Nature Catalysis

Article	Citations
N-heteroarenes via transmutation	795
Multimodal in situ X-ray mechanistic studies of a bimetallic oxide electrocatalyst in alkaline media	791
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	709
Work in tandem	676
Greenwashed catalysis?	651
Cations galore	609
Recharge your batteries	505
Oxide mixology	485
Red light is ‘Go!’ for protein labelling	474
Lanthanide chemodivergence	473
Scatter and conquer	466
A precious pair for aldols	428
Seeing double	422
Setting the standard	407
Oxygen evolving atoms	403
Author Correction: Coupling electrochemical CO2 conversion with CO2 capture	392
Repurposing organic pollutants	384
N-between the aryls	360
Author Correction: Denary oxide nanoparticles as highly stable catalysts for methane combustion	357
Ammonia to chiral α-amino acid	313
Feeling the weight	310
O2-tolerant CO dehydrogenase via tunnel redesign for the removal of CO from industrial flue gas	302
Pushing hybrids to the limits	296
Nickel catalysts for affordable fuel cells	274
Reply to: Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	267

ML helps predict enzyme turnover rates	265
Imagine polypropylene	257
Publisher Correction: Switching of metal–oxygen hybridization for selective CO2 electrohydrogenation under mild temperature and pressure	251
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	247
Without that crystalline touch	245
Photobiocatalysts tame nitrogen-centred radicals	244
Drug design via single-carbon atom insertion	242
Bioproduction from methanol	236
Publisher Correction: Solid–liquid phase transition induced electrocatalytic switching from hydrogen evolution to highly selective CO2 reduction	234
PASADENA NMR	234
Deconvoluting the cation effect on carbon monoxide electroreduction	234
Publisher Correction: Catalyst control over sixfold stereogenicity	231
Non-innocent electrophiles unlock exogenous base-free coupling reactions	227
Harnessing the ambiphilicity of silyl nitronates in a catalytic asymmetric approach to aliphatic β3-amino acids	226
Stereodefined rhodium-catalysed 1,4-H/D delivery for modular syntheses and deuterium integration	222
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	220
Zeolites as equilibrium-shifting agents in shuttle catalysis	217
Enantioconvergent and regioselective reductive coupling of propargylic esters with chlorogermanes by nickel catalysis	214
Modifying Fe–N interaction to boost catalytic performance	207
Four on the floor	204
1,3-Butadiene formation through selective acetylene electrolysis on partially oxidized copper	195
Surface (dis)order sleuthing	190
Structure and engineering of miniature Acidibacillus sulfuroxidans Cas12f1	189
Catalysts made from vapour	189
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	187
An efficient catalytic route in haem peroxygenases mediated by O2/small-molecule reductant pairs for sustainable applications	184
Mind the gaps in CO2-to-methanol	180
Highly selective hydrogenation of CO2 to propane over GaZrOx/H-SSZ-13 composite	179
Mo3+ hydride as the common origin of H2 evolution and selective NADH regeneration in molybdenum sulfide electrocatalysts	178
Oxygenate-based routes regulate syngas conversion over oxide–zeolite bifunctional catalysts	177
Performance evaluation and multidisciplinary analysis of catalytic fixation reactions by material–microbe hybrids	172
Metallaphotoredox catalysis for sp3 C–H functionalizations through single-electron transfer	169
Nickel-catalysed enantioselective hydrosulfenation of alkynes	165
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	163
CO2 fixation into carbon nanofibres using electrochemical–thermochemical tandem catalysis	160
Harnessing electron-rich arenes in nickel photoredox catalysis	159
Lighten the holes	158
A MOF-supported Pd1–Au1 dimer catalyses the semihydrogenation reaction of acetylene in ethylene with a nearly barrierless activation energy	157
Regulating oxygen activity of perovskites to promote NOx oxidation and reduction kinetics	157
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	153
Catalytic synthesis of β-lactam derivatives by carbonylative cycloaddition of acylsilanes with imines via a palladium Fischer-carbene intermediate	150
Atomic metal–non-metal catalytic pair drives efficient hydrogen oxidation catalysis in fuel cells	149
Enhancing the connection between computation and experiments in electrocatalysis	147
Evidence of substrate binding and product release via belt-sulfur mobilization of the nitrogenase cofactor	146
Modulating the dynamics of Brønsted acid sites on PtWOx inverse catalyst	144
Electrified synthesis of n-propanol using a dilute alloy catalyst	143
Metallaphotoredox-enabled aminocarboxylation of alkenes with CO2	142
A heterogeneous iridium single-atom-site catalyst for highly regioselective carbenoid O–H bond insertion	141
Pickering emulsion droplets and solid microspheres acting synergistically for continuous-flow cascade reactions	139
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	135

Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium	135
Enantioselective C–H annulations enabled by either nickel- or cobalt-electrocatalysed C–H activation for catalyst-controlled chemodivergence	134
Enantioselective C–C cross-coupling of unactivated alkenes	132
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	132
Reaction environment impacts charge transfer but not chemical reaction steps in hydrogen evolution catalysis	131
High-performance anion-exchange membrane water electrolysers using NiX (X = Fe,Co,Mn) catalyst-coated membranes with redox-active Ni–O ligands	130
Selective deoxygenation of biomass-derived carbonyl compounds on Zn via electrochemical Clemmensen reduction	130
Radical control for enantioselective Csp3–Csp3 cross-coupling	129
Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	129
Operando proton-transfer-reaction time-of-flight mass spectrometry of carbon dioxide reduction electrocatalysis	126
Interplay of electrochemical and electrical effects induces structural transformations in electrocatalysts	123
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	120
Interfacial tuning of electrocatalytic Ag surfaces for fragment-based electrophile coupling	120
Selectively monitoring the operando temperature of active metal nanoparticles during catalytic reactions by X-ray absorption nanothermometry	119
Decreasing the catalytic ignition temperature of diesel soot using electrified conductive oxide catalysts	118
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	113
Maximizing light-driven CO2 and N2 fixation efficiency in quantum dot–bacteria hybrids	109
Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4	108
Coupling electrochemical CO2 conversion with CO2 capture	107
Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide	107
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	106
Metal-free organocatalytic S-formylation of thiols using CO2	106
Light-driven CO2 methanation over Au-grafted Ce0.95Ru0.05O2 solid-solution catalysts with activities approaching the thermodynamic limit	105
Cation-doped ZnS catalysts for polysulfide conversion in lithium–sulfur batteries	104
Selective production of ethylene glycol at high rate via cascade catalysis	102
Bacteria–photocatalyst sheet for sustainable carbon dioxide utilization	101
Intermetallic synergy in platinum–cobalt electrocatalysts for selective C–O bond cleavage	101
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	101
Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion	101
Engineering catalyst supports to stabilize PdOx two-dimensional rafts for water-tolerant methane oxidation	100
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	100
Redox-mediated electrosynthesis of ethylene oxide from CO2 and water	98
Ensemble effect for single-atom, small cluster and nanoparticle catalysts	98
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	96
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	95
Methanotrophic catalysis for methane oxidation to formaldehyde	95
Concentrating on ethanol	94
Density control	93
Ancient fixations	92
A breath of fresh air	92
An antidote for chemical reaction networks	91
Motorized catalysis	89
Big Al for In	88
Silver linings	87
Learning by osmosis	87
A titanic breakthrough	86
Acid solution	86
Deacylation-aided C–H alkylative annulation through C–C cleavage of unstrained ketones	85
Author Correction: Design and evolution of chimeric streptavidin for protein-enabled dual gold catalysis	85
Reshaping catalysis beyond the conventional	84
[Fe]-hydrogenase intermediates revealed	84
Synergistic role for CO	83
Olefin functionalization/isomerization enables stereoselective alkene synthesis	81
Reply to: Distinguishing thermal from non-thermal contributions to plasmonic hydrodefluorination	81
Electrocatalyst nanoparticles go with the flow	80
Boron-catalysed hydrogenolysis of unactivated C(aryl)–C(alkyl) bonds	80
RNA-catalysed guanosine methylation	80
Understanding organic electrosynthesis	79
On the role of metal cations in CO2 electrocatalytic reduction	79
The synchronized catalytic dance of CRISPR-Cas9	79
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	79
Electrochemistry-inspired design of thermocatalysts	77
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	77
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	76
A radical strategy towards ortho-amination reactions	75
Identifying the activity of nanocatalyst sites	75
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	75
Publisher Correction: Bacteria–photocatalyst sheet for sustainable carbon dioxide utilization	75
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	74
Author Correction: Stabilization of layered lithium-rich manganese oxide for anion exchange membrane fuel cells and water electrolysers	73
New tricks for old plastics	72
Stereoselective alkyl–alkyl cross-coupling	72
A boronic enzyme	71
Metal–support cooperation in Al(PO3)3-supported platinum nanoparticles for the selective hydrogenolysis of phenols to arenes	70
Site- and enantioselective allylic and propargylic C–H oxidation enabled by copper-based biomimetic catalysis	70
Privileged Brønsted acid organocatalysis	70
Neither H2 nor O2 in hydrogenative oxidations with water	70
Molecular water oxidation catalysts based on first-row transition metal complexes	69
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	68
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts	68

Light on peroxide	68
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	67
Atomically dispersed Pt and Fe sites and Pt–Fe nanoparticles for durable proton exchange membrane fuel cells	67
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	67
Halide-guided active site exposure in bismuth electrocatalysts for selective CO2 conversion into formic acid	66
Coupled catalytic states and the role of metal coordination in Cas9	66
Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	65
Ternary ruthenium complex hydrides for ammonia synthesis via the associative mechanism	64
Cascade electrosynthesis of LiTFSI and N-containing analogues via a looped Li–N2 battery	64
An electrochemical way to pure ethylene	63
Nickel-catalysed asymmetric heteroarylative cyclotelomerization of isoprene	63
An electrochemical approach for designing thermochemical bimetallic nitrate hydrogenation catalysts	63
Regulation of the electrocatalytic nitrogen cycle based on sequential proton–electron transfer	63
Engineering the Cu/Mo2CTx (MXene) interface to drive CO2 hydrogenation to methanol	62
Alkali metal cations act as homogeneous cocatalysts for the oxygen reduction reaction in aqueous electrolytes	62
Chemodivergent C(sp3)–H and C(sp2)–H cyanomethylation using engineered carbene transferases	61
Standardized protocols for evaluating platinum group metal-free oxygen reduction reaction electrocatalysts in polymer electrolyte fuel cells	60
The identification and characterization of a selected SAM-dependent methyltransferase ribozyme that is present in natural sequences	60
Enantioconvergent nucleophilic substitution via synergistic phase-transfer catalysis	60
Electrochemical acetate production from high-pressure gaseous and liquid CO2	60
Identification of the active sites in supported subnanometric metal catalysts	59
Direct methane activation by atomically thin platinum nanolayers on two-dimensional metal carbides	58
DYW domain structures imply an unusual regulation principle in plant organellar RNA editing catalysis	58
Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis	57
Plasmonic bimetallic two-dimensional supercrystals for H2 generation	57
Machine learning-enabled retrobiosynthesis of molecules	57
Site-selective arene C–H amination with iron-aminyl radical	57
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	57
Programmed exosome fusion for energy generation in living cells	56
Deep learning-based kcat prediction enables improved enzyme-constrained model reconstruction	56
Room-temperature electrochemical acetylene reduction to ethylene with high conversion and selectivity	55
Au-ZSM-5 catalyses the selective oxidation of CH4 to CH3OH and CH3COOH using O2	55
Synergistic interactions between PtRu catalyst and nitrogen-doped carbon support boost hydrogen oxidation	55
Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses	54
Carbon monoxide enabling synergistic carbonylation and (hetero)aryl migration	53
The iron-catalysed Suzuki coupling of aryl chlorides	53
Rational design of perovskite ferrites as high-performance proton-conducting fuel cell cathodes	53
Light-driven CO2 sequestration in Escherichia coli to achieve theoretical yield of chemicals	53
On the origin of multihole oxygen evolution in haematite photoanodes	52
Symbiotic oxides in catalysts	51
Enantioselective alkylation of α-amino C(sp3)−H bonds via photoredox and nickel catalysis	51
Directed evolution of an efficient and thermostable PET depolymerase	51
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	51
Dicarboxylation of alkenes, allenes and (hetero)arenes with CO2 via visible-light photoredox catalysis	50
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	50
Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts	49
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	49
Photoenzymatic enantioselective intermolecular radical hydroamination	49
Urea synthesis via electrocatalytic oxidative coupling of CO with NH3 on Pt	48
Best practices for experiments and reporting in photocatalytic CO2 reduction	47
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	47
Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium	46
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	46
Acid-stable manganese oxides for proton exchange membrane water electrolysis	45
Dynamic and reversible transformations of subnanometre-sized palladium on ceria for efficient methane removal	45
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	45
Benign hyperpolarization	45
Hydrogen bond network connectivity in the electric double layer dominates the kinetic pH effect in hydrogen electrocatalysis on Pt	45
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	44
Core strength	44
Electrify to decarbonize	44
Development of a versatile and efficient C–N lyase platform for asymmetric hydroamination via computational enzyme redesign	44
The quest for correlations	43
Heavy labels from gas surrogates	43
Biocatalytic polymer synthesis with β-amino acids	43
A Janus concept against flooding	43
Scaling it up	43
Plasmonic polemic	43
An enantioselective HAT for diols	42
Generating alkyl carbanions for organic synthesis	42
Reaching out	42
Effective anions	42
Chiral phosphorus compounds by catalytic asymmetric C–P coupling	42
Engineering yeast metabolism for the discovery and production of polyamines and polyamine analogues	41
High-throughput activity screening and sorting of single catalyst particles with a droplet microreactor using dielectrophoresis	41
Retraction Note: Theory-guided Sn/Cu alloying for efficient CO2 electroreduction at low overpotentials	41
Author Correction: Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide	40
Iron-catalysed regioselective thienyl C–H/C–H coupling	40
Author Correction: Solar methanol energy storage	40
Striking gold with chimeric proteins	40
Electrocatalytic cyclic deracemization enabled by a chemically modified electrode	39
LimF is a versatile prenyltransferase for histidine-C-geranylation on diverse non-natural substrates	39
Author Correction: Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols	39
An enzyme to cure age-related diseases	39
Spectroscopy predicts catalyst functionality	38
In the zeolite zone	38
Cations play an essential role in CO2 reduction	37
Defying thermodynamics to synthetize hydrazine	35
Alkene 1,1-difunctionalizations via organometallic-radical relay	35
Choreography of a self-splicing ribozyme	35
The 3D secrets of fuel cell catalyst layers	35
Methane oxidation by catalyst reduction	34
Nitrogenase loosens its belt to fix dinitrogen	34
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	34
Parallel experiments in electrochemical CO2 reduction enabled by standardized analytics	34