Nature Catalysis

Article	Citations
Greenwashed catalysis?	809
PASADENA NMR	684
N-between the aryls	636
Bioproduction from methanol	580
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	534
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	516
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	496
Red light is ‘Go!’ for protein labelling	480
Enhancing the connection between computation and experiments in electrocatalysis	475
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	461
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	456
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	444
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	435
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	361
Imagine polypropylene	352
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	340
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	320
Neither H2 nor O2 in hydrogenative oxidations with water	319
Silver linings	312
Methanotrophic catalysis for methane oxidation to formaldehyde	305
Density control	298
Electrochemistry-inspired design of thermocatalysts	291
Programmed exosome fusion for energy generation in living cells	287
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	281
The iron-catalysed Suzuki coupling of aryl chlorides	279

RNA-catalysed guanosine methylation	277
The synchronized catalytic dance of CRISPR-Cas9	273
Motorized catalysis	271
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	271
Pulsed away	269
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	267
Behind the curtain	265
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	263
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts	258
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	256
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	253
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	233
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	230
Symbiotic oxides in catalysts	215
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	215
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	214
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	211
Choreography of a self-splicing ribozyme	209
O2 so good	208
Optimizing iridium sites	206
Heavy labels from gas surrogates	204
Retro Hits	202
Iminium catalysis in natural Diels–Alderase	201
Pulsed electrolysis through neutron lenses	197
Active sites overcrowding	194
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	193
Metabolic network remodelling enhances yeast’s fitness on xylose using aerobic glycolysis	189
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	186
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	181
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	180
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	177
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	172
The rise of ab initio surface thermodynamics	172
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	171
Current state and future prospects of liquid metal catalysis	170
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	170
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	168
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	166
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	160
One, two, three, four, five!	158
Catalysing rate and capacity	157
Organocatalytic acylation of remote arene C–H bonds	157
Bubble trouble	152
Wireless potentiometry of thermochemical heterogeneous catalysis	149
Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	147
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	146
Modulation to probe the interface	141
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	139
Catalytic borylation of tertiary C–H bonds	138
Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	136

Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	134
Durable MnO2 electrocatalysts by stronger Mn–O bonds	132
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	130
Lengthened by ethylene	128
Frustration-driven efficiency	127
Author Correction: Stereoselective alkyl–alkyl cross-coupling	126
CYP screening for a better terpenoid world	125
Tailored for semi-hydrogenation	122
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	121
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	120
Blowing in the tube	120
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	118
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	118
Bridging catalysis	118
Regioselective silyl installation for arene diversification	118
A fine adjustment	117
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	116
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	115
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	114
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	112
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	112
Step bunching instability and its effects in electrocatalysis on platinum surfaces	110
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	110
The role of ruthenium in improving the kinetics of hydrogen oxidation and evolution reactions of platinum	109
Enantioselective Chan–Lam S-arylation of sulfenamides	109
Uniting biological and chemical strategies for selective CO2 reduction	109
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	108
An efficient Morita–Baylis–Hillmanase	107
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	107
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	106
Divide and conquer towards synthetic autotrophy	103
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	101
Terpene synthases in giant viruses	101
Shining light to break planarity	101
Cations in alkaline hydrogen electrocatalysis	99
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	97
Author Correction: Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface	96
Monitoring catalytic nanosites in action	96
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	95
The STRENDA Biocatalysis Guidelines for cataloguing metadata	95
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	95
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	93
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	93
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	93
The shape of water in zeolites and its impact on epoxidation catalysis	92
Operando visualization of the hydrogen evolution reaction with atomic-scale precision at different metal–graphene interfaces	91
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	90
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	90
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	90
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	88
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	88
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	87
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	87
Atomically dispersed iridium on MgO(111) nanosheets catalyses benzene–ethylene coupling towards styrene	87
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	84
Mass-based biocatalyst metrics to guide protein engineering and bioprocess development	84
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	84
Methyl formate as a hydrogen energy carrier	84
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	83
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	83
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering	82
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	82
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	82
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	81
Recharge your batteries	81
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	81
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	81
Scatter and conquer	81
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	79
Coupling electrochemical CO2 conversion with CO2 capture	78
An antidote for chemical reaction networks	77
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	77
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	75
Challenges and prospects in precision medicine with RNA-based biocatalysts	75
Shape matters too	75
Complex behaviour of isotopes in CO2 electroreduction	74
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	74
Site-selective arene C–H amination with iron-aminyl radical	74
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	73
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	72

Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	72
Photoenzymatic enantioselective intermolecular radical hydroamination	71
Privileged Brønsted acid organocatalysis	71
Deciphering electrochemical methanol production	70
Benign hyperpolarization	69
Seeking selectivity in alkene couplings	69
Self-correcting science at work	69
Chiral phosphorus compounds by catalytic asymmetric C–P coupling	68
Effective anions	68
Defying thermodynamics to synthetize hydrazine	68
Operando probing dynamic migration of copper carbonyl during electrocatalytic CO2 reduction	67
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	67
Methane oxidation by catalyst reduction	67
Unlocking iron spin states for oxygen reduction	67
Organocatalytic regio- and stereoselective cyclopropanation of olefins	66
A radical way to ethylene	65
A pyridoxal 5′-phosphate-dependent Mannich cyclase	65
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	65
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	64
Alkene 1,1-difunctionalizations via organometallic-radical relay	64
Generating alkyl carbanions for organic synthesis	64
High-purity and high-concentration liquid fuels through CO2 electroreduction	63
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	63
The 3D secrets of fuel cell catalyst layers	61
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction	60
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	60
Rising to the surface	60
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	60
Controlling carbocations	59
Assisting with protons	59
Artificial enzymes for artificial photosynthesis	59
Electrifying start-up	59
A structured catalyst for anion exchange membrane water electrolysis	58
Catalytic mechanism for Renilla-type luciferases	57
The functional coupling between restriction and DNA phosphorothioate modification systems underlying the DndFGH restriction complex	57
Immobilized cations boost acidic CO2 reduction	56
Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3	55
Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation	55
A red-light-powered silicon nanowire biophotochemical diode for simultaneous CO2 reduction and glycerol valorization	55
Active alloy ahoy!	54
Electrocatalytic conversion of carbon dioxide for the Paris goals	54
Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2	54
The value of negative results in data-driven catalysis research	54
The masked synthon	53
Unlocking C–C cleavage in the electrochemical toolbox	52
Sustainable methanol synthesis	52
Molecular mechanism of topoisomerase poisoning by the peptide antibiotic albicidin	51
Clustering for methane	51
Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	51
Catalytic cycle of formate dehydrogenase captured by single-molecule conductance	50
Iron-catalysed alkenylzincation of allenes via electrophilicity reversal	50
Rates against the machine	50
Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9	50
Tunable layered Mn oxides for oxygen electrocatalysis	50
Sub-micro- and nano-sized polyethylene terephthalate deconstruction with engineered protein nanopores	49
An enantioselective ambimodal cross-Diels–Alder reaction and applications in synthesis	49
The era of stable electrocatalysis	48
Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	48
Enantioconvergent copper-catalysed difluoromethylation of alkyl halides	48
Critical enzyme reactions in aromatic catabolism for microbial lignin conversion	48
Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation	47
Edge sites dominate the hydrogen evolution reaction on platinum nanocatalysts	47
Different distributions of multi-carbon products in CO2 and CO electroreduction under practical reaction conditions	46
Threshold potentials for fast kinetics during mediated redox catalysis of insulators in Li–O2 and Li–S batteries	46
Enhancing the stability of cobalt spinel oxide towards sustainable oxygen evolution in acid	46
Structurally defined anti-π-allyliridium complexes catalyse Z-retentive asymmetric allylic alkylation of oxindoles	45
Microenvironment control	45
Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2 + 2] cycloaddition/rearrangement reactions of quinolines with alkenes	45
Activating catalysts by adsorbate-induced reconstructions	44
A zero-gap bipolar solution	44
Publisher Correction: A selective Au-ZnO/TiO2 hybrid photocatalyst for oxidative coupling of methane to ethane with dioxygen	43
Starch synthesis from CO2	42
And yet it rotates!	42
Radical dissolution	42
Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer	41
Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds	41
Decoding CO2 hydrogenation	41
Photoenzymes for radical C–C coupling	41
Iridium nitrenoid-enabled arene C−H functionalization	39
Direct propylene epoxidation with oxygen using a photo-electro-heterogeneous catalytic system	39
Unveiling the reconstruction of copper bimetallic catalysts during CO2 electroreduction	39
The why and how of NOx electroreduction to ammonia	38
Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles	38
Unveiling metal mobility in a liquid Cu–Ga catalyst for ammonia synthesis	38
Birth of organocatalysis by N-heterocyclic carbenes	38
Mimicking hydrogen-atom-transfer-like reactivity in copper-catalysed olefin hydrofunctionalization	38
Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions	37
Bimetallic monolayer catalyst breaks the activity–selectivity trade-off on metal particle size for efficient chemoselective hydrogenations	37
Delocalization state-induced selective bond breaking for efficient methanol electrosynthesis from CO2	37
Four on the floor	37
Three-dimensional nanoimaging of fuel cell catalyst layers	37
Oxide mixology	36
Catalysts made from vapour	36
Work in tandem	36
A precious pair for aldols	36