Chem

Article	Citations
In this issue	582
In This Issue	385
2D covalent organic framework via catenation	339
ortho-Aromatic polyamides by ring-opening polymerization of N-carboxyanhydrides	315
Sequence-specific, mechanophore-free mechanochemistry of DNA	274
Anion-coordination- and π-π-stacking-interaction-driven assembly of a complex Frank-Kasper structure	265
Quantity effect of heteroatom incorporation on the oxygen evolution mechanism in ruthenium oxide	241
Directed discovery of high-loading nanoaggregates enabled by drug-matched oligo-peptide excipients	233
Morphological-transition-induced motion	212
The progress and challenges of tin-lead alloyed perovskites: Toward the development of large-scale all-perovskite tandem solar cells	199
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	198
Repurposing myoglobin into an abiological asymmetric ketoreductase	194
Catalyst: Systems chemistry links reactions to molecular function	192
Why sulfur is important in lincosamide antibiotics	183
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2	173
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	171
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications	169
Precision in protein chemical modification and total synthesis	156
Computation-aided design of oxygen-ligand-steered single-atom catalysts: Sewing unzipped carbon nanotubes	154
Harnessing the reactivity of borenium for methane activation	151
Accessing aliphatic alcohols for metallaphotoredox catalyzed C(sp3)-arylation	149
Growing twisted bilayer graphene at small angles	144
A Star of David [2]catenane of single handedness	141
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	138
Conformational selection accelerates catalysis by an organocatalytic molecular motor	138

Alkane recognition enhanced by solvophobic interactions enables site-selective aliphatic C–H oxidation	130
Reactive bonds for closed-loop chemical processing of polyethylene mimics	130
A new nexus in metal-organic frameworks	129
In this issue	127
Spin-coupled electron densities of iron-sulfur cluster imaged by in situ serial Laue diffraction	126
Dual catalysis by homogeneous/heterogeneous ruthenium species	126
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	125
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	124
One-pot catalytic conversion of polyethylene wastes to gasoline through a dual-catalyst system	123
Bifunctional tandem catalytic upcycling of polyethylene to surfactant-range alkylaromatics	123
New insight into carrier transport in 2D layered perovskites	120
Deciphering nickel-catalyzed electrochemical ammonia synthesis from nitric oxide	120
From carbon superbases to superacids	118
Exploiting charged groups for metal-catalyzed meta-C–H functionalization of arenes	118
Perovskite intermediate phases fundamentally address the urgent stability issue	118
Camphor the polymerization; stay for the depolymerization	117
The legacy of Professor Li-Xin Dai: Organometallic and asymmetric catalysis	117
In this issue	114
Anchoring the AIEgen by Zr clusters in metal-organic gel for efficient X-ray detection and imaging	111
Grinding the way to enantiopurification	111
Measuring solubility automatically with vision	110
Enantioselective total syntheses of melotenine-, voacafrine-, and tabersonine-type Aspidosperma indole alkaloids	110
Real-time observation of the dynamics of an individual rotaxane molecular shuttle using a single-molecule junction	108
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	107
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	106
Selective nitrogen fixation via Janus C-N coupling in co-electrolysis	104
Ion-dipole interaction manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	102
Reaction: Navigating the promises and perils of AI-powered drug synthesis	102
Hierarchical anions at the electrode-electrolyte interface for synergized neutral water oxidation	100
In this issue	100
Out-of-equilibrium chemical logic systems	99
Reaction: Harnessing reactive oxygen species (ROS) for water purification	99
Polypeptide-based batteries toward sustainable and cyclic manufacturing	99
Intramolecular [3 + 2] annulation of allenylsilane-enes: Direct synthesis of highly strained trans-fused 5/5 ring systems	98
Shining light on nitrogen: Alkene amination with N-heteroaromatic radicals via energy transfer	98
From low-res measurements to high-res insights: Revolutionizing COF structural determination	97
Terahertz-Raman spectroscopy for in situ benchtop monitoring of changes to extended, supramolecular structure in milling mechanochemistry	93
Producing economically viable renewable diesel by upgrading organic solid waste with natural gas	93
A multistate memory cell based on electrochromic metallo-organic assemblies	92
Stereoselective synthesis of topologically chiral molecular entanglements	92
An evolutionary algorithm for interpretable molecular representations	92
Weaving on a molecular scale: A challenge in two dimensions	92
Organo-Se BTSAs-enabled performance: From racemic and asymmetric synthesis to click chemistry application	90
Broken vows: Separation of carbene and the lone pair unleashes dicationic revelry	90
Computational de novo protein design: From secondary to primary, then toward tertiary structures	90
Construction of a three-state responsive framework from a bistable photoswitch	89
Obtaining clean hydrogen from waste plastics	88
Transformative ligand effects in iron photocatalysis	88
Fluorinating electrophilic interception in the oxidation or protonation of alkynyl tetracoordinate borons	88
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	87

A nanopore distance away from next-generation protein sequencing	85
Quantifying zinc and manganese reduction potentials in organic solvents	85
Development of an energy-dense and high-power Li-Cl2 battery using reversible interhalogen bonds	83
Championing systems thinking to create a circular economy of chemicals	83
Efficient flow synthesis of a Star of David [2]catenane and a pentafoil knot	83
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	82
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	82
Macrocyclic ligands open new channels in electrically conductive metal-organic frameworks	82
One ring to rule them all	81
A plausible prebiotic selection of ribose for RNA - formation, dynamic isolation, and nucleotide synthesis based on metal-doped-clays	80
Hierarchical toughening: A step toward matching the complexity of biological materials	80
Metalloradical activation of carbonyl azides for enantioselective radical aziridination	80
Making monodispersed ultralong graphene nanoribbons with an accelerated iterative approach	79
Catalyst metal-ligand design for rapid, selective, and solventless depolymerization of Nylon-6 plastics	77
Element-specific electronic and structural dynamics using transient XUV and soft X-ray spectroscopy	77
A prebiotic Krebs cycle analog generates amino acids with H2 and NH3 over nickel	76
Efficient earth-abundant copper photocatalysis enabled by metal-arene interaction	76
Rapid determination of experimental sorption isotherms from non-equilibrium sorption kinetic data	76
Thermosetting supramolecular polymerization of compartmentalized DNA fibers with stereo sequence and length control	75
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	75
Construction of a caged single-molecule protein with ultra-stability	75
Evolution of MOF single crystals	74
Perrhenate recognition within a superphane cavity	74
Photothermal tandem catalysis for CO2 hydrogenation to methanol	73
Leukocyte-nanomedicine system for targeted delivery and precise theragnostics	73
Economical and efficient access to polyselenophene derivatives	73
Variable nanosheets for highly efficient oxygen evolution reaction	73
Reversible-deactivation radical copolymerization of tetrafluoroethylene via the formation of divergent termini in dormant chains	72
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	72
Next-generation de novo luciferases: How artificial intelligence is improving its own designs at light speed	68
Strong uranium-phosphorus antiferromagnetic exchange coupling in a crystalline diphosphorus radical trianion actinide complex	68
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	66
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	66
Selenium nanomedicine: From basic science to clinical applications	65
Three-component aminofluorination of alkenes with electronically rich amino sources	65
Selective hydroboration of terminal alkynes catalyzed by heterometallic clusters with uranium–metal triple bonds	65
Reticular chemistry in action: 3D porphyrinic COFs with scu topology	64
Multiscale design of biological meta-composites with omnidirectional crack resistance	64
Phonon-promoted superionic conduction in fluorite-structured compounds	63
Oscillatory adaptive catalysis: Intramolecular chain shuttling regulated by stereo-autocorrection in stereoselective polymerization of lactide	63
In this issue	63
New rhodamines with changeable π-conjugation for lengthening fluorescence wavelengths and imaging peroxynitrite	63
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	63
Charge delocalization and global aromaticity in a partially fused 12-porphyrin nanoring	63
Solid-state photon energy storage via reversible [2+2] cycloaddition of donor-acceptor styrylpyrylium system	62
Enhanced coherence by coupling spins through a delocalized π-system: Vanadyl porphyrin dimers	62
Medium-independent hydrogen atom binding isotherms of nickel oxide electrodes	61
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	61
Reaction: Is a circular economy for chemicals and materials possible?	61
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	61
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	61
Enantioselective hydroamination of unactivated terminal alkenes	61
Bioorthogonal click and release: A general, rapid, chemically revertible bioconjugation strategy employing enamine N-oxides	60
Artificial light-triggered smart nanochannels relying on optoionic effects	60
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	59
Fertilizer and oxygen from Martian atmosphere via microwave plasma	59
Switching the O–O bond-formation mechanism by controlling water activity	59
Universal self-driving laboratory for accelerated discovery of materials and molecules	59
Catalyst: The roles of chemistry in clean water for all	59
Stabilizing the microstructure for Y6-series nonfullerene solar cells	59
Controlled radical depolymerization: Structural differentiation and molecular weight control	58
Cationic polaron delocalization in porphyrin nanoribbons	58
2D conjugated metal-organic framework as a proton-electron dual conductor	58
Reshaping quinolines by single-electron-transfer-triggered dearomatization	58
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	58
Generative design of de novo proteins based on secondary-structure constraints using an attention-based diffusion model	57
Synthesizing a nanographyne	57
Developing real-time mechanochromic probes for polymeric materials	57
Quantum-dot-photocatalyzed production of allylic C–C products with hydrogen evolution	57
Organic charge-transfer complex induces chemoselective decarboxylation to aryl radicals for general functionalization	56
Single-step conversion of wood lignin into phenolic amines	56
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction	56
Click chemistry in polymer science	55
Trapping highly reactive photoinduced charge-transfer complex between amine and imide by light	55
CO2-mediated oxidative dehydrogenation of propane enabled by Pt-based bimetallic catalysts	55
Ion-pair effects in photoredox chemistry	55
Sensitive short-wavelength infrared photodetection with a quinoidal ultralow band-gap n-type organic semiconductor	54
Machine learning photodynamics uncover blocked non-radiative mechanisms in aggregation-induced emission	54
Weak bonding strategies for achieving regio- and site-selective transformations	54
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	53

Unified sensing of the concentration and enantiomeric composition of chiral compounds with an achiral probe	53
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites	53
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	52
Electrochemical CO2 reduction in membrane-electrode assemblies	51
Nanocellulose: New horizons in organic chemistry and beyond	50
Heterogeneous manganese-oxide-catalyzed successive cleavage and functionalization of alcohols to access amides and nitriles	50
New insights and discoveries in anion receptor chemistry	49
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	49
Curbing pollutant CO2 by using two-dimensional MXenes and MBenes	49
A bulky 1,4,7-triazacyclononane and acetonitrile, a Goldilocks system for probing the role of NiIII and NiI centers in cross-coupling catalysis	49
Rationally fabricating 3D porphyrinic covalent organic frameworks with scu topology as highly efficient photocatalysts	48
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	48
Peptide self-assembly through liquid-liquid phase separation	48
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	48
Non-covalent interactions of graphene surface: Mechanisms and applications	48
Ampere-level CO2-to-formate electrosynthesis using highly exposed bismuth(110) facets modified with sulfur-anchored sodium cations	47
Iron-mediated modular decarboxylative cross-nucleophile coupling	47
Mirror-image protein and peptide drug discovery through mirror-image phage display	47
Catalytic cross-electrophile coupling of aryl chlorides with unactivated alkyl chlorides: The synergy of iron and Li	47
Run-and-halt motility of droplets in response to light	47
Concise chemoenzymatic synthesis of N-glycans	47
In situ characterization techniques and methodologies for high-temperature electrochemistry	46
Selective tumor targeting enabled by picomolar fibroblast activation protein inhibitors isolated from a DNA-encoded affinity maturation library	46
Controlled radical depolymerization: Structural differentiation and molecular weight control	46
Porous materials for hydrogen storage	45
Designing carbon dots for enhanced photo-catalysis: Challenges and opportunities	45
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	45
Emissive fluoren-triangles for solid-state fluorochromism and selective gas sorption	44
In situ probing the origin of interfacial instability of Na metal anode	44
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	44
Reinforced double-threaded slide-ring networks for accelerated hydrogel discovery and 3D printing	44
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	44
An old polymer class revisited: Versatile, degradable, non-alternating polyketones	44
Design principle of electrocatalysts for the electrooxidation of organics	44
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis	44
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	43
Mucin-mimetic glycan arrays integrating machine learning for analyzing receptor pattern recognition by influenza A viruses	43
Misorientation strategy on high-entropy metal oxides for enhanced acidic oxygen evolution reaction	43
Interface of biomolecular condensates modulates redox reactions	43
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries	43
Tuning the gating energy barrier of metal-organic framework for molecular sieving	42
Protein desulfurization: Sodium tetraethylborate makes it fast	42
Accelerating Li-based battery design by computationally engineering materials	42
Synthesis of magnesium nanoparticle for NIR-II-photoacoustic-imaging-guided synergistic burst-like and H2 cancer therapy	41
Controlled carbon nanotube growth with hydrocarbon nanobelt templates	41
In this issue	41
Alignment of linear polymeric grains for highly stable N-type thin-film transistors	41
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	41
In This Issue	41
Supramolecular triangular orthobicupola: Self-assembly of a giant Johnson solid J27	41
Direct air capture with bis-iminoguanidines: From discovery to commercialization	41
Polyolefin recycling by C–C bond alumination	41
Mechanochemistry: A sustainable chemistry path	40
Deciphering the rational design of the early transition metals for ammonia synthesis	40
In this issue	40
In this issue	40
Swapping benches from chemistry PhD student to science advisor at law firm	39
Advancing beyond Sabatier: Strategies for dynamic synthetic catalysis	39
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	39
Tactics for uncovering intermediates in nickel Kumada cross-coupling catalysis	39
In this issue	39
In this issue	39
In this issue	38
Nanoporous synthetic metal: A nickel MOF with an amino-functionalized macrocyclic ligand	38
Lithium recovery using porous polymers	38
Synthesis and magnetic property of a telluryl radical	38
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	38
In this issue	38
The subtle art of radical control	38
Chemical space-property predictor model of perovskite materials by high-throughput synthesis and artificial neural networks	38
An unconventional photochemical tetrahydroisoquinoline synthesis from sulfonylimines and alkenes	38
In this issue	38
Stable crystalline keteniminyl anions	38
Systematic evolution of functional oligonucleotides for targeted protein degradation	37
In This Issue	37
Enhanced X-ray luminescence in one-dimensional Cu–I coordination polymers via ligand halogen engineering	37
Fine-tuned coordination environment of Pt-Fe-Pt active site for selective heterogeneous hydrogenation of crotonaldehyde	37
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	37
Flexibility-frustrated porosity for enhanced selective CO2 adsorption in an ultramicroporous metal-organic framework	37
Real-time study of on-water chemistry: Surfactant monolayer-assisted growth of a crystalline quasi-2D polymer	37
10B-labelled diboron(4) reagents: Applications and relevance to boron neutron capture therapy	37
Evolutionary features for task-specific machine-learning applications	36
Asymmetric access to β-funebrene via a trans-selective annulation of allenylsilane-enes	36
Exerting control of self-assembly pathways via morphological switching and patterning in amino-acid-based benzene-1,3,5-tricarboxamide conjugates	36
In this issue	36
Strengthening the academic pipeline for underrepresented students via early exposure to graduate education	36
Electrochemical 6Li isotope enrichment based on selective insertion in 1D tunnel-structured V2O5	36
Selective control of donor-acceptor Stenhouse adduct populations with non-selective stimuli	36
Selective C–H fluoroalkylation of azines enabled by tailored phosphorus-based reagents	36
Dimerization approach to (+)-asperazine A	36
Higher-order cycloadditions in the age of catalysis	36
Reaction: Avoid fairy dust when engineering water-purification technologies	36
From bio-based furanics to biodegradable plastics	36
Richard Ernst beyond Fourier transforms: A legacy of multiple reincarnations	36
Make it stick: Fixable ligands for tissue imaging	36