Nature Catalysis

Article	Citations
Greenwashed catalysis?	883
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	681
Bioproduction from methanol	584
Red light is ‘Go!’ for protein labelling	568
PASADENA NMR	566
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	464
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	459
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	433
Imagine polypropylene	399
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	388
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	386
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	385
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	380
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	372
N-between the aryls	341
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	341
Zeolites like to move it	333
Supramolecular control of cationic intermediates	319
Enhancing the connection between computation and experiments in electrocatalysis	310
Electrocatalytic upcycling of high-pressure captured CO2 to ethylene	292
An NAD⁺ analogue enables assembly of structurally diverse artificial photoenzymes for enantiodivergent [2 + 2] cycloadditions	290
Methanotrophic catalysis for methane oxidation to formaldehyde	274
Neither H2 nor O2 in hydrogenative oxidations with water	272
Pulsed away	271
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	270

Growing the carbon chain	269
Density control	264
The synchronized catalytic dance of CRISPR-Cas9	263
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	260
Behind the curtain	253
Electrochemistry-inspired design of thermocatalysts	250
Motorized catalysis	247
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	230
Tailored water–surface interactions on cobalt oxide for stable proton-exchange-membrane water electrolysis	229
Symbiotic oxides in catalysts	229
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	222
Fluoroform for PET	213
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	209
Quantum computing for faster enzyme discovery and engineering	206
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	206
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	203
Iron-based single-atom catalysts for selective ammoxidation of C(sp3)–H bonds and oxidative C–C cleavage reactions	200
The iron-catalysed Suzuki coupling of aryl chlorides	197
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	195
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	189
Choreography of a self-splicing ribozyme	186
Heavy labels from gas surrogates	183
Optimizing iridium sites	181
Electrolysis in tandem	180
Substrate promiscuity fuels biosynthesis success	176
Iminium catalysis in natural Diels–Alderase	176
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	175
Active sites overcrowding	169
Quantum-sensing-enabled in situ imaging of free radicals in chemical reactions	168
Pulsed electrolysis through neutron lenses	165
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	163
Enantioselective radical dearomative conjugate amination enabled by Co(II)-based metalloradical catalysis	162
Copper-catalysed enantioconvergent O-alkylation of alcohols with racemic α-tertiary haloamides to access enantioenriched hindered dialkyl ethers	162
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	161
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	161
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	160
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	155
The rise of ab initio surface thermodynamics	155
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	154
Current state and future prospects of liquid metal catalysis	154
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	151
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	151
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	149
Electrolyte effects in proton–electron transfer reactions and implications for renewable fuels and chemicals synthesis	147
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	145
Morphological and chemical state effects in pulsed CO2 electroreduction on Cu(100) unveiled by correlated spectro-microscopy	143
Organocatalytic acylation of remote arene C–H bonds	140
Catalytic borylation of tertiary C–H bonds	136
Triplet quenchers for energy-transfer photobiocatalysis	135
Modulation to probe the interface	135

Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	134
Catalysing rate and capacity	134
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	133
Practical conversion of carboxylic acids to nitriles	131
Bubble trouble	131
One, two, three, four, five!	129
Durable MnO2 electrocatalysts by stronger Mn–O bonds	128
Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	124
Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	124
Structural insights and engineering of the T4 td intron for improved RNA circularization	123
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	122
Determining CO adsorption free energies on CO2 electroreduction active sites through kinetic analysis	121
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	119
Splitting water under dryness	117
Wireless potentiometry of thermochemical heterogeneous catalysis	115
Blowing in the tube	113
CYP screening for a better terpenoid world	112
Author Correction: Stereoselective alkyl–alkyl cross-coupling	111
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	111
Frustration-driven efficiency	111
Electrosynthesis of ethylene glycol from ethylene coupled with CO2 capture	110
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	109
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	109
Step bunching instability and its effects in electrocatalysis on platinum surfaces	107
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	106
Regioselective silyl installation for arene diversification	105
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	104
Tailored for semi-hydrogenation	104
Bridging catalysis	104
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	103
A fine adjustment	103
Author Correction: A polyketide-based biosynthetic platform for diols, amino alcohols and hydroxy acids	101
And yet it catalyses	101
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	101
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	100
Continuity of reaction kinetics across the pressure and materials gaps in CO oxidation on FeO–Pt interfaces	100
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	99
Silicon frustrated Lewis pairs catalyse α-deuteration of amides and esters	98
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	98
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	97
Enantioselective Chan–Lam S-arylation of sulfenamides	96
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	95
Terpene synthases in giant viruses	94
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	93
Shining light to break planarity	93
Divide and conquer towards synthetic autotrophy	93
A TIM-barrel metalloenzyme with sugar-cleavage activity	92
Catalyst optimization through synthetic Darwinian evolution	92
Monitoring catalytic nanosites in action	92
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	91
The STRENDA Biocatalysis Guidelines for cataloguing metadata	91
Cations in alkaline hydrogen electrocatalysis	91
Molecular-scale interactions in heterogeneous (photo)electrocatalysis	90
A modular synthesis of azetidines from reactive triplet imine intermediates using an intermolecular aza Paternò–Büchi reaction	90
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	89
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	89
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	89
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	89
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	88
Stable acidic oxygen-evolving catalyst discovery through mixed accelerations	87
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	87
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	87
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	87
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	85
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	84
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	84
Methyl formate as a hydrogen energy carrier	83
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	82
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	82
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	80
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	79
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	79
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	78
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	77
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	77
Recharge your batteries	76
Scatter and conquer	76
Shielding PEM electrolysers from real-world water	75
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	75
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	74

Electrochemical imaging of thermochemical catalysis	73
Author Correction: Co3O4 as full-solar-spectrum photocatalyst for selective methane conversion through reactive oxygen species control	71
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	70
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	70
Enantioselective C(sp3)–C(sp3) bond formation by synergistic thiamine-dependent radical biocatalysis and photoredox catalysis	69
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	68
Photobiocatalytic stereocontrol of two prochiral radicals	68
An antidote for chemical reaction networks	68
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	68
Photoenzymatic enantioselective intermolecular radical hydroamination	67
Privileged Brønsted acid organocatalysis	66
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	66
Shape matters too	66
Light-driven metabolic makeover	65
Challenges and prospects in precision medicine with RNA-based biocatalysts	65
Site-selective arene C–H amination with iron-aminyl radical	64
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	64
Complex behaviour of isotopes in CO2 electroreduction	64
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	64
Synthesis of α,α-diheteroatomic carboxylic acids	64
Seeking selectivity in alkene couplings	64
Deciphering electrochemical methanol production	63
Defying thermodynamics to synthetize hydrazine	63
Benign hyperpolarization	63
Methane oxidation by catalyst reduction	62
Alkene 1,1-difunctionalizations via organometallic-radical relay	62
Effective anions	62
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	61
A pyridoxal 5′-phosphate-dependent Mannich cyclase	59
Generating alkyl carbanions for organic synthesis	59
Unlocking iron spin states for oxygen reduction	59
The 3D secrets of fuel cell catalyst layers	58
A radical way to ethylene	58
Harnessing thia-Rh-carbenes for the enantioselective synthesis of chiral α,α-diheteroatomic carboxylic acids	58
Organocatalytic regio- and stereoselective cyclopropanation of olefins	58