Chem

Article	Citations
In This Issue	656
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	376
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	327
A Star of David [2]catenane of single handedness	294
Reaction: Harnessing reactive oxygen species (ROS) for water purification	288
Out-of-equilibrium chemical logic systems	282
Multi-omics profiling of a self-assembling bioactive hydrogel for immunomodulation and myogenesis in volumetric muscle loss	231
2D covalent organic framework via catenation	230
Thermosetting supramolecular polymerization of compartmentalized DNA fibers with stereo sequence and length control	209
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	207
Variable nanosheets for highly efficient oxygen evolution reaction	200
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	192
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	192
In this issue	188
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	179
2D conjugated metal-organic framework as a proton-electron dual conductor	167
An M60L60 metal-peptide capsid with a 60-crossing woven network	165
Click chemistry in polymer science	157
Nanocellulose: New horizons in organic chemistry and beyond	157
Ion-dipole-interaction-manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	156
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	154
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	152
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	151
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	146
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	144

Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	143
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	141
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	139
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	135
Supramolecular boosted superexchange	134
In this issue	132
Swapping benches from chemistry PhD student to science advisor at law firm	129
Reaction: Don’t hate the player in chemical AI; hate the game	128
Semiconducting ladder-type covalent organic frameworks	126
Be your own star	126
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	121
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	121
In this issue	120
Catalytic strategies for upvaluing plastic wastes	119
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	118
In this issue	117
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	115
Ionic surface propensity controls pH in nanopores	114
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	113
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	111
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	110
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	110
Molecular design strategy for realizing vectorial electron transfer in photoelectrodes	109
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	109
In This Issue	108
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	108
Protein stabilization and refolding in a gigantic self-assembled cage	108
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	107
Molecule-resolvable SERSome for metabolic profiling	107
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	105
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	105
Switchable diversification of quaternary ammonium salts using photocatalysis	105
General and selective metal-free radical α-C–H borylation of aliphatic amines	101
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	101
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	101
Cation-exchange-upgraded nanostructures for photocatalysts	101
Design of piezoelectric organic cage salts for energy harvesting	100
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	98
Bioinspired chemical design to control interfacial wet adhesion	97
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	96
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	95
Stereodivergent asymmetric hydrogenation of quinoxalines	94
Supramolecular triangular orthobicupola: Self-assembly of a giant Johnson solid J27	92
Higher-order cycloadditions in the age of catalysis	91
The role of concentration waves in synthesizing hollow multi-shelled structures	90
Colorless zinc colored by metal-metal orbital interaction	89
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	88
Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	88
Catalyst: A step forward for PVC manufacture from natural gas	87
Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	87

Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	86
Emerging trends in CO carbonylation	86
Ice quenching for sustained nucleate boiling at large superheats	86
Chemical probes of redox enzymes by rational, reactivity-based design	85
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	82
A light-driven chloride anion transporter	81
The key of Zn2+ transfer kinetics in zinc metal batteries	80
Upcycling waste PET and CO2 to useful chemicals: Multi-functional catalysis at its best	79
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	79
Challenges and perspectives for the perovskite module research	79
Designing generative dissipative networks for programming complex temporal dynamics and functions	79
Engineering reversible isomerization at the nanoscale via intermolecular interactions	79
Enzymatic DNA orthogonal chemistry for multi-cancer diagnosis	78
Dynamic enzymatic synthesis of γ-cyclodextrin using a photoremovable hydrazone template	77
Potent antimicrobial effect induced by disruption of chloride homeostasis	77
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	75
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	74
The mechanical bond in biological systems	73
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	73
Programmable spatial organization of liquid-phase condensations	72
Finding your voice in a diverse audience: Lessons in writing and advocacy	71
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	71
Spontaneous chiral self-assembly of CdSe@CdS nanorods	71
Selective palladium recovery by a highly porous polyisothiocyanurate	71
Omics approach for electrolytes discovery	70
Cold-resilient zinc batteries with organic-free solvation structures	68
A clever trilayer assembly strategy for 2D materials	68
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	68
Industrial PhD: My way to go?	68
Molecule additive design for perovskite light-emitting diodes operated at high current densities	67
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	67
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	67
Reaction: Circular chemical imaginaries	66
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	66
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	66
Transformable quadruply interpenetrated cage with multiple states of different reactivities	66
High-resolution transmission electron microscopy of beam-sensitive halide perovskites	66
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	66
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	65
Frontier research in perovskite solar cells: Following the paths of European research and innovation	65
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	65
Metal-organic frameworks for water vapor adsorption	65
Aqueous electrocatalytic small-molecule valorization trilogy	64
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	64
Rationalizing the design and implementation of chiral hybrid perovskites	64
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	63
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	63
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	62
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	62
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	62
In this issue	61
Innovative low-carbon technology for a sustainable electrolyte industry	61
Hydrogen-bonded organic frameworks: Chemistry and functions	61
Dispersion-driven formation of chiral twisted PAH double helices	61
Conceptually novel diarylation for sustainable synthesis	61
Pursuing electrically pumped lasing with organic semiconductors	61
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	61
In this issue	61
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	60
Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques	60
Selective cellular probes for mammalian thioredoxin reductase TrxR1: Rational design of RX1, a modular 1,2-thiaselenane redox probe	59
Single-chain polymerization dynamics and conformational mechanics of conjugated polymers	59
The road to industrialization of fine chemical carboxylation reactions	59
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage	58
Sculpting photoproducts with DNA origami	58
Dynamic mechanoresponsive polymers enabled by ring-opening polymerization of cyclic propargyl carbonates	58
Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	58
Activating a light-driven molecular motor by metal complexation	57
Downsizing lactams via Rh-catalyzed C–C activation	57
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	56
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	56
High-level hierarchical morphology reinforcing covalent adaptable networks	56
Protein-directed, hydrogen-bonded biohybrid framework	55
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	55
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	55
Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution	54
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	54
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	53
Challenges for photocatalytic overall water splitting	53
DNA membrane nanopores with highly tunable shapes and sizes	52

The cyclotriborate trianion	52
Rethinking catalyst design by using data science	52
In my blue-light era	52
Operando scattering techniques for detecting precipitation reactions in lithium-sulfur batteries	52
Boosting single-molecule magnet performance	52
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	51
Single-component organic solar cells with over 11% efficiency	51
Biocatalytic activation of diazirines for carbene-transfer reactions	51
Electrophilic selenium drives electron leakage	50
Versatile deacylative cross-coupling of aromatic ketones	50
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	50
Remotely controllable supramolecular rotor mounted inside a porphyrinic cage	49
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	49
A 10-nm-sized multicompartment cuboctahedron and its 2D hierarchical arrays observed by cryo-EM	49
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	49
Reaction: A three-pronged approach toward a sustainable chemical industry	48
Role of delocalized electrons on the doping effect in vanadia	48
In this issue	48
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	48
Surface and interface control of black phosphorus	47
Van der Waals organic/inorganic heterostructures in the two-dimensional limit	47
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	47
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	47
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	47
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	46
Does in-situ-generated H2O2 promote important industrial reactions?	46
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	46
Evidence for new enantiospecific interaction force in chiral biomolecules	46
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	46
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	46
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	46
Supramolecular repair of hydration lubrication surfaces	45
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	45
Zero-valent species of group 13–15 elements	45
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	45
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	45
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	45
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	45
Information transduction via fuel-controlled chemical waves	45
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	44
Tailoring dynamic hydrogels by controlling associative exchange rates	44
The Co/NbN interphase as an effective ammonia synthesis catalyst	44
Controlled radical depolymerization: Structural differentiation and molecular weight control	44
Perovskite intermediate phases fundamentally address the urgent stability issue	44
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	44
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	44
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	44
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	43
Catalytic and selective chemical recycling of post-consumer rubbers into cycloalkenes	43
Reaction: Navigating the promises and perils of AI-powered drug synthesis	43
Triazasupersumanenes: Bowl-shaped nanographenes with tunable properties and unexpected charge transport performance	43
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	43
Mucin-mimetic glycan arrays integrating machine learning for analyzing receptor pattern recognition by influenza A viruses	43
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	42
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	42
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	42
Synthesizing a nanographyne	42
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	42
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	42
Championing systems thinking to create a circular economy of chemicals	42
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	41
Iron-mediated modular decarboxylative cross-nucleophile coupling	41
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	41
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	41
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	41
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	41
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	41
Selection of assembly complexity in a space of tetrapeptides	40
New insights and discoveries in anion receptor chemistry	40
Photoinduced, ground-state charge-transfer complex	40
A molecular communication channel consisting of a single reversible chain of hydrogen bonds in a conformationally flexible oligomer	40
Non-covalent interactions of graphene surface: Mechanisms and applications	40
The subtle art of radical control	40
The sustainability potential of single-atom catalysts in chemical process	40
New light on proton transfer: Spectral and kinetic signature of a transient Eigen complex	39
In This Issue	39
Deciphering the rational design of the early transition metals for ammonia synthesis	39
Connecting single-nucleotide polymorphisms, glycosylation status, and interactions of plasma serine protease inhibitors	39
Communication between active sites regulates heterogeneous catalysis	39
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	39
Integrating two contrasting biosynthetic pathways for peptide natural products	39
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	39
Stereodynamics of E/Z isomerization in rotaxanes through mechanical shuttling and covalent bond rotation	39
Electrochemical 6Li isotope enrichment based on selective insertion in 1D tunnel-structured V2O5	39
Quantitative and qualitative analysis of nitrogen species in carbon at the ppm level	39
Finding sustainable solutions	38
Reversible isomerization of metal nanoclusters induced by intermolecular interaction	38
3D-printing technologies for C1 chemistry	38
Reversible topochemical polymerization and depolymerization of a crystalline 3D porous organic polymer with C–C bond linkages	38
An ultra-dynamic anion-cluster-based organic framework	37
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	37
BINOLates as potent reducing photocatalysts for inert-bond activation and reduction of unsaturated systems	37
Dynamic active sites behind Cu-based electrocatalysts: Original or restructuring-induced catalytic activity	37
Selective and stable upgrading of biomass-derived furans into plastic monomers by coupling homogeneous and heterogeneous catalysis	37
Out-of-equilibrium chemical logic systems: Light- and sound-controlled programmable spatiotemporal patterns and mechanical functions	37