorinated Ionic Liquid-Based Activatable 19F MRI Platform Detects Biological Targets	52
Integrating the Mechanical Bond into Metal-Organic Frameworks	52
Aerobic Oxidative Cleavage and Esterification of C(OH)–C Bonds	52
Engineering couplings for exciton transport using synthetic DNA scaffolds	52
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	51
Near-infrared photosensitization via direct triplet energy transfer from lanthanide nanoparticles	51
Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants	50
Sensors for In Situ Real-Time Fluorescence Imaging of Enzymes	50
Controlling the shape and chirality of an eight-crossing molecular knot	50
Establishing design principles for emissive organic SWIR chromophores from energy gap laws	50
An isolable, crystalline complex of square-planar silicon(IV)	50
Cationic lithium polysulfides in lithium–sulfur batteries	49
Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media	49
Nitrogenase inspired artificial photosynthetic nitrogen fixation	49
Asymmetric radical cyclopropanation of dehydroaminocarboxylates: Stereoselective synthesis of cyclopropyl α-amino acids	48
Design principle of electrocatalysts for the electrooxidation of organics	48
Synergy between β-Mo2C Nanorods and Non-thermal Plasma for Selective CO2 Reduction to CO	48
Enantioselective Ring-Closing C–H Amination of Urea Derivatives	48
Catalyst: Aggregation-Induced Emission—How Far Have We Come, and Where Are We Going Next?	47
In This Issue	47
Biology-Inspired Supramolecular Peptide Systems	47
Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol	47
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	46
Rationally fabricating 3D porphyrinic covalent organic frameworks with scu topology as highly efficient photocatalysts	46
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts	46
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	46
Diindenoanthracene Diradicaloids Enable Rational, Incremental Tuning of Their Singlet-Triplet Energy Gaps	46
Solution-Processable, Crystalline π-Conjugated Two-Dimensional Polymers with High Charge Carrier Mobility	45
The road to industrialization of fine chemical carboxylation reactions	45
Evaluating Solid-Electrolyte Interphases for Lithium and Lithium-free Anodes from Nanoindentation Features	45
Guest-molecule-induced self-adaptive pore engineering facilitates purification of ethylene from ternary mixture	45
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries	44
Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols	44
Established and Emerging Computational Tools to Study Homogeneous Catalysis—From Quantum Mechanics to Machine Learning	44
Weak bonding strategies for achieving regio- and site-selective transformations	44
Transition to sustainable chemistry through digitalization	44
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction	44
Recent advances in electrode engineering strategies for aqueous Zn-based batteries	43
Fe binuclear sites convert methane to acetic acid with ultrahigh selectivity	43
Reactivity of an air-stable dihydrobenzoimidazole n-dopant with organic semiconductor molecules	43
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications	43
A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 Methanation	43
In This Issue	43
Dual Stimuli Switching: Interconverting Cationic and Radical Polymerizations with Electricity and Light	43
Exceptional electron conduction in two-dimensional covalent organic frameworks	42
Reversible isomerization of metal nanoclusters induced by intermolecular interaction	42
Active learning accelerates ab initio molecular dynamics on reactive energy surfaces	42
Stereospecific and stereoconvergent nucleophilic substitution reactions at tertiary carbon centers	42
Organometallic lanthanide bismuth cluster single-molecule magnets	42
Supramolecular Purification and Regioselective Functionalization of Fullerenes and Endohedral Metallofullerenes	42
A Bioinspired Multicomponent Catalytic System for Converting Carbon Dioxide into Methanol Autocatalytically	41
Mass Photometry of Membrane Proteins	41
Identifying the Conformational Isomers of Single-Molecule Cyclohexane at Room Temperature	41
Discovery of a Small Molecule Drug Candidate for Selective NKCC1 Inhibition in Brain Disorders	41
Dynamic optimization of guest binding in a library of diastereomeric heteroleptic coordination cages	41
On-the-fly interpretable machine learning for rapid discovery of two-dimensional ferromagnets with high Curie temperature	40
Heterogeneous hydroformylation of alkenes by Rh-based catalysts	40
Molecular Representation: Going Long on Fingerprints	40
A see-through electrochromic display via dynamic metal-ligand interactions	40
A base-controlled switch of SO2 reincorporation in photocatalyzed radical difunctionalization of alkenes	39
Liquid fuel synthesis via CO2 hydrogenation by coupling homogeneous and heterogeneous catalysis	39
One-Dimensional Segregated Single Au Sites on Step-Rich ZnO Ladder for Ultrasensitive NO2 Sensors	39
Hydrogen-bond activation of N2 molecules and photocatalytic nitrogen fixation	39
Laser-Microstructured Copper Reveals Selectivity Patterns in the Electrocatalytic Reduction of CO2	39
High-yield exfoliation of 2D semiconductor monolayers and reassembly of organic/inorganic artificial superlattices	39
Protein stabilization and refolding in a gigantic self-assembled cage	39
Porous Ladder Polymer Networks	38
An integrated solid-state lithium-oxygen battery with highly stable anionic covalent organic frameworks electrolyte	38
Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions	38
Reaction: Semiconducting MOFs Offer New Strategy for Uranium Extraction from Seawater	38