Chem

Article	Citations
Programming extracellular protein fate with peptide chimeras	805
Transitioning aliphatic C–H functionalization from bench to plant: Is decatungstate photocatalysis ready for the leap yet?	426
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	405
Catalysis, replication, and non-equilibrium behavior: Key determinants for life-like complexity realized using short peptides	360
Highly selective and efficient uranium recovery by size-sieving porous aromatic frameworks with rigidly functionalized windows	358
Click chemistry in polymer science	330
Nanocellulose: New horizons in organic chemistry and beyond	317
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	287
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	247
2D conjugated metal-organic framework as a proton-electron dual conductor	221
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	207
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	201
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	199
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	190
ElectroChemputer with integrated monitoring for programmable electrochemistry	184
An M60L60 metal-peptide capsid with a 60-crossing woven network	177
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	175
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	157
A Star of David [2]catenane of single handedness	156
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	156
In this issue	149
Out-of-equilibrium chemical logic systems	148
Multi-omics profiling of a self-assembling bioactive hydrogel for immunomodulation and myogenesis in volumetric muscle loss	147
2D covalent organic framework via catenation	146
N-Heterocyclic carbene-derived second-period main-group radicals: Synthesis, fundamentals, and applications	146

Selective recognition of quaternary ammonium cations	145
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	141
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	141
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	140
Variable nanosheets for highly efficient oxygen evolution reaction	136
Reaction: Harnessing reactive oxygen species (ROS) for water purification	134
Ion-dipole-interaction-manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	133
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	132
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	129
Semiconducting ladder-type covalent organic frameworks	129
Ionic surface propensity controls pH in nanopores	125
In This Issue	123
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	123
Iridium-mediated methane dehydrogenation and methylidene (=CH2) transfer	122
Switchable diversification of quaternary ammonium salts using photocatalysis	122
Design of piezoelectric organic cage salts for energy harvesting	121
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	120
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	119
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	118
Breaking ampere-level current density limitations in multi-carbon products through crystal facet engineering	118
Oxygen reduction active-site regulation enables reverse photocurrent in photoelectrochemical sensing	118
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	117
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	116
Catalytic strategies for upvaluing plastic wastes	115
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	114
Swapping benches from chemistry PhD student to science advisor at law firm	111
Be your own star	111
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	110
In this issue	107
Reaction: Don’t hate the player in chemical AI; hate the game	105
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	105
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	105
Supramolecular boosted superexchange	104
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	103
A radical–polar crossover approach to complex nitrogen heterocycles via the triplet state	102
General and selective metal-free radical α-C–H borylation of aliphatic amines	100
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	98
Stereodivergent asymmetric hydrogenation of quinoxalines	97
In this issue	97
Structure-performance relationships for catalysis-driven molecular machinery	97
Bioinspired chemical design to control interfacial wet adhesion	96
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	95
Improving productivity and stability for CO2 hydrogenation by using pincer-ligated Mn complexes with hemilabile ligands	93
Molecule-resolvable SERSome for metabolic profiling	92
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	89
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	88
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	88
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	88
Cation-exchange-upgraded nanostructures for photocatalysts	87
A light-driven chloride anion transporter	86

Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	85
Chemical probes of redox enzymes by rational, reactivity-based design	84
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	84
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	83
Colorless zinc colored by metal-metal orbital interaction	82
Selective palladium recovery by a highly porous polyisothiocyanurate	82
The role of concentration waves in synthesizing hollow multi-shelled structures	82
A dynamic charge-dependent nanofungicide platform for sustainable agrochemical deposition and delivery	81
Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	80
The mechanical bond in biological systems	80
From “heavy” water to “heavy” boron clusters	80
The 40th anniversary of covalent dendrimers	79
Unexpected diastereoselective chemistry on a 2D protein surface	78
Potent antimicrobial effect induced by disruption of chloride homeostasis	77
Enzymatic DNA orthogonal chemistry for multi-cancer diagnosis	77
Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	77
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	77
Ice quenching for sustained nucleate boiling at large superheats	77
Challenges and perspectives for the perovskite module research	76
Designing generative dissipative networks for programming complex temporal dynamics and functions	76
Emerging trends in CO carbonylation	75
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	75
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	73
The key of Zn2+ transfer kinetics in zinc metal batteries	73
Molecule additive design for perovskite light-emitting diodes operated at high current densities	72
A clever trilayer assembly strategy for 2D materials	70
Industrial PhD: My way to go?	70
Reaction: Circular chemical imaginaries	70
Omics approach for electrolytes discovery	69
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	69
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	68
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	68
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	67
Water-centric framework for confinement catalysis: Beyond nanomaterials	67
Light-intensity-dependent out-of-equilibrium processes toward dimensionally distinct nanopolymorphs	67
Cold-resilient zinc batteries with organic-free solvation structures	67
Frontier research in perovskite solar cells: Following the paths of European research and innovation	66
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	66
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	66
Transformable quadruply interpenetrated cage with multiple states of different reactivities	65
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	64
The Cation Shuffle: Interplay of silylium, carbenium, and arenium ions in superelectrophile catalysis	64
Regulating the topology and pore size of covalent metal-organic framework for boosting catalytic CO2 conversion	64
One step further to efficient Li-mediated ammonia synthesis in flow cells	63
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	63
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	63
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	63
Aqueous electrocatalytic small-molecule valorization trilogy	63
Metal-organic frameworks for water vapor adsorption	62
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	62
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	62
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	62
Rationalizing the design and implementation of chiral hybrid perovskites	62
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	61
Hydrogen-bonded organic frameworks: Chemistry and functions	61
Unlocking the synthesis of homochiral carborane-fused boraphenanthrenes	60
Downsizing lactams via Rh-catalyzed C–C activation	60
Divergent scaffold redesign of ecteinascidin 743 as a gateway to anticancer macrocycles	60
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	59
Confinement-induced chiroptical photoswitching —An encapsulation approach for advanced photochemical functions	59
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	59
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	59
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	59
Sculpting photoproducts with DNA origami	58
Dispersion-driven formation of chiral twisted PAH double helices	58
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	58
Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	58
Innovative low-carbon technology for a sustainable electrolyte industry	58
In this issue	57
Activating a light-driven molecular motor by metal complexation	57
Isoreactivity in chemistry	57
Directional long-distance signal transmission on two-dimensional DNA origami assemblies	57
Long-wavelength photocatalysis enabled by an in-situ-assembled manganese platform	57
Dynamic mechanoresponsive polymers enabled by ring-opening polymerization of cyclic propargyl carbonates	57
Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques	56
Rewriting lysine reactivity: Lysine-targeted bioconjugation via biomimetic polarity reversal for diversified biomolecule modification	56
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	56
Selective cellular probes for mammalian thioredoxin reductase TrxR1: Rational design of RX1, a modular 1,2-thiaselenane redox probe	56
Multiply entangled receptors for high-affinity anion recognition in water	56
Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution	56

DNA-mediated force transmission for precise and efficient mechanochemical activation	56
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	55
Modular synthesis of fluoroalkyl-substituted cyclopropenes with fluoroalkylacylsilanes as carbynyl cation equivalents	55
Self-assembly of 10-nm-sized pentagonal dodecahedra through heteroleptic complexation coupled with orientational self-sorting	55
Challenges for photocatalytic overall water splitting	54
DNA membrane nanopores with highly tunable shapes and sizes	54
Biocatalytic activation of diazirines for carbene-transfer reactions	54
Rethinking catalyst design by using data science	54
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	54
In this issue	54
Information transduction via fuel-controlled chemical waves	53
The cyclotriborate trianion	53
Does in-situ-generated H2O2 promote important industrial reactions?	53
Reaction: A three-pronged approach toward a sustainable chemical industry	53
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	53
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	52
In my blue-light era	52
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	52
Electrophilic selenium drives electron leakage	52
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	52
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	51
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	51
Boosting single-molecule magnet performance	50
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	50
A critical assessment of fluorescent probes as cellular reporters for thioredoxin system enzyme activities	50
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	50
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	49
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	49
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	49
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	49
Versatile deacylative cross-coupling of aromatic ketones	49
Role of delocalized electrons on the doping effect in vanadia	49
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	49
Tailoring dynamic hydrogels by controlling associative exchange rates	49
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	48
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	48
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	48
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	48
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	48
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	48
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	48
Reaction: Navigating the promises and perils of AI-powered drug synthesis	47
Operando scattering techniques for detecting precipitation reactions in lithium-sulfur batteries	47
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	47
Photovoltaic potential of nitro-functionalized non-fullerene acceptors depends on its bonding site	47
Targeted spin regulation in multi-spin systems via σ-bond rotation	47
Championing systems thinking to create a circular economy of chemicals	46
Cancer nanomedicine: Concepts, promises, and challenges	46
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	46
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	46
Zeolite-based catalysts for methane conversion: Challenges and opportunities	46
Triazasupersumanenes: Bowl-shaped nanographenes with tunable properties and unexpected charge transport performance	46
New insights and discoveries in anion receptor chemistry	46
Depositing atom by atom: Pt–Ru–Co triple-atom catalysts	45
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	45
Controlled radical depolymerization: Structural differentiation and molecular weight control	45
Light-controlled colloidal crystallization	45
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	45
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	45
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	45
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	45
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	45
Synthesizing a nanographyne	45
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	44
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	44
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	44
Iron-mediated modular decarboxylative cross-nucleophile coupling	44
Catalytic and selective chemical recycling of post-consumer rubbers into cycloalkenes	44
The Co/NbN interphase as an effective ammonia synthesis catalyst	44
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	43
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	43
Solar-to-chemical conversion in catalytic plastic transformation	43
Photoinduced, ground-state charge-transfer complex	43
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	43
The third wave of enzyme engineering: Navigating the AI-powered IDEA paradigm	43
Finding sustainable solutions	43
Aqueous-phase organic photochemistry: Distinct modes and interfaces	42
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	42
Reversible topochemical polymerization and depolymerization of a crystalline 3D porous organic polymer with C–C bond linkages	42
Out-of-equilibrium confinement catalysis mediated by compressive force	42
Fluoride up- and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages	42
A metal-ion-linked self-assembled molecular layer as a robust hole-selective contact for perovskite solar cells	42
p-p orbital hybridization enables durable aqueous zinc-iodine batteries	42
Integrating two contrasting biosynthetic pathways for peptide natural products	41
The subtle art of radical control	41
Selection of assembly complexity in a space of tetrapeptides	41
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	40
In This Issue	40
Programmable reconfiguration of one-dimensional supramolecular polymers into multidimensional topological nanostructures	39
New light on proton transfer: Spectral and kinetic signature of a transient Eigen complex	39
Electrochemical 6Li isotope enrichment based on selective insertion in 1D tunnel-structured V2O5	39
Communication between active sites regulates heterogeneous catalysis	39
Connecting single-nucleotide polymorphisms, glycosylation status, and interactions of plasma serine protease inhibitors	39
The sustainability potential of single-atom catalysts in chemical process	39
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	39