Nature Catalysis

Article	Citations
Greenwashed catalysis?	849
PASADENA NMR	669
Bioproduction from methanol	597
N-between the aryls	552
Enhancing the connection between computation and experiments in electrocatalysis	529
Red light is ‘Go!’ for protein labelling	510
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	500
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	490
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	489
Electrocatalytic upcycling of high-pressure captured CO2 to ethylene	468
Imagine polypropylene	456
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	450
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	366
An NAD⁺ analogue enables assembly of structurally diverse artificial photoenzymes for enantiodivergent [2 + 2] cycloadditions	352
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	337
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	336
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	323
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	313
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	310
Neither H2 nor O2 in hydrogenative oxidations with water	307
Silver linings	294
Methanotrophic catalysis for methane oxidation to formaldehyde	293
Density control	288
Electrochemistry-inspired design of thermocatalysts	286
The iron-catalysed Suzuki coupling of aryl chlorides	283

Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	278
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	277
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	277
Symbiotic oxides in catalysts	276
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	274
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	273
Programmed exosome fusion for energy generation in living cells	271
RNA-catalysed guanosine methylation	268
The synchronized catalytic dance of CRISPR-Cas9	264
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	245
Motorized catalysis	238
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	225
Behind the curtain	223
Pulsed away	218
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	217
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts	216
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	215
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	214
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	213
O2 so good	212
Choreography of a self-splicing ribozyme	212
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	206
Optimizing iridium sites	205
Heavy labels from gas surrogates	202
Retro Hits	195
Pulsed electrolysis through neutron lenses	188
Active sites overcrowding	184
Iminium catalysis in natural Diels–Alderase	183
Metabolic network remodelling enhances yeast’s fitness on xylose using aerobic glycolysis	183
The rise of ab initio surface thermodynamics	182
Morphological and chemical state effects in pulsed CO2 electroreduction on Cu(100) unveiled by correlated spectro-microscopy	182
Copper-catalysed enantioconvergent O-alkylation of alcohols with racemic α-tertiary haloamides to access enantioenriched hindered dialkyl ethers	181
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	175
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	174
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	173
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	168
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	164
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	163
Current state and future prospects of liquid metal catalysis	163
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	160
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	156
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	156
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	153
One, two, three, four, five!	151
Organocatalytic acylation of remote arene C–H bonds	150
Catalysing rate and capacity	147
Modulation to probe the interface	144
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	144
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	141
Bubble trouble	141

Wireless potentiometry of thermochemical heterogeneous catalysis	134
Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	130
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	129
Durable MnO2 electrocatalysts by stronger Mn–O bonds	129
Catalytic borylation of tertiary C–H bonds	128
Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	127
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	126
Lengthened by ethylene	125
Author Correction: Stereoselective alkyl–alkyl cross-coupling	125
Tailored for semi-hydrogenation	124
CYP screening for a better terpenoid world	124
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	123
Blowing in the tube	123
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	123
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	122
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	119
Regioselective silyl installation for arene diversification	119
Bridging catalysis	115
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	113
A fine adjustment	113
Electrosynthesis of ethylene glycol from ethylene coupled with CO2 capture	113
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	113
Step bunching instability and its effects in electrocatalysis on platinum surfaces	112
Frustration-driven efficiency	111
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	111
Enantioselective Chan–Lam S-arylation of sulfenamides	110
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	110
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	110
Uniting biological and chemical strategies for selective CO2 reduction	109
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	107
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	106
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	105
An efficient Morita–Baylis–Hillmanase	104
Shining light to break planarity	103
Divide and conquer towards synthetic autotrophy	103
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	103
Terpene synthases in giant viruses	100
Mass-based biocatalyst metrics to guide protein engineering and bioprocess development	98
The STRENDA Biocatalysis Guidelines for cataloguing metadata	98
Cations in alkaline hydrogen electrocatalysis	97
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	96
Author Correction: Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface	95
Monitoring catalytic nanosites in action	95
The shape of water in zeolites and its impact on epoxidation catalysis	94
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	94
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	93
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	92
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	92
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	92
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	91
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	90
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	90
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering	89
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	89
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	89
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	88
Atomically dispersed iridium on MgO(111) nanosheets catalyses benzene–ethylene coupling towards styrene	88
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	87
Methyl formate as a hydrogen energy carrier	87
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	86
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	86
Operando visualization of the hydrogen evolution reaction with atomic-scale precision at different metal–graphene interfaces	85
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	85
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	85
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	84
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	83
Recharge your batteries	82
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	82
Scatter and conquer	82
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	81
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	80
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	80
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	77
Coupling electrochemical CO2 conversion with CO2 capture	76
An antidote for chemical reaction networks	76
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	76
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	75
Challenges and prospects in precision medicine with RNA-based biocatalysts	75
Shape matters too	75
Complex behaviour of isotopes in CO2 electroreduction	72

Photoenzymatic enantioselective intermolecular radical hydroamination	72
Privileged Brønsted acid organocatalysis	71
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	71
Site-selective arene C–H amination with iron-aminyl radical	71
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	71
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	71
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	70
Self-correcting science at work	69
Deciphering electrochemical methanol production	69
Benign hyperpolarization	69
Seeking selectivity in alkene couplings	69
Defying thermodynamics to synthetize hydrazine	68
Chiral phosphorus compounds by catalytic asymmetric C–P coupling	68
Effective anions	68
The 3D secrets of fuel cell catalyst layers	67
Organocatalytic regio- and stereoselective cyclopropanation of olefins	67
A radical way to ethylene	67
Unlocking iron spin states for oxygen reduction	67
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	66
Methane oxidation by catalyst reduction	65
Alkene 1,1-difunctionalizations via organometallic-radical relay	65
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	64
Operando probing dynamic migration of copper carbonyl during electrocatalytic CO2 reduction	64
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	63
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	61
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction	60
Generating alkyl carbanions for organic synthesis	60
A pyridoxal 5′-phosphate-dependent Mannich cyclase	60
High-purity and high-concentration liquid fuels through CO2 electroreduction	60
Assisting with protons	59
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	59
Artificial enzymes for artificial photosynthesis	59
Rising to the surface	59
Electrifying start-up	59
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	59
Controlling carbocations	58
A structured catalyst for anion exchange membrane water electrolysis	58
Immobilized cations boost acidic CO2 reduction	57
The value of negative results in data-driven catalysis research	55
Catalytic mechanism for Renilla-type luciferases	55
The functional coupling between restriction and DNA phosphorothioate modification systems underlying the DndFGH restriction complex	55
Electrocatalytic conversion of carbon dioxide for the Paris goals	54
Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2	53
Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation	53
Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3	53
The masked synthon	52
Active alloy ahoy!	52
A red-light-powered silicon nanowire biophotochemical diode for simultaneous CO2 reduction and glycerol valorization	52
Unlocking C–C cleavage in the electrochemical toolbox	51
Molecular mechanism of topoisomerase poisoning by the peptide antibiotic albicidin	51
Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	51
The era of stable electrocatalysis	51
Clustering for methane	51
Rates against the machine	50
Iron-catalysed alkenylzincation of allenes via electrophilicity reversal	50
Catalytic cycle of formate dehydrogenase captured by single-molecule conductance	50
An enantioselective ambimodal cross-Diels–Alder reaction and applications in synthesis	49
Sustainable methanol synthesis	48
Structurally defined anti-π-allyliridium complexes catalyse Z-retentive asymmetric allylic alkylation of oxindoles	48
Sub-micro- and nano-sized polyethylene terephthalate deconstruction with engineered protein nanopores	48
Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2 + 2] cycloaddition/rearrangement reactions of quinolines with alkenes	47
Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation	47
Enantioconvergent copper-catalysed difluoromethylation of alkyl halides	47
Critical enzyme reactions in aromatic catabolism for microbial lignin conversion	47
Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	46
Tunable layered Mn oxides for oxygen electrocatalysis	46
Edge sites dominate the hydrogen evolution reaction on platinum nanocatalysts	46
Different distributions of multi-carbon products in CO2 and CO electroreduction under practical reaction conditions	44
Threshold potentials for fast kinetics during mediated redox catalysis of insulators in Li–O2 and Li–S batteries	43
Enhancing the stability of cobalt spinel oxide towards sustainable oxygen evolution in acid	43
Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9	43
Activating catalysts by adsorbate-induced reconstructions	42
A zero-gap bipolar solution	42
Microenvironment control	42
Starch synthesis from CO2	42
Mimicking hydrogen-atom-transfer-like reactivity in copper-catalysed olefin hydrofunctionalization	40
And yet it rotates!	40
Decoding CO2 hydrogenation	40
Radical dissolution	40
Birth of organocatalysis by N-heterocyclic carbenes	40
Photoenzymes for radical C–C coupling	40
Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer	39
Iron–sulfur cluster with double duty	39
Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles	39
Delocalization state-induced selective bond breaking for efficient methanol electrosynthesis from CO2	38
Direct propylene epoxidation with oxygen using a photo-electro-heterogeneous catalytic system	38
Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds	38
Unveiling metal mobility in a liquid Cu–Ga catalyst for ammonia synthesis	38
Iridium nitrenoid-enabled arene C−H functionalization	38
Publisher Correction: A selective Au-ZnO/TiO2 hybrid photocatalyst for oxidative coupling of methane to ethane with dioxygen	38
Selective electrooxidation of 5-hydroxymethylfurfural at pilot scale by engineering a solid polymer electrolyte reactor	38
Bimetallic monolayer catalyst breaks the activity–selectivity trade-off on metal particle size for efficient chemoselective hydrogenations	37
Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions	37
Three-dimensional nanoimaging of fuel cell catalyst layers	37
The why and how of NOx electroreduction to ammonia	36