Nature Catalysis

Article	Citations
Greenwashed catalysis?	798
PASADENA NMR	676
N-between the aryls	585
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	559
Bioproduction from methanol	555
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	540
Electrocatalytic upcycling of high-pressure captured CO2 to ethylene	522
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	510
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	408
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	405
An NAD⁺ analogue enables assembly of structurally diverse artificial photoenzymes for enantiodivergent [2 + 2] cycloadditions	399
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	379
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	365
Red light is ‘Go!’ for protein labelling	360
Enhancing the connection between computation and experiments in electrocatalysis	349
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	347
Imagine polypropylene	336
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	335
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	333
Methanotrophic catalysis for methane oxidation to formaldehyde	319
Neither H2 nor O2 in hydrogenative oxidations with water	315
Pulsed away	313
Quantum computing for faster enzyme discovery and engineering	309
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	309
Growing the carbon chain	300

Electrochemistry-inspired design of thermocatalysts	283
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	279
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	278
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	276
Density control	249
The synchronized catalytic dance of CRISPR-Cas9	248
Behind the curtain	246
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	246
Motorized catalysis	246
Symbiotic oxides in catalysts	245
The iron-catalysed Suzuki coupling of aryl chlorides	244
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	238
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	233
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	233
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	231
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	230
O2 so good	228
Heavy labels from gas surrogates	226
Choreography of a self-splicing ribozyme	226
Optimizing iridium sites	224
Iminium catalysis in natural Diels–Alderase	222
Electrolysis in tandem	204
Substrate promiscuity fuels biosynthesis success	199
Pulsed electrolysis through neutron lenses	199
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	193
Electrolyte effects in proton–electron transfer reactions and implications for renewable fuels and chemicals synthesis	193
Morphological and chemical state effects in pulsed CO2 electroreduction on Cu(100) unveiled by correlated spectro-microscopy	189
Current state and future prospects of liquid metal catalysis	188
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	185
Enantioselective radical dearomative conjugate amination enabled by Co(II)-based metalloradical catalysis	184
Active sites overcrowding	183
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	182
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	180
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	179
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	171
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	163
The rise of ab initio surface thermodynamics	161
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	160
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	160
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	155
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	154
Copper-catalysed enantioconvergent O-alkylation of alcohols with racemic α-tertiary haloamides to access enantioenriched hindered dialkyl ethers	151
One, two, three, four, five!	148
Modulation to probe the interface	145
Organocatalytic acylation of remote arene C–H bonds	145
Bubble trouble	145
Determining CO adsorption free energies on CO2 electroreduction active sites through kinetic analysis	139
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	139
Catalytic borylation of tertiary C–H bonds	137
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	136

Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	136
Triplet quenchers for energy-transfer photobiocatalysis	134
Catalysing rate and capacity	134
Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	133
Structural insights and engineering of the T4 td intron for improved RNA circularization	132
Durable MnO2 electrocatalysts by stronger Mn–O bonds	132
Practical conversion of carboxylic acids to nitriles	132
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	129
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	127
Wireless potentiometry of thermochemical heterogeneous catalysis	126
Lengthened by ethylene	125
Blowing in the tube	124
Author Correction: Stereoselective alkyl–alkyl cross-coupling	123
Tailored for semi-hydrogenation	122
CYP screening for a better terpenoid world	122
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	121
Frustration-driven efficiency	119
Regioselective silyl installation for arene diversification	119
Bridging catalysis	118
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	117
A fine adjustment	116
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	115
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	111
Silicon frustrated Lewis pairs catalyse α-deuteration of amides and esters	111
Electrosynthesis of ethylene glycol from ethylene coupled with CO2 capture	109
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	109
Enantioselective Chan–Lam S-arylation of sulfenamides	108
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	105
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	105
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	104
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	104
Step bunching instability and its effects in electrocatalysis on platinum surfaces	102
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	102
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	102
An efficient Morita–Baylis–Hillmanase	101
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	101
Terpene synthases in giant viruses	101
Divide and conquer towards synthetic autotrophy	100
Shining light to break planarity	100
Catalyst optimization through synthetic Darwinian evolution	99
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	99
A modular synthesis of azetidines from reactive triplet imine intermediates using an intermolecular aza Paternò–Büchi reaction	98
A TIM-barrel metalloenzyme with sugar-cleavage activity	98
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	97
Cations in alkaline hydrogen electrocatalysis	95
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	94
Author Correction: Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface	93
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	92
Monitoring catalytic nanosites in action	92
Mass-based biocatalyst metrics to guide protein engineering and bioprocess development	92
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	92
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	92
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	90
The STRENDA Biocatalysis Guidelines for cataloguing metadata	88
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	88
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	87
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	87
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	85
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering	85
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	85
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	85
Methyl formate as a hydrogen energy carrier	84
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	84
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	84
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	83
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	82
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	82
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	81
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	81
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	81
Recharge your batteries	80
Scatter and conquer	78
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	77
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	76
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	76
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	76
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	76
An antidote for chemical reaction networks	76
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	75
Shape matters too	75

Privileged Brønsted acid organocatalysis	74
Challenges and prospects in precision medicine with RNA-based biocatalysts	74
Complex behaviour of isotopes in CO2 electroreduction	74
Site-selective arene C–H amination with iron-aminyl radical	73
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	73
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	72
Photoenzymatic enantioselective intermolecular radical hydroamination	72
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	72
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	71
Seeking selectivity in alkene couplings	70
Deciphering electrochemical methanol production	69
Benign hyperpolarization	68
A radical way to ethylene	67
Defying thermodynamics to synthetize hydrazine	66
The 3D secrets of fuel cell catalyst layers	66
Operando probing dynamic migration of copper carbonyl during electrocatalytic CO2 reduction	65
A pyridoxal 5′-phosphate-dependent Mannich cyclase	64
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	64
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	63
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	62
Unlocking iron spin states for oxygen reduction	62
Methane oxidation by catalyst reduction	61
Generating alkyl carbanions for organic synthesis	61
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	61
Organocatalytic regio- and stereoselective cyclopropanation of olefins	60
Effective anions	60
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction	60
Alkene 1,1-difunctionalizations via organometallic-radical relay	60
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	60
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	59
Rising to the surface	59
Immobilized cations boost acidic CO2 reduction	58
Pushing the boundaries of biocatalysis	58
Controlling carbocations	58
Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation	57
A structured catalyst for anion exchange membrane water electrolysis	56
A red-light-powered silicon nanowire biophotochemical diode for simultaneous CO2 reduction and glycerol valorization	55
The value of negative results in data-driven catalysis research	55
The functional coupling between restriction and DNA phosphorothioate modification systems underlying the DndFGH restriction complex	55
Artificial enzymes for artificial photosynthesis	55
Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2	54
Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3	53
Catalytic mechanism for Renilla-type luciferases	53
Active alloy ahoy!	52
Clustering for methane	50
Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	50
Unlocking C–C cleavage in the electrochemical toolbox	50
Molecular mechanism of topoisomerase poisoning by the peptide antibiotic albicidin	49
Enantioconvergent copper-catalysed difluoromethylation of alkyl halides	49
Rates against the machine	49
Sub-micro- and nano-sized polyethylene terephthalate deconstruction with engineered protein nanopores	48
Catalytic cycle of formate dehydrogenase captured by single-molecule conductance	48
Tunable layered Mn oxides for oxygen electrocatalysis	48
Iron-catalysed alkenylzincation of allenes via electrophilicity reversal	48
Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2 + 2] cycloaddition/rearrangement reactions of quinolines with alkenes	48
Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation	47
Sustainable methanol synthesis	47
Different distributions of multi-carbon products in CO2 and CO electroreduction under practical reaction conditions	47
The era of stable electrocatalysis	47
Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	46
Structurally defined anti-π-allyliridium complexes catalyse Z-retentive asymmetric allylic alkylation of oxindoles	46
Threshold potentials for fast kinetics during mediated redox catalysis of insulators in Li–O2 and Li–S batteries	46
Edge sites dominate the hydrogen evolution reaction on platinum nanocatalysts	46
Critical enzyme reactions in aromatic catabolism for microbial lignin conversion	45
Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9	45
Enhancing the stability of cobalt spinel oxide towards sustainable oxygen evolution in acid	45
Establishing coupling trends	44
Microenvironment control	44
Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds	44
A zero-gap bipolar solution	44
Photoenzymes for radical C–C coupling	43
Radical dissolution	43
Publisher Correction: A selective Au-ZnO/TiO2 hybrid photocatalyst for oxidative coupling of methane to ethane with dioxygen	43
And yet it rotates!	42
Activating catalysts by adsorbate-induced reconstructions	42
Iron–sulfur cluster with double duty	41
Unveiling metal mobility in a liquid Cu–Ga catalyst for ammonia synthesis	41
Birth of organocatalysis by N-heterocyclic carbenes	41
The deuterium source matters	41
Mimicking hydrogen-atom-transfer-like reactivity in copper-catalysed olefin hydrofunctionalization	41
Decoding CO2 hydrogenation	41
Iridium nitrenoid-enabled arene C−H functionalization	41
Selective electrooxidation of 5-hydroxymethylfurfural at pilot scale by engineering a solid polymer electrolyte reactor	40
Unveiling the reconstruction of copper bimetallic catalysts during CO2 electroreduction	40
Delocalization state-induced selective bond breaking for efficient methanol electrosynthesis from CO2	40
Oxide mixology	39
Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer	39
The why and how of NOx electroreduction to ammonia	39
Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles	39
Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions	39
ML helps predict enzyme turnover rates	39
Three-dimensional nanoimaging of fuel cell catalyst layers	39
Work in tandem	37
A precious pair for aldols	37
Drug design via single-carbon atom insertion	37